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Mapping structure heterogeneities and visualizing moisture degradation of perovskite films with nano-focus WAXS

Author

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  • Nian Li

    (Technische Universität München)

  • Shambhavi Pratap

    (Technische Universität München)

  • Volker Körstgens

    (Technische Universität München)

  • Sundeep Vema

    (Indian Institute of Technology Delhi
    Lensfield Road)

  • Lin Song

    (Northwestern Polytechnical University (NPU), Youyixilu 127)

  • Suzhe Liang

    (Technische Universität München)

  • Anton Davydok

    (Helmholtz-Zentrum Hereon, Max-Planck-Straße 1)

  • Christina Krywka

    (Helmholtz-Zentrum Hereon, Max-Planck-Straße 1)

  • Peter Müller-Buschbaum

    (Technische Universität München
    Technische Universität München)

Abstract

Extensive attention has focused on the structure optimization of perovskites, whereas rare research has mapped the structure heterogeneity within mixed hybrid perovskite films. Overlooked aspects include material and structure variations as a function of depth. These depth-dependent local structure heterogeneities dictate their long-term stabilities and efficiencies. Here, we use a nano-focused wide-angle X-ray scattering method for the mapping of film heterogeneities over several micrometers across lateral and vertical directions. The relative variations of characteristic perovskite peak positions show that the top film region bears the tensile strain. Through a texture orientation map of the perovskite (100) peak, we find that the perovskite grains deposited by sequential spray-coating grow along the vertical direction. Moreover, we investigate the moisture-induced degradation products in the perovskite film, and the underlying mechanism for its structure-dependent degradation. The moisture degradation along the lateral direction primarily initiates at the perovskite-air interface and grain boundaries. The tensile strain on the top surface has a profound influence on the moisture degradation.

Suggested Citation

  • Nian Li & Shambhavi Pratap & Volker Körstgens & Sundeep Vema & Lin Song & Suzhe Liang & Anton Davydok & Christina Krywka & Peter Müller-Buschbaum, 2022. "Mapping structure heterogeneities and visualizing moisture degradation of perovskite films with nano-focus WAXS," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34426-y
    DOI: 10.1038/s41467-022-34426-y
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    1. Makhsud I. Saidaminov & Junghwan Kim & Ankit Jain & Rafael Quintero-Bermudez & Hairen Tan & Guankui Long & Furui Tan & Andrew Johnston & Yicheng Zhao & Oleksandr Voznyy & Edward H. Sargent, 2018. "Suppression of atomic vacancies via incorporation of isovalent small ions to increase the stability of halide perovskite solar cells in ambient air," Nature Energy, Nature, vol. 3(8), pages 648-654, August.
    2. Renjun Guo & Dan Han & Wei Chen & Linjie Dai & Kangyu Ji & Qiu Xiong & Saisai Li & Lennart K. Reb & Manuel A. Scheel & Shambhavi Pratap & Nian Li & Shanshan Yin & Tianxiao Xiao & Suzhe Liang & Anna Le, 2021. "Degradation mechanisms of perovskite solar cells under vacuum and one atmosphere of nitrogen," Nature Energy, Nature, vol. 6(10), pages 977-986, October.
    3. Nam Joong Jeon & Jun Hong Noh & Woon Seok Yang & Young Chan Kim & Seungchan Ryu & Jangwon Seo & Sang Il Seok, 2015. "Compositional engineering of perovskite materials for high-performance solar cells," Nature, Nature, vol. 517(7535), pages 476-480, January.
    4. Alexander Z. Chen & Michelle Shiu & Jennifer H. Ma & Matthew R. Alpert & Depei Zhang & Benjamin J. Foley & Detlef-M. Smilgies & Seung-Hun Lee & Joshua J. Choi, 2018. "Origin of vertical orientation in two-dimensional metal halide perovskites and its effect on photovoltaic performance," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    5. Cheng Zhu & Xiuxiu Niu & Yuhao Fu & Nengxu Li & Chen Hu & Yihua Chen & Xin He & Guangren Na & Pengfei Liu & Huachao Zai & Yang Ge & Yue Lu & Xiaoxing Ke & Yang Bai & Shihe Yang & Pengwan Chen & Yujing, 2019. "Strain engineering in perovskite solar cells and its impacts on carrier dynamics," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    6. Shambhavi Pratap & Finn Babbe & Nicola S. Barchi & Zhenghao Yuan & Tina Luong & Zach Haber & Tze-Bin Song & Jonathan L. Slack & Camelia V. Stan & Nobumichi Tamura & Carolin M. Sutter-Fella & Peter Mül, 2021. "Out-of-equilibrium processes in crystallization of organic-inorganic perovskites during spin coating," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    7. Hsinhan Tsai & Wanyi Nie & Jean-Christophe Blancon & Constantinos C. Stoumpos & Reza Asadpour & Boris Harutyunyan & Amanda J. Neukirch & Rafael Verduzco & Jared J. Crochet & Sergei Tretiak & Laurent P, 2016. "High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells," Nature, Nature, vol. 536(7616), pages 312-316, August.
    8. Nicholas Aristidou & Christopher Eames & Irene Sanchez-Molina & Xiangnan Bu & Jan Kosco & M. Saiful Islam & Saif A. Haque, 2017. "Fast oxygen diffusion and iodide defects mediate oxygen-induced degradation of perovskite solar cells," Nature Communications, Nature, vol. 8(1), pages 1-10, August.
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