IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v17y2024i21p5439-d1510976.html
   My bibliography  Save this article

Hydrothermal Liquefaction of Sugarcane Bagasse and Straw: Effect of Operational Conditions on Product Fractionation and Bio-Oil Composition

Author

Listed:
  • Raquel Santos Silva

    (Department of Chemical Engineering, Federal University of Pernambuco, Av. dos Economistas, s/n, Recife 50740-590, Brazil
    Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil)

  • Reinaldo Alves da Silva

    (Department of Chemical Engineering, Federal University of Pernambuco, Av. dos Economistas, s/n, Recife 50740-590, Brazil
    Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil)

  • Flávio Montenegro de Andrade

    (Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil
    Department of Fundamental Chemistry, Federal University of Pernambuco, Av. Jorn. Aníbal Fernandes, s/n, Recife 50740-560, Brazil)

  • Pedro Nunes Acácio Neto

    (Department of Chemical Engineering, Federal University of Pernambuco, Av. dos Economistas, s/n, Recife 50740-590, Brazil
    Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil)

  • Rayane Maria do Nascimento

    (Department of Chemistry, Federal Rural University of Pernambuco, Rua Manuel de Medeiros, s/n, Recife 52171-900, Brazil)

  • Jandyson Machado Santos

    (Department of Chemistry, Federal Rural University of Pernambuco, Rua Manuel de Medeiros, s/n, Recife 52171-900, Brazil)

  • Luiz Stragevitch

    (Department of Chemical Engineering, Federal University of Pernambuco, Av. dos Economistas, s/n, Recife 50740-590, Brazil
    Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil)

  • Maria Fernanda Pimentel

    (Department of Chemical Engineering, Federal University of Pernambuco, Av. dos Economistas, s/n, Recife 50740-590, Brazil
    Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil)

  • Diogo Ardaillon Simoes

    (Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil
    Department of Biochemistry, Federal University of Pernambuco, Av. Reitor Joaquim Amazonas, s/n, Recife 50740-570, Brazil)

  • Leandro Danielski

    (Department of Chemical Engineering, Federal University of Pernambuco, Av. dos Economistas, s/n, Recife 50740-590, Brazil
    Fuel Laboratory (LAC), Institute for Petroleum and Energy Research (i-LITPEG), Federal University of Pernambuco, Av. da Arquitetura, s/n, Recife 50740-550, Brazil)

Abstract

In the energy transition process, aiming for zero disposal and clean production in the elimination of waste is crucial; consequently, agricultural residues have significant potential for reduction in the use of fossil fuels. This study investigates the hydrothermal liquefaction (HTL) of sugarcane bagasse (BSC) and straw (SSC), examining the products’ distribution and bio-oil composition relative to the reaction conditions. The experiments used a 2 3 factorial design, evaluating the temperature (300–350 °C), constant heating time (0–30 min), and the use of the K 2 CO 3 concentration as the catalyst (0–0.5 mol/L −1 ). The main factor affecting the biocrude yield from BSC and SSC was the use of K 2 CO 3 . Statistically significant interaction effects were also observed. Milder conditions resulted in the highest bio-oil yields, 36% for BSC and 31% for SSC. The catalyst had no impact on the biocrude production. The bio-oils were analyzed by GC/MS and FTIR; a principal component analysis (PCA) was performed to evaluate the samples’ variability. The FTIR highlighted bands associated with common oxygenated compounds in lignocellulosic biomass-derived bio-oils. The GC-MS results indicated a predominance of oxygenated compounds, and these were highest in the presence of the catalyst for both the BSC (90.6%) and SSC (91.7%) bio-oils. The SSC bio-oils presented higher oxygenated compound contents than the BSC bio-oils. Statistical analysis provided valuable insights for optimizing biomass conversion processes, such as determining the optimal conditions for maximizing product yields.

