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Ultrastable and efficient slight-interlayer-displacement 2D Dion-Jacobson perovskite solar cells

Author

Listed:
  • Weichuan Zhang

    (National Center for Nanoscience and Technology
    University of South China
    University of Chinese Academy of Sciences)

  • Ziyuan Liu

    (National Center for Nanoscience and Technology, Chinese Academy of Sciences)

  • Lizhi Zhang

    (National Center for Nanoscience and Technology, Chinese Academy of Sciences)

  • Hui Wang

    (National Center for Nanoscience and Technology, Chinese Academy of Sciences)

  • Chuanxiu Jiang

    (University of Chinese Academy of Sciences
    National Center for Nanoscience and Technology)

  • Xianxin Wu

    (University of Chinese Academy of Sciences
    National Center for Nanoscience and Technology)

  • Chuanyun Li

    (National Center for Nanoscience and Technology
    Beijing Technology And Business University)

  • Shengli Yue

    (Beihang University)

  • Rongsheng Yang

    (National Center for Nanoscience and Technology)

  • Hong Zhang

    (National Center for Nanoscience and Technology)

  • Jianqi Zhang

    (National Center for Nanoscience and Technology)

  • Xinfeng Liu

    (University of Chinese Academy of Sciences
    National Center for Nanoscience and Technology)

  • Yuan Zhang

    (Beihang University)

  • Huiqiong Zhou

    (National Center for Nanoscience and Technology
    University of Chinese Academy of Sciences)

Abstract

Stability has been a long-standing concern for solution-processed perovskite photovoltaics and their practical applications. However, stable perovskite materials for photovoltaic remain insufficient to date. Here we demonstrate a series of ultrastable Dion−Jacobson (DJ) perovskites (1,4-cyclohexanedimethanammonium)(methylammonium)n−1PbnI3n+1 (n ≥ 1) for photovoltaic applications. The scalable technology by blade-coated solar cells for the designed DJ perovskites (nominal n = 5) achieves a maximum stabilized power conversion efficiency (PCE) of 19.11% under an environmental atmosphere. Un-encapsulated cells by blade-coated technology retain 92% of their initial efficiencies for over 4000 hours under ~90% relative humidity (RH) aging conditions. More importantly, these cells also exhibit remarkable thermal (85 °C) and operational stability, which shows negligible efficiency loss after exceeding 5000-hour heat treatment or after operation at maximum power point (MPP) exceeding 6000 hours at 45 °C under a 100 mW cm−2 continuous light illumination.

Suggested Citation

  • Weichuan Zhang & Ziyuan Liu & Lizhi Zhang & Hui Wang & Chuanxiu Jiang & Xianxin Wu & Chuanyun Li & Shengli Yue & Rongsheng Yang & Hong Zhang & Jianqi Zhang & Xinfeng Liu & Yuan Zhang & Huiqiong Zhou, 2024. "Ultrastable and efficient slight-interlayer-displacement 2D Dion-Jacobson perovskite solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-50018-4
    DOI: 10.1038/s41467-024-50018-4
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    References listed on IDEAS

    as
    1. Yang Yang & Jingbi You, 2017. "Make perovskite solar cells stable," Nature, Nature, vol. 544(7649), pages 155-156, April.
    2. Cheng Zhu & Xiuxiu Niu & Yuhao Fu & Nengxu Li & Chen Hu & Yihua Chen & Xin He & Guangren Na & Pengfei Liu & Huachao Zai & Yang Ge & Yue Lu & Xiaoxing Ke & Yang Bai & Shihe Yang & Pengwan Chen & Yujing, 2019. "Strain engineering in perovskite solar cells and its impacts on carrier dynamics," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    3. Hsinhan Tsai & Wanyi Nie & Jean-Christophe Blancon & Constantinos C. Stoumpos & Reza Asadpour & Boris Harutyunyan & Amanda J. Neukirch & Rafael Verduzco & Jared J. Crochet & Sergei Tretiak & Laurent P, 2016. "High-efficiency two-dimensional Ruddlesden–Popper perovskite solar cells," Nature, Nature, vol. 536(7616), pages 312-316, August.
    4. Yan Shao & Wei Gao & Hejin Yan & Runlai Li & Ibrahim Abdelwahab & Xiao Chi & Lukas Rogée & Lyuchao Zhuang & Wei Fu & Shu Ping Lau & Siu Fung Yu & Yongqing Cai & Kian Ping Loh & Kai Leng, 2022. "Unlocking surface octahedral tilt in two-dimensional Ruddlesden-Popper perovskites," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    5. Yeoun-Woo Jang & Seungmin Lee & Kyung Mun Yeom & Kiwan Jeong & Kwang Choi & Mansoo Choi & Jun Hong Noh, 2021. "Intact 2D/3D halide junction perovskite solar cells via solid-phase in-plane growth," Nature Energy, Nature, vol. 6(1), pages 63-71, January.
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