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Magnetically recoverable catalysts for the conversion of inulin to mannitol

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  • Manaenkov, Oleg V.
  • Ratkevich, Ekaterina A.
  • Kislitsa, Olga V.
  • Lawson, Bret
  • Morgan, David Gene
  • Stepacheva, Antonina A.
  • Matveeva, Valentina G.
  • Sulman, Mikhail G.
  • Sulman, Esther M.
  • Bronstein, Lyudmila M.

Abstract

Inulin is a naturally occurring polysaccharide, widely available as plant biomass. Here, we report utilization of a magnetically separable Ru-containing catalyst based on magnetic silica (Fe3O4-SiO2) in the inulin hydrolytic hydrogenation to mannitol (a sweetener used in diabetic foods). The influence of the reaction parameters on the selectivity to mannitol has been studied. Under the optimal conditions the maximum selectivity to mannitol reached 44.3% at 100% conversion of the initial polysaccharide, exceeding that obtained with conventional Ru/C. The catalyst used in this work is stable under hydrothermal conditions of the process. It can be easily magnetically separated from the reaction mixture and reused without any loss of selectivity and activity, making this catalyst promising for practical applications in biomass conversion.

Suggested Citation

  • Manaenkov, Oleg V. & Ratkevich, Ekaterina A. & Kislitsa, Olga V. & Lawson, Bret & Morgan, David Gene & Stepacheva, Antonina A. & Matveeva, Valentina G. & Sulman, Mikhail G. & Sulman, Esther M. & Brons, 2018. "Magnetically recoverable catalysts for the conversion of inulin to mannitol," Energy, Elsevier, vol. 154(C), pages 1-6.
    • Handle: RePEc:eee:energy:v:154:y:2018:i:c:p:1-6
    DOI: 10.1016/j.energy.2018.04.103
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    References listed on IDEAS

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    1. Brand, Steffen & Susanti, Ratna Frida & Kim, Seok Ki & Lee, Hong-shik & Kim, Jaehoon & Sang, Byung-In, 2013. "Supercritical ethanol as an enhanced medium for lignocellulosic biomass liquefaction: Influence of physical process parameters," Energy, Elsevier, vol. 59(C), pages 173-182.
    2. Paixão, Susana M. & Alves, Luís & Pacheco, Rui & Silva, Carla M., 2018. "Evaluation of Jerusalem artichoke as a sustainable energy crop to bioethanol: energy and CO2eq emissions modeling for an industrial scenario," Energy, Elsevier, vol. 150(C), pages 468-481.
    3. Toor, Saqib Sohail & Rosendahl, Lasse & Rudolf, Andreas, 2011. "Hydrothermal liquefaction of biomass: A review of subcritical water technologies," Energy, Elsevier, vol. 36(5), pages 2328-2342.
    4. Brand, Steffen & Hardi, Flabianus & Kim, Jaehoon & Suh, Dong Jin, 2014. "Effect of heating rate on biomass liquefaction: Differences between subcritical water and supercritical ethanol," Energy, Elsevier, vol. 68(C), pages 420-427.
    5. Alva, Guruprasad & Lin, Yaxue & Fang, Guiyin, 2018. "An overview of thermal energy storage systems," Energy, Elsevier, vol. 144(C), pages 341-378.
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