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Investigation into the Catalytic Activity of Microporous and Mesoporous Catalysts in the Pyrolysis of Waste Polyethylene and Polypropylene Mixture

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  • Kaixin Li

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore
    School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, Singapore)

  • Shao Wee Lee

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore)

  • Guoan Yuan

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore)

  • Junxi Lei

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore)

  • Shengxuan Lin

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore)

  • Piyarat Weerachanchai

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore)

  • Yanhui Yang

    (School of Chemical and Biomedical Engineering, Nanyang Technological University, Singapore 637459, Singapore)

  • Jing-Yuan Wang

    (Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore)

Abstract

Catalytic pyrolysis behavior of synthesized microporous catalysts (conventional Zeolite Socony Mobil–5 (C-ZSM-5), highly uniform nanocrystalline ZSM-5 (HUN-ZSM-5) and β-zeolite), Mesoporous catalysts (highly hydrothermally stable Al-MCM-41 with accessible void defects (Al-MCM-41(hhs)), Kanemite-derived folded silica (KFS-16B) and well-ordered Al-SBA-15 (Al-SBA-15(wo)) were studied with waste polyethylene (PE) and polypropylene (PP) mixture which are the main constituents in municipal solid waste. All the catalysts were characterized by Brunauer-Emmett-Teller (BET), X-ray powder diffraction (XRD), and NH3-temperature programmed desorption (TPD). The results demonstrated that microporous catalysts exhibited high yields of gas products and high selectivity for aromatics and alkene, whereas the mesoporous catalysts showed high yields of liquid products with considerable amounts of aliphatic compounds. The differences between the microporous and mesoporous catalysts could be attributed to their characteristic acidic and textural properties. A significant amount of C2–C4 gases were produced from both types of catalysts. The composition of the liquid and gas products from catalytic pyrolysis is similar to petroleum-derived fuels. In other words, products of catalytic pyrolysis of plastic waste can be potential alternatives to the petroleum-derived fuels.

Suggested Citation

  • Kaixin Li & Shao Wee Lee & Guoan Yuan & Junxi Lei & Shengxuan Lin & Piyarat Weerachanchai & Yanhui Yang & Jing-Yuan Wang, 2016. "Investigation into the Catalytic Activity of Microporous and Mesoporous Catalysts in the Pyrolysis of Waste Polyethylene and Polypropylene Mixture," Energies, MDPI, vol. 9(6), pages 1-15, June.
    • Handle: RePEc:gam:jeners:v:9:y:2016:i:6:p:431-:d:71548
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    References listed on IDEAS

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    1. Panda, Achyut K. & Singh, R.K. & Mishra, D.K., 2010. "Thermolysis of waste plastics to liquid fuel: A suitable method for plastic waste management and manufacture of value added products--A world prospective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 233-248, January.
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    Cited by:

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    3. Munir, Dureem & Irfan, Muhammad F. & Usman, Muhammad R., 2018. "Hydrocracking of virgin and waste plastics: A detailed review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 490-515.
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    9. Tan, Kai Qi & Ahmad, Mohd Azmier & Oh, Wen Da & Low, Siew Chun, 2023. "Valorization of hazardous plastic wastes into value-added resources by catalytic pyrolysis-gasification: A review of techno-economic analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).

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