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Carbon-Supported Nickel Catalysts—Comparison in Alpha-Pinene Oxidation Activity

Author

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  • Adrianna Kamińska

    (Department of Catalytic and Sorbent Materials Engineering, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów Avenue 42, 71-065 Szczecin, Poland)

  • Joanna Sreńscek-Nazzal

    (Department of Catalytic and Sorbent Materials Engineering, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów Avenue 42, 71-065 Szczecin, Poland)

  • Karolina Kiełbasa

    (Department of Catalytic and Sorbent Materials Engineering, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów Avenue 42, 71-065 Szczecin, Poland)

  • Jadwiga Grzeszczak

    (Department of Catalytic and Sorbent Materials Engineering, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów Avenue 42, 71-065 Szczecin, Poland)

  • Jarosław Serafin

    (Department of Inorganic and Organic Chemistry, University of Barcelona, Martí i Franquès 1–11, 08028 Barcelona, Spain)

  • Agnieszka Wróblewska

    (Department of Catalytic and Sorbent Materials Engineering, Faculty of Chemical Technology and Engineering, West Pomeranian University of Technology in Szczecin, Piastów Avenue 42, 71-065 Szczecin, Poland)

Abstract

In this work, carbon-supported nickel catalysts with different Ni content (1, 2.5, 5, 10, and 20 wt%) were tested in the oxidation of alpha-pinene in solvent-free reaction conditions. The process of catalyst preparation consisted of two stages. In the first stage, the activated carbon from spent coffee grounds was obtained. In the second stage, the active phase in the form of nickel compounds was applied using two methods: (1) the impregnation of the material with the nickel salt solution, and next reduction in H 2 , and (2) the hydrothermal method in the autoclave using the reductor and the reaction stabilizer. The obtained catalysts were subjected to the following instrumental studies: FT-IR, XRD, SEM, and N 2 adsorption at −196 °C. The performed catalytic tests showed that the catalysts containing 5 wt% of Ni (porous material obtained by the impregnation method) and 1 wt% of Ni (porous material obtained by the hydrothermal method) were the most active in the oxidation of alpha-pinene, and the main oxidation products were alpha-pinene oxide, verbenol, and verbenone. Ultimately, the hydrothermal method of catalyst preparation turned out to be more advantageous because it allows one to obtain higher selectivities of the epoxide compound, probably due to the greater stability of this organic compound in pores.

Suggested Citation

  • Adrianna Kamińska & Joanna Sreńscek-Nazzal & Karolina Kiełbasa & Jadwiga Grzeszczak & Jarosław Serafin & Agnieszka Wróblewska, 2023. "Carbon-Supported Nickel Catalysts—Comparison in Alpha-Pinene Oxidation Activity," Sustainability, MDPI, vol. 15(6), pages 1-23, March.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:6:p:5317-:d:1099669
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    References listed on IDEAS

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    1. Md. Matiar Rahman & Mahbubul Muttakin & Animesh Pal & Abu Zar Shafiullah & Bidyut Baran Saha, 2019. "A Statistical Approach to Determine Optimal Models for IUPAC-Classified Adsorption Isotherms," Energies, MDPI, vol. 12(23), pages 1-34, November.
    2. Yahya, Mohd Adib & Al-Qodah, Z. & Ngah, C.W. Zanariah, 2015. "Agricultural bio-waste materials as potential sustainable precursors used for activated carbon production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 46(C), pages 218-235.
    3. Mussatto, Solange I. & Machado, Ercília M.S. & Carneiro, Lívia M. & Teixeira, José A., 2012. "Sugars metabolism and ethanol production by different yeast strains from coffee industry wastes hydrolysates," Applied Energy, Elsevier, vol. 92(C), pages 763-768.
    4. Danish, Mohammed & Ahmad, Tanweer, 2018. "A review on utilization of wood biomass as a sustainable precursor for activated carbon production and application," Renewable and Sustainable Energy Reviews, Elsevier, vol. 87(C), pages 1-21.
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