IDEAS home Printed from https://ideas.repec.org/a/wly/greenh/v11y2021i6p1213-1221.html
   My bibliography  Save this article

Effect of micropores on the structure and CO2 methanation performance of supported Ni/SiO2 catalyst

Author

Listed:
  • Liang Shen
  • Minghui Zhu
  • Jing Xu

Abstract

Two types of SiO2 with different microporosities were evaluated as supports for the Ni/SiO2 catalysts. The CO2 methanation performance of the catalysts was evaluated, and the structure‐activity relationship was elucidated with thorough characterizations. For the Ni/SiO2 catalyst with plenty of micropores, both ultrasmall Ni nanoclusters and larger Ni nanoparticles are present. In contrast, the one with fewer micropores only contains large Ni nanoparticles. During the CO2 methanation reaction, CO2 can be activated to CO on small Ni nanoclusters and further converted to CH4 on larger Ni nanoparticles. Such a tandem catalysis behavior greatly improves the CO2 methanation activity. The CH4 yield reaches 33.5 μmol·g–1·s–1 at 450 °C under 0.1 MPa with a feed H2/CO2 mol ratio of 4:1 and a space velocity of 30 L·h–1·g–1. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd.

Suggested Citation

  • Liang Shen & Minghui Zhu & Jing Xu, 2021. "Effect of micropores on the structure and CO2 methanation performance of supported Ni/SiO2 catalyst," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 11(6), pages 1213-1221, December.
    • Handle: RePEc:wly:greenh:v:11:y:2021:i:6:p:1213-1221
    DOI: 10.1002/ghg.2116
    as

