IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-45700-6.html
   My bibliography  Save this article

Dual-site segmentally synergistic catalysis mechanism: boosting CoFeSx nanocluster for sustainable water oxidation

Author

Listed:
  • Siran Xu

    (Zhengzhou University)

  • Sihua Feng

    (University of Science and Technology of China)

  • Yue Yu

    (Zhengzhou University)

  • Dongping Xue

    (Zhengzhou University)

  • Mengli Liu

    (Zhengzhou University)

  • Chao Wang

    (University of Science and Technology of China)

  • Kaiyue Zhao

    (Peking University)

  • Bingjun Xu

    (Peking University)

  • Jia-Nan Zhang

    (Zhengzhou University
    State Key Laboratory of Coking Coal Resources Green Exploitation)

Abstract

Efficient oxygen evolution reaction electrocatalysts are essential for sustainable clean energy conversion. However, catalytic materials followed the conventional adsorbate evolution mechanism (AEM) with the inherent scaling relationship between key oxygen intermediates *OOH and *OH, or the lattice-oxygen-mediated mechanism (LOM) with the possible lattice oxygen migration and structural reconstruction, which are not favorable to the balance between high activity and stability. Herein, we propose an unconventional Co-Fe dual-site segmentally synergistic mechanism (DSSM) for single-domain ferromagnetic catalyst CoFeSx nanoclusters on carbon nanotubes (CNT) (CFS-ACs/CNT), which can effectively break the scaling relationship without sacrificing stability. Co3+ (L.S, t2g6eg0) supplies the strongest OH* adsorption energy, while Fe3+ (M.S, t2g4eg1) exposes strong O* adsorption. These dual-sites synergistically produce of Co-O-O-Fe intermediates, thereby accelerating the release of triplet-state oxygen ( ↑ O = O ↑ ). As predicted, the prepared CFS-ACs/CNT catalyst exhibits less overpotential than that of commercial IrO2, as well as approximately 633 h of stability without significant potential loss.

