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Experimental Study on Mineral Dissolution and Carbonation Efficiency Applied to pH-Swing Mineral Carbonation for Improved CO 2 Sequestration

Author

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  • Natália R. Galina

    (Laboratory of Combustion and Carbon Capture (LC3), Department of Energy and Chemistry, School of Engineering, UNESP—São Paulo State University, Av. Dr. Ariberto Pereira da Cunha, 333, Guaratinguetá 12516-410, SP, Brazil)

  • Gretta L. A. F. Arce

    (Laboratory of Combustion and Carbon Capture (LC3), Department of Energy and Chemistry, School of Engineering, UNESP—São Paulo State University, Av. Dr. Ariberto Pereira da Cunha, 333, Guaratinguetá 12516-410, SP, Brazil)

  • Mercedes Maroto-Valer

    (Research Centre for Carbon Solutions (RCCS), School of Engineering & Physical Sciences, Heriot-Watt University, Edinburgh EH14 4AS, UK)

  • Ivonete Ávila

    (Laboratory of Combustion and Carbon Capture (LC3), Department of Energy and Chemistry, School of Engineering, UNESP—São Paulo State University, Av. Dr. Ariberto Pereira da Cunha, 333, Guaratinguetá 12516-410, SP, Brazil)

Abstract

Mineral carbonation incurs high operating costs, as large amounts of chemicals and energy must be used in the process. Its implementation on an industrial scale requires reducing expenditures on chemicals and energy consumption. Thus, this work aimed to investigate the significant factors involved in pH-swing mineral carbonation and their effects on CO 2 capture efficiency. A central composite rotatable design (CCRD) was employed for optimizing the operational parameters of the acid dissolution of serpentinite. The results showed that temperature exerts a significant effect on magnesium dissolution. By adjusting the reaction temperature to 100 °C and setting the hydrochloric acid concentration to 2.5 molar, 96% magnesium extraction was achieved within 120 min of the reaction and 91% within 30 min of the reaction. The optimal efficiency of carbon dioxide capture was 40–50%, at higher values than those found in literature, and 90% at 150 bar and high pressures. It was found that it is technically possible to reduce the reaction time to 30 min and maintain magnesium extraction levels above 90% through the present carbonation experiments.

Suggested Citation

  • Natália R. Galina & Gretta L. A. F. Arce & Mercedes Maroto-Valer & Ivonete Ávila, 2023. "Experimental Study on Mineral Dissolution and Carbonation Efficiency Applied to pH-Swing Mineral Carbonation for Improved CO 2 Sequestration," Energies, MDPI, vol. 16(5), pages 1-19, March.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:5:p:2449-:d:1087530
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    References listed on IDEAS

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    1. Rubens C. Toledo & Gretta L. A. F. Arce & João A. Carvalho & Ivonete Ávila, 2023. "Experimental Development of Calcium Looping Carbon Capture Processes: An Overview of Opportunities and Challenges," Energies, MDPI, vol. 16(9), pages 1-27, April.
    2. Wenjin Chen & Jun Zhang & Feng Li & Ruoyi Zhang & Sennan Qi & Guoqing Li & Chong Wang, 2023. "Low Carbon Economic Dispatch of Integrated Energy System Considering Power-to-Gas Heat Recovery and Carbon Capture," Energies, MDPI, vol. 16(8), pages 1-19, April.
    3. Muhammad Hameer Soomro & Faradiella Mohd Kusin & Ferdaus Mohamat-Yusuff & Nik Norsyahariati Nik Daud, 2024. "Elution of Divalent Cations from Iron Ore Mining Waste in an Indirect Aqueous Mineral Carbonation for Carbon Capture and Storage," Sustainability, MDPI, vol. 16(2), pages 1-20, January.

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