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Converting CO2 from biogas and MgCl2 residues into valuable magnesium carbonate: A novel strategy for renewable energy production

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  • Baena-Moreno, Francisco M.
  • Rodríguez-Galán, Mónica
  • Vega, Fernando
  • Reina, T.R.
  • Vilches, Luis F.
  • Navarrete, Benito

Abstract

In this work a novel strategy for bio-methane production and magnesium chloride waste valorization is addressed. The proposed process is a potential alternative path to the already existing biogas upgrading technologies by carbon dioxide mineralization into valuable magnesium carbonate. The main parameters affecting the precipitation efficiency (reaction time, reaction temperature, and molar ratio reactant/precipitator) are studied, leading to promising results which spark further investigation in this innovative route. Additionally the purity and the morphology of the obtained solid product was accurately analysed through different physicochemical characterization techniques such as Raman, X-Ray diffraction and Scanning electron microscope. The characterisation study reveals a mixture of Nesqueonite and Dypingite carbonate phases obtained in the process being the later the dominant phase in the resulting precipitate. Overall, the results discussed herein confirmed the technical feasibility of this innovative strategy for synergizing carbon dioxide mineralization and renewable energy production.

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  • Baena-Moreno, Francisco M. & Rodríguez-Galán, Mónica & Vega, Fernando & Reina, T.R. & Vilches, Luis F. & Navarrete, Benito, 2019. "Converting CO2 from biogas and MgCl2 residues into valuable magnesium carbonate: A novel strategy for renewable energy production," Energy, Elsevier, vol. 180(C), pages 457-464.
    • Handle: RePEc:eee:energy:v:180:y:2019:i:c:p:457-464
    DOI: 10.1016/j.energy.2019.05.106
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    Cited by:

    1. Vega, F. & Baena-Moreno, F.M. & Gallego Fernández, Luz M. & Portillo, E. & Navarrete, B. & Zhang, Zhien, 2020. "Current status of CO2 chemical absorption research applied to CCS: Towards full deployment at industrial scale," Applied Energy, Elsevier, vol. 260(C).
    2. Baena-Moreno, Francisco M. & Malico, Isabel & Rodríguez-Galán, Mónica & Serrano, Antonio & Fermoso, Fernando G. & Navarrete, Benito, 2020. "The importance of governmental incentives for small biomethane plants in South Spain," Energy, Elsevier, vol. 206(C).
    3. Li, Xiangrong & Zhu, Shaoying & Yüksel, Serhat & Dinçer, Hasan & Ubay, Gözde Gülseven, 2020. "Kano-based mapping of innovation strategies for renewable energy alternatives using hybrid interval type-2 fuzzy decision-making approach," Energy, Elsevier, vol. 211(C).
    4. Baena-Moreno, Francisco M. & Sebastia-Saez, Daniel & Pastor-Pérez, Laura & Reina, Tomas Ramirez, 2021. "Analysis of the potential for biogas upgrading to syngas via catalytic reforming in the United Kingdom," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    5. Bose, A. & O'Shea, R. & Lin, R. & Long, A. & Rajendran, K. & Wall, D. & De, S. & Murphy, J.D., 2022. "Evaluation of a biomethane, food and biofertiliser polygeneration system in a circular economy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
    6. Baena-Moreno, Francisco M. & Pastor-Pérez, Laura & Zhang, Zhien & Reina, T.R., 2020. "Stepping towards a low-carbon economy. Formic acid from biogas as case of study," Applied Energy, Elsevier, vol. 268(C).

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