IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v12y2020i3p788-d311557.html
   My bibliography  Save this article

Charge Transfer in Mixed-Phase TiO 2 Photoelectrodes for Perovskite Solar Cells

Author

Listed:
  • Anna Nikolskaia

    (Solar Photovoltaic Laboratory, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia)

  • Marina Vildanova

    (Solar Photovoltaic Laboratory, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia)

  • Sergey Kozlov

    (Solar Photovoltaic Laboratory, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia)

  • Nikolai Tsvetkov

    (Solar Photovoltaic Laboratory, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia
    Department of Energy Environmental Water and Sustainability, Korea Advanced Institute of Science and Technology, Daejeon 305-701, Korea)

  • Liudmila Larina

    (Solar Photovoltaic Laboratory, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia
    Department of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 34134, Korea)

  • Oleg Shevaleevskiy

    (Solar Photovoltaic Laboratory, Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia)

Abstract

In mesoscopic perovskite solar cells (PSCs) the recombination processes within the TiO 2 photoelectrode and at the TiO 2 /perovskite interface limit power conversion efficiency. To overcome this challenge, we investigated the effect of TiO 2 phase composition on the electronic structure of TiO 2 photoelectrodes, as well as on PSCs performance. For this, a set of PSCs based on TiO 2 thin films with different content of anatase and rutile particles was fabricated under ambient conditions. X-ray diffraction, optical spectroscopy and scanning electron microscopy were used to study the structural, morphological and optical characteristics of TiO 2 powders and TiO 2 -based thin films. X-ray photoelectron spectroscopy (XPS) analysis of anatase revealed a cliff conduction band alignment of 0.2 eV with respect to the rutile. Energy band alignment at the anatase/rutile/perovskite interfaces deduced from the XPS data provides the possibility for interparticle electron transport from the rutile to anatase phase and the efficient blocking of electron recombination at the TiO 2 /perovskite interface, leading to efficient electron-hole separation in PSCs based on mixed-phase TiO 2 photoelectrodes. PSCs based on TiO 2 layers with 60/40 anatase/rutile ratio were characterized by optimized charge extraction and low level of recombination at the perovskite/TiO 2 interface and showed the best energy conversion efficiency of 13.4% among the studied PSCs. Obtained results provide a simple and effective approach towards the development of the next generation high efficiency PSCs.

