IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v5y2012i12p5418-5438d22331.html
   My bibliography  Save this article

Fuel-N Evolution during the Pyrolysis of Industrial Biomass Wastes with High Nitrogen Content

Author

Listed:
  • Hongfang Chen

    (Department of Environmental Science and Technology, Tokyo Institute of Technology, G5-8, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan)

  • Yin Wang

    (Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China)

  • Guangwen Xu

    (Institute of Process Engineering, Chinese Academy of Sciences, No. 1 Zhongguancun North Second Street, Beijing 100190, China)

  • Kunio Yoshikawa

    (Department of Environmental Science and Technology, Tokyo Institute of Technology, G5-8, 4259 Nagatsuta, Midori-ku, Yokohama 226-8502, Japan)

Abstract

In this study, sewage sludge and mycelial waste from antibiotic production were pyrolyzed in a batch scale fixed-bed reactor as examples of two kinds of typical industrial biomass wastes with high nitrogen content. A series of experiments were conducted on the rapid pyrolysis and the slow pyrolysis of these wastes in the temperature range from 500–800 °C to investigate the Fuel-N transformation behavior among pyrolysis products. The results showed that Fuel-N conversion to Char-N intimately depended on the pyrolysis temperature and the yield of Char-N reduced with the increase of the pyrolysis temperature . Under the same pyrolysis conditions, Tar-N production mainly depended on complex properties of the different biomasses, including volatile matter, nitrogen content and biomass functional groups. HCN was the predominant NO x precursor in the rapid pyrolysis of biomass, whereas in the slow pyrolysis of mycelial waste, more NH 3 was produced than HCN due to the additional NH 3 formation through the hydrogenation reaction of Char-N, HCN and H radicals. At the same time, some part of the char was analyzed by Fourier Transform infrared spectroscopy (FTIR) to get more information on the nitrogen functionality changes and the tar was also characterized by Gas Chromatography and Mass Spectrometry (GCMS) to identify typical nitrogenous tar compounds. Finally, the whole nitrogen distribution in products was discussed.

