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Effect of low-temperature catalytic hydrothermal liquefaction of Spirulina platensis

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  • Kandasamy, Sabariswaran
  • Zhang, Bo
  • He, Zhixia
  • Chen, Haitao
  • Feng, Huan
  • Wang, Qian
  • Wang, Bin
  • Ashokkumar, Veeramuthu
  • Siva, Subramanian
  • Bhuvanendran, Narayanamoorthy
  • Krishnamoorthi, M.

Abstract

In this work, the cerium oxide (CeO2) nanocatalyst was employed as a catalyst to enhance the hydrothermal liquefaction (HTL) of microalgae to bio-oil conversion. The HTL optimized parameters were obtained from response surface methodology (RSM). The Spirulina Platensis is blue-green algae were used to convert into bio-oil. The major processing method for bio-oil conversion was designed based on three key parameters, such as temperature, residence time and catalyst concentration. A remarkable enhancement of bio-oil production was observed for 0.20 g of CeO2 catalyzed HTL at 250 °C for 30 min, and around 26% of conversion was achieved which is higher than catalyst-free HTL reaction (16%). The synthetic CeO2 nanostructure was characterized using scanning electron microscopy (SEM), field emission scanning electron microscopy (FE-SEM), high-resolution transmission electron microscopy (HR-TEM), brunauer-emmett-teller surface area (BET), X-ray powder diffraction (XRD) and thermal gravimetric analysis (TGA). The chemical composition of bio-oil was analyzed by gas chromatography-mass spectrometry (GC-MS) and the functional group analysis was done using fourier transform-infra red spectroscopy (FT-IR). The obtained results clearly reveal that the major chemical constituents such as hydrocarbons (7.55%), amino acids (36.69%) and nitrogen compounds (21.58%) for the bio-oil increased during CeO2 catalyzed HTL reaction. This investigation depicts that, the CeO2 nanoparticle could be employed as a potential candidate to accelerate the bio-oil conversion through HTL at low temperature from Spirulina platensis.

Suggested Citation

  • Kandasamy, Sabariswaran & Zhang, Bo & He, Zhixia & Chen, Haitao & Feng, Huan & Wang, Qian & Wang, Bin & Ashokkumar, Veeramuthu & Siva, Subramanian & Bhuvanendran, Narayanamoorthy & Krishnamoorthi, M., 2020. "Effect of low-temperature catalytic hydrothermal liquefaction of Spirulina platensis," Energy, Elsevier, vol. 190(C).
    • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219319310
    DOI: 10.1016/j.energy.2019.116236
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    3. Hosseini, Mohammad & Hatefirad, Parvaneh & Salimi, Saeideh & Tavasoli, Ahmad, 2022. "Hydrothermal liquefaction of granular bacteria to high-quality bio-oil using Ni–Ce catalysts supported on functionalized activated carbon," Energy, Elsevier, vol. 241(C).
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    5. Wang, Bin & He, Zhixia & Zhang, Bo & Duan, Yibing, 2021. "Study on hydrothermal liquefaction of spirulina platensis using biochar based catalysts to produce bio-oil," Energy, Elsevier, vol. 230(C).

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