Suggested Citation

  • Anna Nikolskaia & Marina Vildanova & Sergey Kozlov & Nikolai Tsvetkov & Liudmila Larina & Oleg Shevaleevskiy, 2020. "Charge Transfer in Mixed-Phase TiO 2 Photoelectrodes for Perovskite Solar Cells," Sustainability, MDPI, vol. 12(3), pages 1-14, January.
  • Handle: RePEc:gam:jsusta:v:12:y:2020:i:3:p:788-:d:311557
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/12/3/788/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/2071-1050/12/3/788/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Gong, Jiawei & Sumathy, K. & Qiao, Qiquan & Zhou, Zhengping, 2017. "Review on dye-sensitized solar cells (DSSCs): Advanced techniques and research trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 234-246.
    2. Nam-Gyu Park & Michael Grätzel & Tsutomu Miyasaka & Kai Zhu & Keith Emery, 2016. "Towards stable and commercially available perovskite solar cells," Nature Energy, Nature, vol. 1(11), pages 1-8, November.
    3. Hosenuzzaman, M. & Rahim, N.A. & Selvaraj, J. & Hasanuzzaman, M. & Malek, A.B.M.A. & Nahar, A., 2015. "Global prospects, progress, policies, and environmental impact of solar photovoltaic power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 284-297.
    4. Panwar, N.L. & Kaushik, S.C. & Kothari, Surendra, 2011. "Role of renewable energy sources in environmental protection: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1513-1524, April.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Alessandro Cannavale & Francesco Martellotta & Francesco Fiorito & Ubaldo Ayr, 2020. "The Challenge for Building Integration of Highly Transparent Photovoltaics and Photoelectrochromic Devices," Energies, MDPI, vol. 13(8), pages 1-24, April.
    2. Husain, Alaa A.F. & Hasan, Wan Zuha W. & Shafie, Suhaidi & Hamidon, Mohd N. & Pandey, Shyam Sudhir, 2018. "A review of transparent solar photovoltaic technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 779-791.
    3. Firozjaei, Mohammad Karimi & Nematollahi, Omid & Mijani, Naeim & Shorabeh, Saman Nadizadeh & Firozjaei, Hamzeh Karimi & Toomanian, Ara, 2019. "An integrated GIS-based Ordered Weighted Averaging analysis for solar energy evaluation in Iran: Current conditions and future planning," Renewable Energy, Elsevier, vol. 136(C), pages 1130-1146.
    4. Mesquita, Isabel & Andrade, Luísa & Mendes, Adélio, 2018. "Perovskite solar cells: Materials, configurations and stability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2471-2489.
    5. Shahsavari, Amir & Akbari, Morteza, 2018. "Potential of solar energy in developing countries for reducing energy-related emissions," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 275-291.
    6. Sebestyén, Viktor, 2021. "Renewable and Sustainable Energy Reviews: Environmental impact networks of renewable energy power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    7. Suman, A., 2021. "Role of renewable energy technologies in climate change adaptation and mitigation: A brief review from Nepal," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    8. Abbas, Sajid & Yuan, Yanping & Zhou, Jinzhi & Hassan, Atazaz & Yu, Min & Yasheng, Ji, 2022. "Experimental and analytical analysis of the impact of different base plate materials and design parameters on the performance of the photovoltaic/thermal system," Renewable Energy, Elsevier, vol. 187(C), pages 522-536.
    9. Mollik, Sazib & Rashid, M.M. & Hasanuzzaman, M. & Karim, M.E. & Hosenuzzaman, M., 2016. "Prospects, progress, policies, and effects of rural electrification in Bangladesh," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 553-567.
    10. Wenran Gao & Hui Li & Karnowo & Bing Song & Shu Zhang, 2020. "Integrated Leaching and Thermochemical Technologies for Producing High-Value Products from Rice Husk: Leaching of Rice Husk with the Aqueous Phases of Bioliquids," Energies, MDPI, vol. 13(22), pages 1-15, November.
    11. Mahtta, Richa & Joshi, P.K. & Jindal, Alok Kumar, 2014. "Solar power potential mapping in India using remote sensing inputs and environmental parameters," Renewable Energy, Elsevier, vol. 71(C), pages 255-262.
    12. Karatayev, Marat & Clarke, Michèle L., 2016. "A review of current energy systems and green energy potential in Kazakhstan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 491-504.
    13. Hosseini, Seyed Ehsan & Wahid, Mazlan Abdul, 2014. "Development of biogas combustion in combined heat and power generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 40(C), pages 868-875.
    14. Kannan, Nadarajah & Vakeesan, Divagar, 2016. "Solar energy for future world: - A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1092-1105.
    15. Dey, Subhashish & Sreenivasulu, Anduri & Veerendra, G.T.N. & Rao, K. Venkateswara & Babu, P.S.S. Anjaneya, 2022. "Renewable energy present status and future potentials in India: An overview," Innovation and Green Development, Elsevier, vol. 1(1).
    16. Grafström, Jonas & Poudineh, Rahmat, 2023. "No evidence of counteracting policy effects on European solar power invention and diffusion," Energy Policy, Elsevier, vol. 172(C).
    17. Aikifa Raza & Jin-You Lu & Safa Alzaim & Hongxia Li & TieJun Zhang, 2018. "Novel Receiver-Enhanced Solar Vapor Generation: Review and Perspectives," Energies, MDPI, vol. 11(1), pages 1-29, January.
    18. Peng Zhang & Huibin Sui, 2020. "Maximum Power Point Tracking Technology of Photovoltaic Array under Partial Shading Based On Adaptive Improved Differential Evolution Algorithm," Energies, MDPI, vol. 13(5), pages 1-15, March.
    19. Sofia Dahlgren & Jonas Ammenberg, 2021. "Sustainability Assessment of Public Transport, Part II—Applying a Multi-Criteria Assessment Method to Compare Different Bus Technologies," Sustainability, MDPI, vol. 13(3), pages 1-30, January.
    20. Gao, Chunjiao & Chen, Hongxi, 2023. "Electricity from renewable energy resources: Sustainable energy transition and emissions for developed economies," Utilities Policy, Elsevier, vol. 82(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:12:y:2020:i:3:p:788-:d:311557. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.