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Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer

Author

Listed:
  • Masaki Azuma

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
    Present address: Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.)

  • Wei-tin Chen

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
    Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh)

  • Hayato Seki

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.)

  • Michal Czapski

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.)

  • Smirnova Olga

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.)

  • Kengo Oka

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
    Present address: Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503, Japan.)

  • Masaichiro Mizumaki

    (Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan.)

  • Tetsu Watanuki

    (Japan Atomic Energy Agency, 1-1-1 Kouto, Sayo, Hyogo 679-5148, Japan.)

  • Naoki Ishimatsu

    (Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-Hiroshima 739-8526, Japan.)

  • Naomi Kawamura

    (Japan Synchrotron Radiation Research Institute, 1-1-1 Kouto, Sayo, Hyogo 679-5198, Japan.)

  • Shintaro Ishiwata

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.
    University of Tokyo)

  • Matthew G. Tucker

    (ISIS facility, Rutherford Appleton Laboratory, Chilton, Didcot OX11 0QX, UK.)

  • Yuichi Shimakawa

    (Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan.)

  • J. Paul Attfield

    (Centre for Science at Extreme Conditions and School of Chemistry, University of Edinburgh)

Abstract

The unusual property of negative thermal expansion is of fundamental interest and may be used to fabricate composites with zero or other controlled thermal expansion values. Here we report that colossal negative thermal expansion (defined as linear expansion

Suggested Citation

  • Masaki Azuma & Wei-tin Chen & Hayato Seki & Michal Czapski & Smirnova Olga & Kengo Oka & Masaichiro Mizumaki & Tetsu Watanuki & Naoki Ishimatsu & Naomi Kawamura & Shintaro Ishiwata & Matthew G. Tucker, 2011. "Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer," Nature Communications, Nature, vol. 2(1), pages 1-5, September.
    • Handle: RePEc:nat:natcom:v:2:y:2011:i:1:d:10.1038_ncomms1361
    DOI: 10.1038/ncomms1361
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    Cited by:

    1. Chengyi Yu & Kun Lin & Xin Chen & Suihe Jiang & Yili Cao & Wenjie Li & Liang Chen & Ke An & Yan Chen & Dunji Yu & Kenichi Kato & Qinghua Zhang & Lin Gu & Li You & Xiaojun Kuang & Hui Wu & Qiang Li & J, 2023. "Superior zero thermal expansion dual-phase alloy via boron-migration mediated solid-state reaction," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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