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Combined Biological Method for Simultaneous Removal of Hydrogen Sulphide and Volatile Methylsiloxanes from Biogas

Author

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  • Kazimierz Gaj

    (Faculty of Environmental Engineering, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland)

  • Klaudia Cichuta

    (Faculty of Environmental Engineering, Wroclaw University of Science and Technology, 50-370 Wroclaw, Poland)

Abstract

Hydrogen sulphide (H 2 S) and volatile methylsiloxanes (VMSs) are key pollutants from the point of view of the operators of biogas plants. H 2 S poses corrosive hazards, while VMSs transform into difficult-to-remove deposits, reducing the availability and yield of biogas combustion equipment. This study provides a critical overview and evaluation (so-called SWOT analysis) of implemented and promising methods to reduce the content of the above pollutants in biogas, with particular emphasis on biological techniques. The aim of the analyses was to develop an innovative concept for a hybrid biological method for the combined removal of H 2 S and VMSs using the same device, i.e., a two-phase biotrickling filter (BTF), in which the organic phase that intensifies the mass transfer of VMSs is in the form of a low-viscosity methyl silicone oil. The finally developed technological schematic diagram includes the basic devices and media streams. The concept is characterized by closed media circuits and comprehensively solves the problem of purifying biogas from sewage sludge. In conclusion, key issues requiring further research are identified.

Suggested Citation

  • Kazimierz Gaj & Klaudia Cichuta, 2022. "Combined Biological Method for Simultaneous Removal of Hydrogen Sulphide and Volatile Methylsiloxanes from Biogas," Energies, MDPI, vol. 16(1), pages 1-18, December.
    • Handle: RePEc:gam:jeners:v:16:y:2022:i:1:p:100-:d:1010910
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    References listed on IDEAS

    as
    1. Kazimierz Gaj, 2020. "Adsorptive Biogas Purification from Siloxanes—A Critical Review," Energies, MDPI, vol. 13(10), pages 1-10, May.
    2. Shen, Yanwen & Linville, Jessica L. & Urgun-Demirtas, Meltem & Schoene, Robin P. & Snyder, Seth W., 2015. "Producing pipeline-quality biomethane via anaerobic digestion of sludge amended with corn stover biochar with in-situ CO2 removal," Applied Energy, Elsevier, vol. 158(C), pages 300-309.
    3. Läntelä, J. & Rasi, S. & Lehtinen, J. & Rintala, J., 2012. "Landfill gas upgrading with pilot-scale water scrubber: Performance assessment with absorption water recycling," Applied Energy, Elsevier, vol. 92(C), pages 307-314.
    4. Zhang, Yuyao & Kawasaki, Yu & Oshita, Kazuyuki & Takaoka, Masaki & Minami, Daisuke & Inoue, Go & Tanaka, Toshihiro, 2021. "Economic assessment of biogas purification systems for removal of both H2S and siloxane from biogas," Renewable Energy, Elsevier, vol. 168(C), pages 119-130.
    5. Santos-Clotas, Eric & Cabrera-Codony, Alba & Martín, Maria J., 2020. "Coupling adsorption with biotechnologies for siloxane abatement from biogas," Renewable Energy, Elsevier, vol. 153(C), pages 314-323.
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