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Biodiesel production from Camptotheca acuminata seed oil catalyzed by novel Brönsted–Lewis acidic ionic liquid

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  • Li, Ji
  • Peng, Xiao
  • Luo, Meng
  • Zhao, Chun-Jian
  • Gu, Cheng-Bo
  • Zu, Yuan-Gang
  • Fu, Yu-Jie

Abstract

In the present research, microwave-assisted biodiesel production from Camptotheca acuminata seed oil catalyzed by novel Brönsted–Lewis acidic ionic liquid (IL) was investigated. A series of IL catalysts were prepared using Brönsted acidic IL [BSO3HMIM]HSO4 with various metal sulfates for the first time, and the catalytic mechanism of transesterification reaction using the prepared Brönsted–Lewis acidic IL was clarified. The results showed that [BSO3HMIM]HSO4–Fe2(SO4)3 represented a superior catalytic activity. Meanwhile, the parameters affecting the microwave-assisted conversion process were studied. A high conversion yield (95.7%) was achieved in short duration (about 60min) under relatively low temperature (60°C). Analyzing the FAMEs composition by GC–MS and main properties demonstrated that the biodiesel product prepared from C. acuminata seed oil was of high quality. In addition, a kinetic model was established for the conversion process. The results showed that microwave-assisted biodiesel production catalyzed by Brönsted–Lewis acidic IL was an efficient and environment-friendly technology for bioenergy industry.

Suggested Citation

  • Li, Ji & Peng, Xiao & Luo, Meng & Zhao, Chun-Jian & Gu, Cheng-Bo & Zu, Yuan-Gang & Fu, Yu-Jie, 2014. "Biodiesel production from Camptotheca acuminata seed oil catalyzed by novel Brönsted–Lewis acidic ionic liquid," Applied Energy, Elsevier, vol. 115(C), pages 438-444.
    • Handle: RePEc:eee:appene:v:115:y:2014:i:c:p:438-444
    DOI: 10.1016/j.apenergy.2013.10.025
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    5. Ibrahim, Muna Hassan & Hayyan, Maan & Hashim, Mohd Ali & Hayyan, Adeeb, 2017. "The role of ionic liquids in desulfurization of fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1534-1549.
    6. Abrahamsson, Johanna & Andreasson, Emil & Hansson, Niklas & Sandström, David & Wennberg, Ellinor & Maréchal, Manuel & Martinelli, Anna, 2015. "A Raman spectroscopic approach to investigate the production of biodiesel from soybean oil using 1-alkyl-3-methylimidazolium ionic liquids with intermediate chain length," Applied Energy, Elsevier, vol. 154(C), pages 763-770.
    7. Panchal, Balaji & Bian, Kai & Chang, Tao & Zhu, Zheng & Wang, Jinxi & Qin, Shenjun & Zhao, Cunliang & Sun, Yuzhuang, 2021. "Synthesis of Generation-2 polyamidoamine based ionic liquid: Efficient dendrimer based catalytic green fuel production from yellow grease," Energy, Elsevier, vol. 219(C).
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    9. Cao, Leichang & Zhang, Shicheng, 2015. "Production and characterization of biodiesel derived from Hodgsonia macrocarpa seed oil," Applied Energy, Elsevier, vol. 146(C), pages 135-140.
    10. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    11. Troter, Dragan Z. & Todorović, Zoran B. & Đokić-Stojanović, Dušica R. & Stamenković, Olivera S. & Veljković, Vlada B., 2016. "Application of ionic liquids and deep eutectic solvents in biodiesel production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 473-500.
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