Suggested Citation

  • Siran Xu & Sihua Feng & Yue Yu & Dongping Xue & Mengli Liu & Chao Wang & Kaiyue Zhao & Bingjun Xu & Jia-Nan Zhang, 2024. "Dual-site segmentally synergistic catalysis mechanism: boosting CoFeSx nanocluster for sustainable water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45700-6
    DOI: 10.1038/s41467-024-45700-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-45700-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-45700-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhanwu Lei & Wenbin Cai & Yifei Rao & Kuan Wang & Yuyuan Jiang & Yang Liu & Xu Jin & Jianming Li & Zhengxing Lv & Shuhong Jiao & Wenhua Zhang & Pengfei Yan & Shuo Zhang & Ruiguo Cao, 2022. "Coordination modulation of iridium single-atom catalyst maximizing water oxidation activity," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    2. Jie Ding & Zhiming Wei & Fuhua Li & Jincheng Zhang & Qiao Zhang & Jing Zhou & Weijue Wang & Yuhang Liu & Zhen Zhang & Xiaozhi Su & Runze Yang & Wei Liu & Chenliang Su & Hong Bin Yang & Yanqiang Huang , 2023. "Atomic high-spin cobalt(II) center for highly selective electrochemical CO reduction to CH3OH," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Zhen-Feng Huang & Jiajia Song & Yonghua Du & Shibo Xi & Shuo Dou & Jean Marie Vianney Nsanzimana & Cheng Wang & Zhichuan J. Xu & Xin Wang, 2019. "Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts," Nature Energy, Nature, vol. 4(4), pages 329-338, April.
    4. Zhen-Feng Huang & Shibo Xi & Jiajia Song & Shuo Dou & Xiaogang Li & Yonghua Du & Caozheng Diao & Zhichuan J. Xu & Xin Wang, 2021. "Tuning of lattice oxygen reactivity and scaling relation to construct better oxygen evolution electrocatalyst," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    5. Tianze Wu & Xiao Ren & Yuanmiao Sun & Shengnan Sun & Guoyu Xian & Günther G. Scherer & Adrian C. Fisher & Daniel Mandler & Joel W. Ager & Alexis Grimaud & Junling Wang & Chengmin Shen & Haitao Yang & , 2021. "Spin pinning effect to reconstructed oxyhydroxide layer on ferromagnetic oxides for enhanced water oxidation," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    6. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    7. Woong Hee Lee & Man Ho Han & Young-Jin Ko & Byoung Koun Min & Keun Hwa Chae & Hyung-Suk Oh, 2022. "Electrode reconstruction strategy for oxygen evolution reaction: maintaining Fe-CoOOH phase with intermediate-spin state during electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    8. Gege Yang & Jiawei Zhu & Pengfei Yuan & Yongfeng Hu & Gan Qu & Bang-An Lu & Xiaoyi Xue & Hengbo Yin & Wenzheng Cheng & Junqi Cheng & Wenjing Xu & Jin Li & Jinsong Hu & Shichun Mu & Jia-Nan Zhang, 2021. "Regulating Fe-spin state by atomically dispersed Mn-N in Fe-N-C catalysts with high oxygen reduction activity," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    9. Alexis Grimaud & Arnaud Demortière & Matthieu Saubanère & Walid Dachraoui & Martial Duchamp & Marie-Liesse Doublet & Jean-Marie Tarascon, 2017. "Erratum: Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction," Nature Energy, Nature, vol. 2(2), pages 1-1, February.
    10. Alexis Grimaud & Arnaud Demortière & Matthieu Saubanère & Walid Dachraoui & Martial Duchamp & Marie-Liesse Doublet & Jean-Marie Tarascon, 2017. "Activation of surface oxygen sites on an iridium-based model catalyst for the oxygen evolution reaction," Nature Energy, Nature, vol. 2(1), pages 1-10, January.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Shu-Pei Zeng & Hang Shi & Tian-Yi Dai & Yang Liu & Zi Wen & Gao-Feng Han & Tong-Hui Wang & Wei Zhang & Xing-You Lang & Wei-Tao Zheng & Qing Jiang, 2023. "Lamella-heterostructured nanoporous bimetallic iron-cobalt alloy/oxyhydroxide and cerium oxynitride electrodes as stable catalysts for oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    2. Haoyin Zhong & Qi Zhang & Junchen Yu & Xin Zhang & Chao Wu & Hang An & Yifan Ma & Hao Wang & Jun Zhang & Yong-Wei Zhang & Caozheng Diao & Zhi Gen Yu & Shibo Xi & Xiaopeng Wang & Junmin Xue, 2023. "Key role of eg* band broadening in nickel-based oxyhydroxides on coupled oxygen evolution mechanism," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Zuyun He & Jun Zhang & Zhiheng Gong & Hang Lei & Deng Zhou & Nian Zhang & Wenjie Mai & Shijun Zhao & Yan Chen, 2022. "Activating lattice oxygen in