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Biodiesel production by non-catalytic supercritical methyl acetate: Thermal stability study

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  • Niza, Noorzalila Muhammad
  • Tan, Kok Tat
  • Lee, Keat Teong
  • Ahmad, Zainal

Abstract

Biodiesel production by non-catalytic supercritical methyl acetate (SCMA) reaction has been developed and optimized in previous study using Jatropha oil as oil feedstock. The reaction produces fatty methyl acid esters (FAME) as well as triacetin as the co-product. Due to the requirement of high reaction temperatures in SCMA treatment, thus the thermal stability of methyl oleate and methyl linoleate which are the major FAME in SCMA was investigated at temperature ranging from 330°C to 420°C. In addition, thermal stability of triacetin which was utilized as fuel additive in biodiesel was also investigated. The results revealed that the thermal stability of poly-unsaturated methyl linoleate decreases dramatically as temperature is increased from 330°C to 420°C while degradation of methyl oleate was only significant at 390°C and above. Similar behaviour was also observed for triacetin which was found to degrade at high temperatures, resulting in low yield of biodiesel fuel even at optimum conditions.

Suggested Citation

  • Niza, Noorzalila Muhammad & Tan, Kok Tat & Lee, Keat Teong & Ahmad, Zainal, 2013. "Biodiesel production by non-catalytic supercritical methyl acetate: Thermal stability study," Applied Energy, Elsevier, vol. 101(C), pages 198-202.
    • Handle: RePEc:eee:appene:v:101:y:2013:i:c:p:198-202
    DOI: 10.1016/j.apenergy.2012.03.033
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    References listed on IDEAS

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    1. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
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    2. Andreo-Martínez, Pedro & Ortiz-Martínez, Víctor Manuel & García-Martínez, Nuria & de los Ríos, Antonia Pérez & Hernández-Fernández, Francisco José & Quesada-Medina, Joaquín, 2020. "Production of biodiesel under supercritical conditions: State of the art and bibliometric analysis," Applied Energy, Elsevier, vol. 264(C).
    3. Rafael Estevez & Laura Aguado-Deblas & Francisco J. López-Tenllado & Carlos Luna & Juan Calero & Antonio A. Romero & Felipa M. Bautista & Diego Luna, 2022. "Biodiesel Is Dead: Long Life to Advanced Biofuels—A Comprehensive Critical Review," Energies, MDPI, vol. 15(9), pages 1-39, April.
    4. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    5. Lim, Steven & Lee, Keat Teong, 2014. "Investigation of impurity tolerance and thermal stability for biodiesel production from Jatropha curcas L. seeds using supercritical reactive extraction," Energy, Elsevier, vol. 68(C), pages 71-79.
    6. Calero, Juan & Luna, Diego & Sancho, Enrique D. & Luna, Carlos & Bautista, Felipa M. & Romero, Antonio A. & Posadillo, Alejandro & Berbel, Julio & Verdugo-Escamilla, Cristóbal, 2015. "An overview on glycerol-free processes for the production of renewable liquid biofuels, applicable in diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1437-1452.

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