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A strong bimetal-support interaction in ethanol steam reforming

Author

Listed:
  • Hao Meng

    (Beijing University of Chemical Technology)

  • Yusen Yang

    (Beijing University of Chemical Technology)

  • Tianyao Shen

    (Beijing University of Chemical Technology)

  • Wei Liu

    (Beijing University of Chemical Technology)

  • Lei Wang

    (Beijing University of Chemical Technology)

  • Pan Yin

    (Beijing University of Chemical Technology)

  • Zhen Ren

    (Beijing University of Chemical Technology)

  • Yiming Niu

    (Chinese Academy of Sciences)

  • Bingsen Zhang

    (Chinese Academy of Sciences)

  • Lirong Zheng

    (Chinese Academy of Sciences)

  • Hong Yan

    (Beijing University of Chemical Technology)

  • Jian Zhang

    (Beijing University of Chemical Technology)

  • Feng-Shou Xiao

    (Beijing University of Chemical Technology
    Zhejiang University)

  • Min Wei

    (Beijing University of Chemical Technology)

  • Xue Duan

    (Beijing University of Chemical Technology)

Abstract

The metal-support interaction (MSI) in heterogeneous catalysts plays a crucial role in reforming reaction to produce renewable hydrogen, but conventional objects are limited to single metal and support. Herein, we report a type of RhNi/TiO2 catalysts with tunable RhNi-TiO2 strong bimetal-support interaction (SBMSI) derived from structure topological transformation of RhNiTi-layered double hydroxides (RhNiTi-LDHs) precursors. The resulting 0.5RhNi/TiO2 catalyst (with 0.5 wt.% Rh) exhibits extraordinary catalytic performance toward ethanol steam reforming (ESR) reaction with a H2 yield of 61.7%, a H2 production rate of 12.2 L h−1 gcat−1 and a high operational stability (300 h), which is preponderant to the state-of-the-art catalysts. By virtue of synergistic catalysis of multifunctional interface structure (Rh-Niδ−-Ov-Ti3+; Ov denotes oxygen vacancy), the generation of formate intermediate (the rate-determining step in ESR reaction) from steam reforming of CO and CHx is significantly promoted on 0.5RhNi/TiO2 catalyst, accounting for its ultra-high H2 production.

Suggested Citation

  • Hao Meng & Yusen Yang & Tianyao Shen & Wei Liu & Lei Wang & Pan Yin & Zhen Ren & Yiming Niu & Bingsen Zhang & Lirong Zheng & Hong Yan & Jian Zhang & Feng-Shou Xiao & Min Wei & Xue Duan, 2023. "A strong bimetal-support interaction in ethanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38883-x
    DOI: 10.1038/s41467-023-38883-x
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    References listed on IDEAS

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    1. Hui Wang & Guoqing Cui & Hao Lu & Zeyang Li & Lei Wang & Hao Meng & Jiong Li & Hong Yan & Yusen Yang & Min Wei, 2024. "Facilitating the dry reforming of methane with interfacial synergistic catalysis in an Ir@CeO2−x catalyst," Nature Communications, Nature, vol. 15(1), pages 1-10, December.

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