Suggested Citation

  • Hongfang Chen & Yin Wang & Guangwen Xu & Kunio Yoshikawa, 2012. "Fuel-N Evolution during the Pyrolysis of Industrial Biomass Wastes with High Nitrogen Content," Energies, MDPI, vol. 5(12), pages 1-21, December.
    • Handle: RePEc:gam:jeners:v:5:y:2012:i:12:p:5418-5438:d:22331
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/5/12/5418/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/5/12/5418/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Chen, Hongfang & Namioka, Tomoaki & Yoshikawa, Kunio, 2011. "Characteristics of tar, NOx precursors and their absorption performance with different scrubbing solvents during the pyrolysis of sewage sludge," Applied Energy, Elsevier, vol. 88(12), pages 5032-5041.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Jianqiang Zhou & Pan Gao & Changqing Dong & Yongping Yang, 2018. "Effect of Temperature and Mineral Matter on the Formation of NOx Precursors during Fast Pyrolysis of 2,5-Diketopiperazine," Energies, MDPI, vol. 11(3), pages 1-10, March.
    2. Xiaorui Liu & Zhongyang Luo & Chunjiang Yu & Bitao Jin & Hanchao Tu, 2018. "Release Mechanism of Fuel-N into NO x and N 2 O Precursors during Pyrolysis of Rice Straw," Energies, MDPI, vol. 11(3), pages 1-13, February.
    3. Zhan, Hao & Zhuang, Xiuzheng & Song, Yanpei & Yin, Xiuli & Wu, Chuangzhi, 2018. "Insights into the evolution of fuel-N to NOx precursors during pyrolysis of N-rich nonlignocellulosic biomass," Applied Energy, Elsevier, vol. 219(C), pages 20-33.
    4. Benítez, Almudena & Amaro-Gahete, Juan & Chien, Yu-Chuan & Caballero, Álvaro & Morales, Julián & Brandell, Daniel, 2022. "Recent advances in lithium-sulfur batteries using biomass-derived carbons as sulfur host," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    5. Zhao, Peitao & Shen, Yafei & Ge, Shifu & Chen, Zhenqian & Yoshikawa, Kunio, 2014. "Clean solid biofuel production from high moisture content waste biomass employing hydrothermal treatment," Applied Energy, Elsevier, vol. 131(C), pages 345-367.
    6. Evangelopoulos, Panagiotis & Kantarelis, Efthymios & Yang, Weihong, 2017. "Experimental investigation of the influence of reaction atmosphere on the pyrolysis of printed circuit boards," Applied Energy, Elsevier, vol. 204(C), pages 1065-1073.
    7. Cao, Songshan & Duan, Feng & Wang, Ping & Chyang, ChienSong, 2018. "Biochar contribution in biomass reburning technology and transformation mechanism of its nitrogen foundational groups at different oxygen contents," Energy, Elsevier, vol. 155(C), pages 272-280.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Unyaphan, Siriwat & Tarnpradab, Thanyawan & Takahashi, Fumitake & Yoshikawa, Kunio, 2017. "Improvement of tar removal performance of oil scrubber by producing syngas microbubbles," Applied Energy, Elsevier, vol. 205(C), pages 802-812.
    2. Luo, Lei & Zhang, Hai & Jiao, Anyao & Jiang, Yuanzhen & Liu, Jiaxun & Jiang, Xiumin & Tian, Feng, 2019. "Study on the formation and dissipation mechanism of gas phase products during rapid pyrolysis of superfine pulverized coal in entrained flow reactor," Energy, Elsevier, vol. 173(C), pages 985-994.
    3. Fang, Neng & Li, Zhengqi & Xie, Cheng & Liu, Shuxuan & Lu, Yue & Zeng, Lingyan & Chen, Zhichao, 2021. "Influence of the multi-burner bias angle on the air/particle flow characteristics in an improved fly ash entrained-flow gasifier," Energy, Elsevier, vol. 234(C).
    4. Fang, Shiwen & Deng, Zhengbing & Lin, Yan & Huang, Zhen & Ding, Lixing & Deng, Lisheng & Huang, Hongyu, 2021. "Nitrogen migration in sewage sludge chemical looping gasification using copper slag modified by NiO as an oxygen carrier," Energy, Elsevier, vol. 228(C).
    5. Chen, Hui & Chen, Dezhen & Hong, Liu, 2015. "Influences of activation agent impregnated sewage sludge pyrolysis on emission characteristics of volatile combustion and De-NOx performance of activated char," Applied Energy, Elsevier, vol. 156(C), pages 767-775.
    6. Li, Chenlin & Aston, John E. & Lacey, Jeffrey A. & Thompson, Vicki S. & Thompson, David N., 2016. "Impact of feedstock quality and variation on biochemical and thermochemical conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 65(C), pages 525-536.
    7. Ren, Qiangqiang & Zhao, Changsui, 2013. "NOx and N2O precursors (NH3 and HCN) from biomass pyrolysis: interaction between amino acid and mineral matter," Applied Energy, Elsevier, vol. 112(C), pages 170-174.
    8. Fang, Neng & Li, Zhengqi & Xie, Cheng & Liu, Shuxuan & Zeng, Lingyan & Chen, Zhichao & Zhang, Bin, 2020. "The application of fly ash gasification for purifying the raw syngas in an industrial-scale entrained flow gasifier," Energy, Elsevier, vol. 195(C).
    9. Zeng, Xi & Wang, Fang & Li, Hongling & Wang, Yin & Dong, Li & Yu, Jian & Xu, Guangwen, 2014. "Pilot verification of a low-tar two-stage coal gasification process with a fluidized bed pyrolyzer and fixed bed gasifier," Applied Energy, Elsevier, vol. 115(C), pages 9-16.
    10. Shen, Yafei & Wang, Junfeng & Ge, Xinlei & Chen, Mindong, 2016. "By-products recycling for syngas cleanup in biomass pyrolysis – An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 1246-1268.
    11. Hu, Fu-Xiang & Yang, Guo-Hua & Ding, Guo-Zhu & Li, Zhen & Du, Ka-Shuai & Hu, Zhi-Fa & Tian, Su-Rui, 2016. "Experimental study on catalytic cracking of model tar compounds in a dual layer granular bed filter," Applied Energy, Elsevier, vol. 170(C), pages 47-57.
    12. Zhan, Hao & Zhuang, Xiuzheng & Song, Yanpei & Yin, Xiuli & Wu, Chuangzhi, 2018. "Insights into the evolution of fuel-N to NOx precursors during pyrolysis of N-rich nonlignocellulosic biomass," Applied Energy, Elsevier, vol. 219(C), pages 20-33.
    13. Zheng, Anqing & Li, Luwei & Tippayawong, Nakorn & Huang, Zhen & Zhao, Kun & Wei, Guoqiang & Zhao, Zengli & Li, Haibin, 2020. "Reducing emission of NOx and SOx precursors while enhancing char production from pyrolysis of sewage sludge by torrefaction pretreatment," Energy, Elsevier, vol. 192(C).
    14. Jianqiang Zhou & Pan Gao & Changqing Dong & Yongping Yang, 2018. "Effect of Temperature and Mineral Matter on the Formation of NOx Precursors during Fast Pyrolysis of 2,5-Diketopiperazine," Energies, MDPI, vol. 11(3), pages 1-10, March.
    15. Sever Akdağ, Ayşe & Atak, Onur & Atimtay, Aysel T. & Sanin, Faika Dilek, 2018. "Co-combustion of sewage sludge from different treatment processes and a lignite coal in a laboratory scale combustor," Energy, Elsevier, vol. 158(C), pages 417-426.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:5:y:2012:i:12:p:5418-5438:d:22331. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.