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Analysis, synthesis, and design of a one-step dimethyl ether production via a thermodynamic approach

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  • Chen, Hsi-Jen
  • Fan, Chei-Wei
  • Yu, Chiou-Shia

Abstract

In this work, we have developed a direct one-step process design on an oxygenate production, namely, dimethyl ether (DME). DME can be used as a cetane-number booster for diesel, in addition to being capable of a substitute for liquefied petroleum gas (LPG). In order to analyze the independent chemical reactions involved in the reactor, it is necessary to carry out a study of the chemical reaction stoichiometry. And with a specific syngas feed, the following reactions are found: (1) CO2+H2=H2O+CO, (2) CO+2H2=CH3OH, and (3) 3CO+3H2=(CH3)2O+CO2. To gain an insight into the reactor design, we have also utilized the concept of thermodynamics, including equilibrium-constant method and the minimization of Gibbs free energy. Additionally, we have also united the pinch technology with the base-case design for heat exchanger network synthesis in order to compare the energy consumption and capital costs of the process with/without heat integration. Two kinds of software were used in the research–Aspen Plus and SuperTarget. The former was used for the process synthesis, design, and simulation; the latter was used to carry out the pinch analysis and the synthesis of heat exchanger network.

Suggested Citation

  • Chen, Hsi-Jen & Fan, Chei-Wei & Yu, Chiou-Shia, 2013. "Analysis, synthesis, and design of a one-step dimethyl ether production via a thermodynamic approach," Applied Energy, Elsevier, vol. 101(C), pages 449-456.
  • Handle: RePEc:eee:appene:v:101:y:2013:i:c:p:449-456
    DOI: 10.1016/j.apenergy.2012.08.025
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    References listed on IDEAS

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    1. Pellegrini, Laura A. & Soave, Giorgio & Gamba, Simone & Langè, Stefano, 2011. "Economic analysis of a combined energy–methanol production plant," Applied Energy, Elsevier, vol. 88(12), pages 4891-4897.
    2. Vakili, R. & Pourazadi, E. & Setoodeh, P. & Eslamloueyan, R. & Rahimpour, M.R., 2011. "Direct dimethyl ether (DME) synthesis through a thermally coupled heat exchanger reactor," Applied Energy, Elsevier, vol. 88(4), pages 1211-1223, April.
    3. Arab Aboosadi, Z. & Jahanmiri, A.H. & Rahimpour, M.R., 2011. "Optimization of tri-reformer reactor to produce synthesis gas for methanol production using differential evolution (DE) method," Applied Energy, Elsevier, vol. 88(8), pages 2691-2701, August.
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    Cited by:

    1. Chen, Wei-Hsin & Hsu, Chih-Liang & Wang, Xiao-Dong, 2016. "Thermodynamic approach and comparison of two-step and single step DME (dimethyl ether) syntheses with carbon dioxide utilization," Energy, Elsevier, vol. 109(C), pages 326-340.
    2. Ateka, Ainara & Pérez-Uriarte, Paula & Gamero, Mónica & Ereña, Javier & Aguayo, Andrés T. & Bilbao, Javier, 2017. "A comparative thermodynamic study on the CO2 conversion in the synthesis of methanol and of DME," Energy, Elsevier, vol. 120(C), pages 796-804.
    3. Rahman, Farahiyah Abdul & Aziz, Md Maniruzzaman A. & Saidur, R. & Bakar, Wan Azelee Wan Abu & Hainin, M.R & Putrajaya, Ramadhansyah & Hassan, Norhidayah Abdul, 2017. "Pollution to solution: Capture and sequestration of carbon dioxide (CO2) and its utilization as a renewable energy source for a sustainable future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 112-126.
    4. Kang, Yinhu & Wang, Quanhai & Lu, Xiaofeng & Wan, Hu & Ji, Xuanyu & Wang, Hu & Guo, Qiang & Yan, Jin & Zhou, Jinliang, 2015. "Experimental and numerical study on NOx and CO emission characteristics of dimethyl ether/air jet diffusion flame," Applied Energy, Elsevier, vol. 149(C), pages 204-224.
    5. Mevawala, Chirag & Jiang, Yuan & Bhattacharyya, Debangsu, 2017. "Plant-wide modeling and analysis of the shale gas to dimethyl ether (DME) process via direct and indirect synthesis routes," Applied Energy, Elsevier, vol. 204(C), pages 163-180.

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