NiFe-based (oxy)hydroxide for water electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    4. Shiyi Chen & Shishi Zhang & Lei Guo & Lun Pan & Chengxiang Shi & Xiangwen Zhang & Zhen-Feng Huang & Guidong Yang & Ji-Jun Zou, 2023. "Reconstructed Ir‒O‒Mo species with strong Brønsted acidity for acidic water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    5. Fangqing Wang & Peichao Zou & Yangyang Zhang & Wenli Pan & Ying Li & Limin Liang & Cong Chen & Hui Liu & Shijian Zheng, 2023. "Activating lattice oxygen in high-entropy LDH for robust and durable water oxidation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    6. Gyu Rac Lee & Jun Kim & Doosun Hong & Ye Ji Kim & Hanhwi Jang & Hyeuk Jin Han & Chang-Kyu Hwang & Donghun Kim & Jin Young Kim & Yeon Sik Jung, 2023. "Efficient and sustainable water electrolysis achieved by excess electron reservoir enabling charge replenishment to catalysts," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    7. Fan Liao & Kui Yin & Yujin Ji & Wenxiang Zhu & Zhenglong Fan & Youyong Li & Jun Zhong & Mingwang Shao & Zhenhui Kang & Qi Shao, 2023. "Iridium oxide nanoribbons with metastable monoclinic phase for highly efficient electrocatalytic oxygen evolution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    8. Pengcheng Ye & Keqing Fang & Haiyan Wang & Yahao Wang & Hao Huang & Chenbin Mo & Jiqiang Ning & Yong Hu, 2024. "Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    9. Yiming Zhu & Jiaao Wang & Toshinari Koketsu & Matthias Kroschel & Jin-Ming Chen & Su-Yang Hsu & Graeme Henkelman & Zhiwei Hu & Peter Strasser & Jiwei Ma, 2022. "Iridium single atoms incorporated in Co3O4 efficiently catalyze the oxygen evolution in acidic conditions," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    10. Chen, Xuejun & Yang, Yongming & Cui, Zhixin & Shen, Jun, 2019. "Vibration fault diagnosis of wind turbines based on variational mode decomposition and energy entropy," Energy, Elsevier, vol. 174(C), pages 1100-1109.
    11. Panlong Zhai & Chen Wang & Yuanyuan Zhao & Yanxue Zhang & Junfeng Gao & Licheng Sun & Jungang Hou, 2023. "Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    12. Muhammad Habib Ur Rehman & Luigi Coppola & Ernestino Lufrano & Isabella Nicotera & Cataldo Simari, 2023. "Enhancing Water Retention, Transport, and Conductivity Performance in Fuel Cell Applications: Nafion-Based Nanocomposite Membranes with Organomodified Graphene Oxide Nanoplatelets," Energies, MDPI, vol. 16(23), pages 1-11, November.
    13. Pin Li & Jinsuo Zhang, 2019. "Is China’s Energy Supply Sustainable? New Research Model Based on the Exponential Smoothing and GM(1,1) Methods," Energies, MDPI, vol. 12(2), pages 1-30, January.
    14. Mao, Guozhu & Zou, Hongyang & Chen, Guanyi & Du, Huibin & Zuo, Jian, 2015. "Past, current and future of biomass energy research: A bibliometric analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1823-1833.
    15. Luo, Rongrong & Wang, Liuwei & Yu, Wei & Shao, Feilong & Shen, Haikuo & Xie, Huaqing, 2023. "High energy storage density titanium nitride-pentaerythritol solid–solid composite phase change materials for light-thermal-electric conversion," Applied Energy, Elsevier, vol. 331(C).
    16. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    17. Géremi Gilson Dranka & Paula Ferreira, 2020. "Electric Vehicles and Biofuels Synergies in the Brazilian Energy System," Energies, MDPI, vol. 13(17), pages 1-22, August.
    18. Shiquan Lin & Laipan Zhu & Zhen Tang & Zhong Lin Wang, 2022. "Spin-selected electron transfer in liquid–solid contact electrification," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    19. Neves, Renato Cruz & Klein, Bruno Colling & da Silva, Ricardo Justino & Rezende, Mylene Cristina Alves Ferreira & Funke, Axel & Olivarez-Gómez, Edgardo & Bonomi, Antonio & Maciel-Filho, Rubens, 2020. "A vision on biomass-to-liquids (BTL) thermochemical routes in integrated sugarcane biorefineries for biojet fuel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    20. Li, Jinpeng & Chen, Xiangjie & Li, Guiqiang, 2023. "Effect of separation wavelength on a novel solar-driven hybrid hydrogen production system (SDHPS) by solar full spectrum energy," Renewable Energy, Elsevier, vol. 215(C).

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-45700-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.