    Download full text from publisher

    File URL: https://doi.org/10.1002/ghg.2116
    Download Restriction: no
    File URL: https://libkey.io/10.1002/ghg.2116?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhiqi Zhang & Yugang Chen & Liqi Zhou & Chi Chen & Zhen Han & Bingsen Zhang & Qiang Wu & Lijun Yang & Lingyu Du & Yongfeng Bu & Peng Wang & Xizhang Wang & Hui Yang & Zheng Hu, 2019. "The simplest construction of single-site catalysts by the synergism of micropore trapping and nitrogen anchoring," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    2. Jeremy D. Shakun & Peter U. Clark & Feng He & Shaun A. Marcott & Alan C. Mix & Zhengyu Liu & Bette Otto-Bliesner & Andreas Schmittner & Edouard Bard, 2012. "Global warming preceded by increasing carbon dioxide concentrations during the last deglaciation," Nature, Nature, vol. 484(7392), pages 49-54, April.
    3. Yu Tang & Yuting Li & Victor Fung & De-en Jiang & Weixin Huang & Shiran Zhang & Yasuhiro Iwasawa & Tomohiro Sakata & Luan Nguyen & Xiaoyan Zhang & Anatoly I. Frenkel & Franklin (Feng) Tao, 2018. "Single rhodium atoms anchored in micropores for efficient transformation of methane under mild conditions," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    4. Charlotte Vogt & Matteo Monai & Ellen B. Sterk & Jonas Palle & Angela E. M. Melcherts & Bart Zijlstra & Esther Groeneveld & Peter H. Berben & Jelle M. Boereboom & Emiel J. M. Hensen & Florian Meirer &, 2019. "Understanding carbon dioxide activation and carbon–carbon coupling over nickel," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shuai Zhang & Zhoufei Yu & Yue Wang & Xun Gong & Ann Holbourn & Fengming Chang & Heng Liu & Xuhua Cheng & Tiegang Li, 2022. "Thermal coupling of the Indo-Pacific warm pool and Southern Ocean over the past 30,000 years," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    2. Granville Tunnicliffe Wilson & John Haywood & Lynda Petherick, 2022. "Modeling cycles and interdependence in irregularly sampled geophysical time series," Environmetrics, John Wiley & Sons, Ltd., vol. 33(2), March.
    3. Inmaculada Carrasco & Juan Sebastián Castillo-Valero & Carmen Córcoles & Marcos Carchano, 2021. "Greening Wine Exports? Changes in the Carbon Footprint of Spanish Wine Exports," IJERPH, MDPI, vol. 18(17), pages 1-13, August.
    4. Heather M. Stoll & Isabel Cacho & Edward Gasson & Jakub Sliwinski & Oliver Kost & Ana Moreno & Miguel Iglesias & Judit Torner & Carlos Perez-Mejias & Negar Haghipour & Hai Cheng & R. Lawrence Edwards, 2022. "Rapid northern hemisphere ice sheet melting during the penultimate deglaciation," Nature Communications, Nature, vol. 13(1), pages 1-16, December.
    5. Pranav P. Sharma & Xiao‐Dong Zhou, 2017. "Electrocatalytic conversion of carbon dioxide to fuels: a review on the interaction between CO2 and the liquid electrolyte," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 6(4), July.
    6. Olivier Cartapanis & Lukas Jonkers & Paola Moffa-Sanchez & Samuel L. Jaccard & Anne Vernal, 2022. "Complex spatio-temporal structure of the Holocene Thermal Maximum," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    7. Si Woo Lee & Mauricio Lopez Luna & Nikolay Berdunov & Weiming Wan & Sebastian Kunze & Shamil Shaikhutdinov & Beatriz Roldan Cuenya, 2023. "Unraveling surface structures of gallium promoted transition metal catalysts in CO2 hydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-7, December.
    8. Charlotte Vogt & Florian Meirer & Matteo Monai & Esther Groeneveld & Davide Ferri & Rutger A. Santen & Maarten Nachtegaal & Raymond R. Unocic & Anatoly I. Frenkel & Bert M. Weckhuysen, 2021. "Dynamic restructuring of supported metal nanoparticles and its implications for structure insensitive catalysis," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    9. Wenchao Zhang & Haibin Wu & Jun Cheng & Junyan Geng & Qin Li & Yong Sun & Yanyan Yu & Huayu Lu & Zhengtang Guo, 2022. "Holocene seasonal temperature evolution and spatial variability over the Northern Hemisphere landmass," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    10. Acevedo, Sebastian & Mrkaic, Mico & Novta, Natalija & Pugacheva, Evgenia & Topalova, Petia, 2020. "The Effects of Weather Shocks on Economic Activity: What are the Channels of Impact?," Journal of Macroeconomics, Elsevier, vol. 65(C).
    11. Shengtai Hou & Xuefeng Ma & Yuan Shu & Jiafeng Bao & Qiuyue Zhang & Mingshu Chen & Pengfei Zhang & Sheng Dai, 2021. "Self-regeneration of supported transition metals by a high entropy-driven principle," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    12. Mengmeng Liu & Hao Wu & Haopeng Wang, 2023. "Will Trade Protection Trigger a Surge in Investment-Related CO 2 Emissions? Evidence from Multi-Regional Input–Output Model," Sustainability, MDPI, vol. 15(13), pages 1-21, June.
    13. Anne Dallmeyer & Thomas Kleinen & Martin Claussen & Nils Weitzel & Xianyong Cao & Ulrike Herzschuh, 2022. "The deglacial forest conundrum," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    14. Yiping Yang & Lanlan Zhang & Liang Yi & Fuchang Zhong & Zhengyao Lu & Sui Wan & Yan Du & Rong Xiang, 2023. "A contracting Intertropical Convergence Zone during the Early Heinrich Stadial 1," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    15. Yelin Wang & Ping Yang & Zan Song & Julien Chevallier & Qingtai Xiao, 2024. "Intelligent Prediction of Annual CO2 Emissions Under Data Decomposition Mode," Computational Economics, Springer;Society for Computational Economics, vol. 63(2), pages 711-740, February.
    16. Wenqing Zhang & Dawei Xi & Yihong Chen & Aobo Chen & Yawen Jiang & Hengjie Liu & Zeyu Zhou & Hui Zhang & Zhi Liu & Ran Long & Yujie Xiong, 2023. "Light-driven flow synthesis of acetic acid from methane with chemical looping," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    17. Tsai, Bi-Huei & Chang, Chih-Jen & Chang, Chun-Hsien, 2016. "Elucidating the consumption and CO2 emissions of fossil fuels and low-carbon energy in the United States using Lotka–Volterra models," Energy, Elsevier, vol. 100(C), pages 416-424.
    18. Hongfei Wang & Zhipeng Yu & Jie Zhou & Chengming Li & Ananthanarasimhan Jayanarasimhan & Xiqiang Zhao & Hao Zhang, 2023. "A Scientometric Review of CO 2 Electroreduction Research from 2005 to 2022," Energies, MDPI, vol. 16(2), pages 1-21, January.
    19. Fernando Goulart & Frédéric Mertens, 2017. "The Late mangos- Is There Any Doubt Humans Are Inducing Climate Change?," Biomedical Journal of Scientific & Technical Research, Biomedical Research Network+, LLC, vol. 1(7), pages 2022-2024, December.
    20. Guusje Delen & Matteo Monai & Katarina Stančiaková & Bettina Baumgartner & Florian Meirer & Bert M. Weckhuysen, 2023. "Structure sensitivity in gas sorption and conversion on metal-organic frameworks," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:wly:greenh:v:11:y:2021:i:6:p:1213-1221. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Wiley Content Delivery (email available below). General contact details of provider: https://doi.org/10.1002/(ISSN)2152-3878 .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.