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Tracking the correlation between spintronic structure and oxygen evolution reaction mechanism of cobalt-ruthenium-based electrocatalyst

Author

Listed:
  • Chen Wang

    (Dalian University of Technology)

  • Chaoyuan Deng

    (Southwest Jiaotong University)

  • Panlong Zhai

    (Dalian University of Technology)

  • Xiaoran Shi

    (Ministry of Education)

  • Wei Liu

    (Dalian University of Technology)

  • Dingfeng Jin

    (Dalian University of Technology)

  • Bing Shang

    (Dalian University of Technology)

  • Junfeng Gao

    (Ministry of Education)

  • Licheng Sun

    (Westlake University
    KTH Royal Institute of Technology)

  • Jungang Hou

    (Dalian University of Technology)

Abstract

Regulating the spintronic structure of electrocatalysts can improve the oxygen evolution reaction performance efficiently. Nonetheless, the effects of tuning the spintronic structure for the oxygen evolution reaction mechanisms have rarely been discussed. Here, we show a ruthenium-cobalt-tin oxide with optimized spintronic structure due to the quantum spin interaction of Ru and Co. The specific spintronic structure of ruthenium-cobalt-tin oxide promotes the charge transfer kinetics and intermediates evolution behavior under applied potential, generating long-lived active species with higher spin density sites for the oxygen evolution reaction after the reconstruction process. Moreover, the ruthenium-cobalt-tin oxide possesses decoupled proton-electron transfer procedure during the oxygen evolution reaction process, demonstrating that the electron transfer procedure of O-O bond formation between *O intermediate and lattice oxygen in Co-O-Ru is the rate-determining step of the oxygen evolution reaction process. This work provides rational perspectives on the correlation between spintronic structure and oxygen evolution reaction mechanism.

Suggested Citation

  • Chen Wang & Chaoyuan Deng & Panlong Zhai & Xiaoran Shi & Wei Liu & Dingfeng Jin & Bing Shang & Junfeng Gao & Licheng Sun & Jungang Hou, 2025. "Tracking the correlation between spintronic structure and oxygen evolution reaction mechanism of cobalt-ruthenium-based electrocatalyst," Nature Communications, Nature, vol. 16(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:16:y:2025:i:1:d:10.1038_s41467-024-55688-8
    DOI: 10.1038/s41467-024-55688-8
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    1. Jinzhen Huang & Hongyuan Sheng & R. Dominic Ross & Jiecai Han & Xianjie Wang & Bo Song & Song Jin, 2021. "Modifying redox properties and local bonding of Co3O4 by CeO2 enhances oxygen evolution catalysis in acid," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Yao Yang & Sheena Louisia & Sunmoon Yu & Jianbo Jin & Inwhan Roh & Chubai Chen & Maria V. Fonseca Guzman & Julian Feijóo & Peng-Cheng Chen & Hongsen Wang & Christopher J. Pollock & Xin Huang & Yu-Tsun, 2023. "Operando studies reveal active Cu nanograins for CO2 electroreduction," Nature, Nature, vol. 614(7947), pages 262-269, February.
    3. Hong Nhan Nong & Lorenz J. Falling & Arno Bergmann & Malte Klingenhof & Hoang Phi Tran & Camillo Spöri & Rik Mom & Janis Timoshenko & Guido Zichittella & Axel Knop-Gericke & Simone Piccinin & Javier P, 2020. "Key role of chemistry versus bias in electrocatalytic oxygen evolution," Nature, Nature, vol. 587(7834), pages 408-413, November.
    4. Zeyu Wang & William A. Goddard & Hai Xiao, 2023. "Potential-dependent transition of reaction mechanisms for oxygen evolution on layered double hydroxides," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    5. Zhen-Feng Huang & Jiajia Song & Yonghua Du & Shibo Xi & Shuo Dou & Jean Marie Vianney Nsanzimana & Cheng Wang & Zhichuan J. Xu & Xin Wang, 2019. "Chemical and structural origin of lattice oxygen oxidation in Co–Zn oxyhydroxide oxygen evolution electrocatalysts," Nature Energy, Nature, vol. 4(4), pages 329-338, April.
    6. Yan Jiao & Yao Zheng & Kenneth Davey & Shi-Zhang Qiao, 2016. "Activity origin and catalyst design principles for electrocatalytic hydrogen evolution on heteroatom-doped graphene," Nature Energy, Nature, vol. 1(10), pages 1-9, October.
    7. Gaurav Assat & Jean-Marie Tarascon, 2018. "Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries," Nature Energy, Nature, vol. 3(5), pages 373-386, May.
    8. Panlong Zhai & Chen Wang & Yuanyuan Zhao & Yanxue Zhang & Junfeng Gao & Licheng Sun & Jungang Hou, 2023. "Regulating electronic states of nitride/hydroxide to accelerate kinetics for oxygen evolution at large current density," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Wenlong Li & Fusheng Li & Hao Yang & Xiujuan Wu & Peili Zhang & Yu Shan & Licheng Sun, 2019. "A bio-inspired coordination polymer as outstanding water oxidation catalyst via second coordination sphere engineering," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    10. Woong Hee Lee & Man Ho Han & Young-Jin Ko & Byoung Koun Min & Keun Hwa Chae & Hyung-Suk Oh, 2022. "Electrode reconstruction strategy for oxygen evolution reaction: maintaining Fe-CoOOH phase with intermediate-spin state during electrolysis," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    11. J. Tyler Mefford & Xi Rong & Artem M. Abakumov & William G. Hardin & Sheng Dai & Alexie M. Kolpak & Keith P. Johnston & Keith J. Stevenson, 2016. "Water electrolysis on La1−xSrxCoO3−δ perovskite electrocatalysts," Nature Communications, Nature, vol. 7(1), pages 1-11, April.
    12. Shangheng Liu & Shize Geng & Ling Li & Ying Zhang & Guomian Ren & Bolong Huang & Zhiwei Hu & Jyh-Fu Lee & Yu-Hong Lai & Ying-Hao Chu & Yong Xu & Qi Shao & Xiaoqing Huang, 2022. "A top-down strategy for amorphization of hydroxyl compounds for electrocatalytic oxygen evolution," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    13. Shiming Zhou & Xianbing Miao & Xu Zhao & Chao Ma & Yuhao Qiu & Zhenpeng Hu & Jiyin Zhao & Lei Shi & Jie Zeng, 2016. "Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition," Nature Communications, Nature, vol. 7(1), pages 1-7, September.
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