Suggested Citation

  • Raquel Santos Silva & Reinaldo Alves da Silva & Flávio Montenegro de Andrade & Pedro Nunes Acácio Neto & Rayane Maria do Nascimento & Jandyson Machado Santos & Luiz Stragevitch & Maria Fernanda Piment, 2024. "Hydrothermal Liquefaction of Sugarcane Bagasse and Straw: Effect of Operational Conditions on Product Fractionation and Bio-Oil Composition," Energies, MDPI, vol. 17(21), pages 1-17, October.
    • Handle: RePEc:gam:jeners:v:17:y:2024:i:21:p:5439-:d:1510976
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/17/21/5439/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/17/21/5439/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.
    2. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    3. Gan, Jing & Yuan, Wenqiao, 2013. "Operating condition optimization of corncob hydrothermal conversion for bio-oil production," Applied Energy, Elsevier, vol. 103(C), pages 350-357.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Brand, Steffen & Kim, Jaehoon, 2015. "Liquefaction of major lignocellulosic biomass constituents in supercritical ethanol," Energy, Elsevier, vol. 80(C), pages 64-74.
    2. Knez, Ž. & Markočič, E. & Leitgeb, M. & Primožič, M. & Knez Hrnčič, M. & Škerget, M., 2014. "Industrial applications of supercritical fluids: A review," Energy, Elsevier, vol. 77(C), pages 235-243.
    3. Ankit Mathanker & Snehlata Das & Deepak Pudasainee & Monir Khan & Amit Kumar & Rajender Gupta, 2021. "A Review of Hydrothermal Liquefaction of Biomass for Biofuels Production with a Special Focus on the Effect of Process Parameters, Co-Solvents, and Extraction Solvents," Energies, MDPI, vol. 14(16), pages 1-60, August.
    4. Prajitno, Hermawan & Park, Jongkeun & Ryu, Changkook & Park, Ho Young & Lim, Hyun Soo & Kim, Jaehoon, 2018. "Effects of solvent participation and controlled product separation on biomass liquefaction: A case study of sewage sludge," Applied Energy, Elsevier, vol. 218(C), pages 402-416.
    5. Isa, Khairuddin Md & Abdullah, Tuan Amran Tuan & Ali, Umi Fazara Md, 2018. "Hydrogen donor solvents in liquefaction of biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 1259-1268.
    6. Hardi, Flabianus & Mäkelä, Mikko & Yoshikawa, Kunio, 2017. "Non-catalytic hydrothermal liquefaction of pine sawdust using experimental design: Material balances and products analysis," Applied Energy, Elsevier, vol. 204(C), pages 1026-1034.
    7. Manaenkov, Oleg V. & Ratkevich, Ekaterina A. & Kislitsa, Olga V. & Lawson, Bret & Morgan, David Gene & Stepacheva, Antonina A. & Matveeva, Valentina G. & Sulman, Mikhail G. & Sulman, Esther M. & Brons, 2018. "Magnetically recoverable catalysts for the conversion of inulin to mannitol," Energy, Elsevier, vol. 154(C), pages 1-6.
    8. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    9. Wang, Liping & Chang, Yuzhi & Li, Aimin, 2019. "Hydrothermal carbonization for energy-efficient processing of sewage sludge: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 423-440.
    10. Muhammad Usman & Shuo Cheng & Sasipa Boonyubol & Jeffrey S. Cross, 2023. "Evaluating Green Solvents for Bio-Oil Extraction: Advancements, Challenges, and Future Perspectives," Energies, MDPI, vol. 16(15), pages 1-45, August.
    11. Ong, Benjamin H.Y. & Walmsley, Timothy G. & Atkins, Martin J. & Varbanov, Petar S. & Walmsley, Michael R.W., 2019. "A heat- and mass-integrated design of hydrothermal liquefaction process co-located with a Kraft pulp mill," Energy, Elsevier, vol. 189(C).
    12. Marwa G. Saad & Noura S. Dosoky & Mohamed S. Zoromba & Hesham M. Shafik, 2019. "Algal Biofuels: Current Status and Key Challenges," Energies, MDPI, vol. 12(10), pages 1-22, May.
    13. Karaca, Hüseyin. & Koyunoğlu, Cemil & Özdemir, Ali & Ergun, Kenan, 2019. "Co-processing behavior of Gölbaşı lignite and poplar sawdust by factorial experimental design method," Energy, Elsevier, vol. 183(C), pages 1040-1048.
    14. Zhuang, Xiuzheng & Liu, Jianguo & Zhang, Qi & Wang, Chenguang & Zhan, Hao & Ma, Longlong, 2022. "A review on the utilization of industrial biowaste via hydrothermal carbonization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    15. Chen, Wan-Ting & Zhang, Yuanhui & Zhang, Jixiang & Schideman, Lance & Yu, Guo & Zhang, Peng & Minarick, Mitchell, 2014. "Co-liquefaction of swine manure and mixed-culture algal biomass from a wastewater treatment system to produce bio-crude oil," Applied Energy, Elsevier, vol. 128(C), pages 209-216.
    16. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    17. Jiaao Zhu & Yun Guo & Na Chen & Baoming Chen, 2024. "A Review of the Efficient and Thermal Utilization of Biomass Waste," Sustainability, MDPI, vol. 16(21), pages 1-30, October.
    18. Liu, Xiang & Chen, Meiqian & Wei, Yuanhang, 2016. "Assessment on oxygen enriched air co-combustion performance of biomass/bituminous coal," Renewable Energy, Elsevier, vol. 92(C), pages 428-436.
    19. Déniel, Maxime & Haarlemmer, Geert & Roubaud, Anne & Weiss-Hortala, Elsa & Fages, Jacques, 2016. "Energy valorisation of food processing residues and model compounds by hydrothermal liquefaction," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 1632-1652.
    20. Thiruvenkadam, Selvakumar & Izhar, Shamsul & Yoshida, Hiroyuki & Danquah, Michael K. & Harun, Razif, 2015. "Process application of Subcritical Water Extraction (SWE) for algal bio-products and biofuels production," Applied Energy, Elsevier, vol. 154(C), pages 815-828.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:17:y:2024:i:21:p:5439-:d:1510976. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.