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Transition Metal Carbides and Nitrides as Electrode Materials for Low Temperature Fuel Cells

Author

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  • Dong Jin Ham

    (Eco-friendly Catalysis and Energy Laboratory (NRL), Department of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, Korea)

  • Jae Sung Lee

    (Eco-friendly Catalysis and Energy Laboratory (NRL), Department of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, Korea)

Abstract

Transition metal carbides (TMCs) and transition metal nitrides (TMNs) have attracted attention as promising electrocatalysts that could replace noble metals of high price and limited supply. Relative to parent metals, TMC and TMN behave like noble metals for electrochemical reactions such as oxidation of hydrogen, CO and alcohols, and reduction of oxygen. When TMC and TMN are combined with other metals, the electrocatalytic synergy is often observed in electrochemical reactions. Thus, combinations with a minute amount of Pt or even non-Pt metals give performance comparable to heavily loaded Pt-based electrocatalysts for low temperature fuel cells. It appears that TMC based electrocatalysts are more active as anode catalysts for oxidation of fuels, whereas TMN based catalysts are more active for cathode catalysts for oxygen reduction and more stable.

Suggested Citation

  • Dong Jin Ham & Jae Sung Lee, 2009. "Transition Metal Carbides and Nitrides as Electrode Materials for Low Temperature Fuel Cells," Energies, MDPI, vol. 2(4), pages 1-27, October.
    • Handle: RePEc:gam:jeners:v:2:y:2009:i:4:p:873-899:d:5929
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    References listed on IDEAS

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    1. Sang Hoon Joo & Seong Jae Choi & Ilwhan Oh & Juhyoun Kwak & Zheng Liu & Osamu Terasaki & Ryong Ryoo, 2001. "Correction: Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles," Nature, Nature, vol. 414(6862), pages 470-470, November.
    2. Brian C. H. Steele & Angelika Heinzel, 2001. "Materials for fuel-cell technologies," Nature, Nature, vol. 414(6861), pages 345-352, November.
    3. Sang Hoon Joo & Seong Jae Choi & Ilwhan Oh & Juhyoun Kwak & Zheng Liu & Osamu Terasaki & Ryong Ryoo, 2001. "Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles," Nature, Nature, vol. 412(6843), pages 169-172, July.
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    2. Maria H. de Sá & Catarina S. Moreira & Alexandra M. F. R. Pinto & Vânia B. Oliveira, 2022. "Recent Advances in the Development of Nanocatalysts for Direct Methanol Fuel Cells," Energies, MDPI, vol. 15(17), pages 1-47, August.

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