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Giant negative thermal expansion exceeding 1000 K in PrMnO3 via synergy of local structure distortion and orbital disordering

Author

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  • Feiyu Qin

    (Xi’an Jiaotong University)

  • Xiaoya Bai

    (Xi’an Jiaotong University)

  • Yue-Wen Fang

    (Europa Plaza 1
    Manuel de Lardizabal pasealekua 5)

  • Pengli Zhu

    (Chinese Academy of Sciences)

  • Jun Wang

    (Fudan University)

  • Pengtao Cheng

    (Hangzhou Dianzi University)

  • Dunhui Wang

    (Hangzhou Dianzi University)

  • Lei Hu

    (Xi’an Jiaotong University)

  • Jun Sun

    (Xi’an Jiaotong University)

  • Xiangdong Ding

    (Xi’an Jiaotong University)

Abstract

Giant negative thermal expansion (NTE), defined by volumetric expansion αV

Suggested Citation

  • Feiyu Qin & Xiaoya Bai & Yue-Wen Fang & Pengli Zhu & Jun Wang & Pengtao Cheng & Dunhui Wang & Lei Hu & Jun Sun & Xiangdong Ding, 2025. "Giant negative thermal expansion exceeding 1000 K in PrMnO3 via synergy of local structure distortion and orbital disordering," Nature Communications, Nature, vol. 16(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-025-64925-7
    DOI: 10.1038/s41467-025-64925-7
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    References listed on IDEAS

    as
    1. Yuan Zhang & Bin Chen & Daqin Guan & Meigui Xu & Ran Ran & Meng Ni & Wei Zhou & Ryan O’Hayre & Zongping Shao, 2021. "Thermal-expansion offset for high-performance fuel cell cathodes," Nature, Nature, vol. 591(7849), pages 246-251, March.
    2. Koshi Takenaka & Yoshihiko Okamoto & Tsubasa Shinoda & Naoyuki Katayama & Yuki Sakai, 2017. "Colossal negative thermal expansion in reduced layered ruthenate," Nature Communications, Nature, vol. 8(1), pages 1-7, April.
    3. M. Uehara & S. Mori & C. H. Chen & S.-W. Cheong, 1999. "Percolative phase separation underlies colossal magnetoresistance in mixed-valent manganites," Nature, Nature, vol. 399(6736), pages 560-563, June.
    4. Meng Xu & Qiang Li & Yuzhu Song & Yuanji Xu & Andrea Sanson & Naike Shi & Na Wang & Qiang Sun & Changtian Wang & Xin Chen & Yongqiang Qiao & Feixiang Long & Hui Liu & Qiang Zhang & Alessandro Venier &, 2023. "Giant uniaxial negative thermal expansion in FeZr2 alloy over a wide temperature range," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    5. Masaki Azuma & Wei-tin Chen & Hayato Seki & Michal Czapski & Smirnova Olga & Kengo Oka & Masaichiro Mizumaki & Tetsu Watanuki & Naoki Ishimatsu & Naomi Kawamura & Shintaro Ishiwata & Matthew G. Tucker, 2011. "Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer," Nature Communications, Nature, vol. 2(1), pages 1-5, September.
    6. Chengyi Yu & Kun Lin & Qinghua Zhang & Huihui Zhu & Ke An & Yan Chen & Dunji Yu & Tianyi Li & Xiaoqian Fu & Qian Yu & Li You & Xiaojun Kuang & Yili Cao & Qiang Li & Jinxia Deng & Xianran Xing, 2024. "An isotropic zero thermal expansion alloy with super-high toughness," Nature Communications, Nature, vol. 15(1), pages 1-9, December.
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