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A method to enhance the CO 2 storage capacity of pyroxenitic rocks

Author

Listed:
  • Ioannis Rigopoulos
  • Michalis A. Vasiliades
  • Klito C. Petallidou
  • Ioannis Ioannou
  • Angelos M. Efstathiou
  • Theodora Kyratsi

Abstract

Investigation of new efficient pathways for CO 2 sequestration is of great significance for the mitigation of climate change. Ultramafic rocks are considered among the most promising lithotypes for the safe storage of CO 2 via mineral carbonation. This paper investigates a powerful method for the optimization of the ex situ carbonation of pyroxenitic rocks, which comprise part of ultramafic lithologies occurring in ophiolite complexes. The ball milling process was applied to a sample of pyroxenite from the Troodos ophiolite (Cyprus) for the first time, in order to create novel nanomaterials with enhanced CO 2 storage capacity. The goal was to accelerate the kinetics of rock‐fluid reactions during the carbonation process. The starting rock material and the ball‐milled samples were characterized using a variety of methodologies. The experimental results imply that only a few hours of wet ball milling with ethanol as process control agent can substantially increase the CO 2 storage capacity of pyroxenites. Through temperature‐programmed desorption of CO 2 (CO 2 ‐TPD) experiments, we show that the optimum milling conditions are 4 h of ball milling with 50 wt% ethanol, leading to an increase of the CO 2 uptake of the studied rock material by 41 times. This notable increase designates that pyroxenites are very promising lithologies for CO 2 storage via ex situ carbonation, and that ball milling can be an effective preparation technique for this process, providing an efficient and secure carbon storage solution.© 2015 Society of Chemical Industry and John Wiley & Sons, Ltd

Suggested Citation

  • Ioannis Rigopoulos & Michalis A. Vasiliades & Klito C. Petallidou & Ioannis Ioannou & Angelos M. Efstathiou & Theodora Kyratsi, 2015. "A method to enhance the CO 2 storage capacity of pyroxenitic rocks," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 5(5), pages 577-591, October.
    • Handle: RePEc:wly:greenh:v:5:y:2015:i:5:p:577-591
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    File URL: http://hdl.handle.net/10.1002/ghg.1502
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    1. Lackner, Klaus S. & Wendt, Christopher H. & Butt, Darryl P. & Joyce, Edward L. & Sharp, David H., 1995. "Carbon dioxide disposal in carbonate minerals," Energy, Elsevier, vol. 20(11), pages 1153-1170.
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    1. Rigopoulos, Ioannis & Török, Ákos & Kyratsi, Theodora & Delimitis, Andreas & Ioannou, Ioannis, 2018. "Sustainable exploitation of mafic rock quarry waste for carbon sequestration following ball milling," Resources Policy, Elsevier, vol. 59(C), pages 24-32.

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