IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i21p7933-d953179.html
   My bibliography  Save this article

Determination of Carbonyls Compound, Ketones and Aldehydes Emissions from CI Diesel Engines Fueled with Pure Diesel/Diesel Methanol Blends

Author

Listed:
  • Hani Al-Rawashdeh

    (Department of Mechanical Engineering, Faculty of Engineering, Al-Hussein Bin Talal University, Ma’an 71110, Jordan)

  • Ahmad O. Hasan

    (Department of Mechanical Engineering, Faculty of Engineering, Al-Hussein Bin Talal University, Ma’an 71110, Jordan)

  • Mohamed R. Gomaa

    (Department of Mechanical Engineering, Faculty of Engineering, Al-Hussein Bin Talal University, Ma’an 71110, Jordan
    Department of Mechanical Engineering, Faculty of Engineering, Benha University, Benha 13512, Egypt)

  • Ahmad Abu-jrai

    (Department of Environmental Engineering, Faculty of Engineering, Al-Hussein Bin Talal University, Ma’an 71110, Jordan)

  • Mohammad Shalby

    (Department of Mechanical Engineering, Faculty of Engineering, Al-Hussein Bin Talal University, Ma’an 71110, Jordan)

Abstract

Quantitative and qualitative analyses of chemical species out of CI engine tailpipe emissions fueled with pure diesel and diesel methanol blends, trapped in dinitro phenylhydrazine (DNPH) solutions, were performed. The formed hydrazine was studied using high-performance liquid chromatography (HPLC) accompanied by a detector for ultraviolet (UV). A set of carbonyl-DNPH derivative standards was developed and compared with engine tailpipe gases produced by both fuel modes. An understanding of carbonyl chemical compounds such as formaldehyde, acetaldehyde, and acrolein (HCHO, CH 3 CHO, and H 2 = CHCHO, respectively) is essential for researchers to know how these chemicals affect human health and the environment. In both fuel modes, acetaldehyde was the main combustible product 25 ppm followed by formaldehyde 17 ppm, croton aldehydes 16 ppm, acrolein 12 ppm, and iso-valerdyhyde 10 ppm. In addition to these species, only a few other chemical species were detected in the exhaust gas. According to this study, carbonyl compounds from blended fuel contribute 15–22% of pure diesel fuel emissions. As shown by the results, engine operating conditions and fuel mode have a strong impact on the total amount of carbonyls released by the engine. Engine performance was highly influenced by different fuel modes and engine speeds. Using pure diesel, the regulated emissions, HC, CO, and NOx, registered high concentrations at a lower speed (1500 rpm) and NOx presented with the highest concentration of 4 g/kWh followed by CO with 1 g/kWh and HC with 0.5 g/kWh.

Suggested Citation

  • Hani Al-Rawashdeh & Ahmad O. Hasan & Mohamed R. Gomaa & Ahmad Abu-jrai & Mohammad Shalby, 2022. "Determination of Carbonyls Compound, Ketones and Aldehydes Emissions from CI Diesel Engines Fueled with Pure Diesel/Diesel Methanol Blends," Energies, MDPI, vol. 15(21), pages 1-16, October.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:21:p:7933-:d:953179
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/21/7933/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/21/7933/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Gomaa, Mohamed R. & Al-Dmour, Nesrien & AL-Rawashdeh, Hani A. & Shalby, Mohammad, 2020. "Theoretical model of a fluidized bed solar reactor design with the aid of MCRT method and synthesis gas production," Renewable Energy, Elsevier, vol. 148(C), pages 91-102.
    2. Mohamed R. Gomaa & Talib K. Murtadha & Ahmad Abu-jrai & Hegazy Rezk & Moath A. Altarawneh & Abdullah Marashli, 2022. "Experimental Investigation on Waste Heat Recovery from a Cement Factory to Enhance Thermoelectric Generation," Sustainability, MDPI, vol. 14(16), pages 1-18, August.
    3. Hulwan, Dattatray Bapu & Joshi, Satishchandra V., 2011. "Performance, emission and combustion characteristic of a multicylinder DI diesel engine running on diesel–ethanol–biodiesel blends of high ethanol content," Applied Energy, Elsevier, vol. 88(12), pages 5042-5055.
    4. Ahmad O. Hasan & Khamis Essa & Mohamed R. Gomaa, 2022. "Synthesis, Structure Characterization and Study of a New Kind of Catalyst: A Monolith of Nickel Made by Additive Manufacturing Coated with Platinum," Energies, MDPI, vol. 15(20), pages 1-13, October.
    5. Lee, Sanghoon & Lee, Chang Sik & Park, Sungwook & Gupta, Jai Gopal & Maurya, Rakesh Kumar & Agarwal, Avinash Kumar, 2017. "Spray characteristics, engine performance and emissions analysis for Karanja biodiesel and its blends," Energy, Elsevier, vol. 119(C), pages 138-151.
    6. Hani Al-Rawashdeh & Ahmad O. Hasan & Hazem A. Al-Shakhanbeh & Mujahed Al-Dhaifallah & Mohamed R. Gomaa & Hegazy Rezk, 2021. "Investigation of the Effect of Solar Ventilation on the Cabin Temperature of Vehicles Parked under the Sun," Sustainability, MDPI, vol. 13(24), pages 1-21, December.
    7. Ali Alahmer & Hegazy Rezk & Wail Aladayleh & Ahmad O. Mostafa & Mahmoud Abu-Zaid & Hussein Alahmer & Mohamed R. Gomaa & Amel A. Alhussan & Rania M. Ghoniem, 2022. "Modeling and Optimization of a Compression Ignition Engine Fueled with Biodiesel Blends for Performance Improvement," Mathematics, MDPI, vol. 10(3), pages 1-29, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Elias Amancio Siqueira-Filho & Maira Farias Andrade Lira & Attilio Converti & Hugo Valadares Siqueira & Carmelo J. A. Bastos-Filho, 2023. "Predicting Thermoelectric Power Plants Diesel/Heavy Fuel Oil Engine Fuel Consumption Using Univariate Forecasting and XGBoost Machine Learning Models," Energies, MDPI, vol. 16(7), pages 1-27, March.
    2. Jinping Liu & Guangzhao Guo & Mingrui Wei, 2023. "Effects of Methanol Addition on the Combustion Process of the Methanol/Diesel Dual-Fuel Based on an Optical Engine," Energies, MDPI, vol. 16(24), pages 1-18, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Ahmad O. Hasan & Khamis Essa & Mohamed R. Gomaa, 2022. "Synthesis, Structure Characterization and Study of a New Kind of Catalyst: A Monolith of Nickel Made by Additive Manufacturing Coated with Platinum," Energies, MDPI, vol. 15(20), pages 1-13, October.
    2. Ala’a K. Al-Bawwat & Francisco Jurado & Mohamed R. Gomaa & Antonio Cano, 2023. "Availability and the Possibility of Employing Wastes and Biomass Materials Energy in Jordan," Sustainability, MDPI, vol. 15(7), pages 1-24, March.
    3. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    4. Yesilyurt, Murat Kadir & Eryilmaz, Tanzer & Arslan, Mevlüt, 2018. "A comparative analysis of the engine performance, exhaust emissions and combustion behaviors of a compression ignition engine fuelled with biodiesel/diesel/1-butanol (C4 alcohol) and biodiesel/diesel/," Energy, Elsevier, vol. 165(PB), pages 1332-1351.
    5. Tse, H. & Leung, C.W. & Cheung, C.S., 2015. "Investigation on the combustion characteristics and particulate emissions from a diesel engine fueled with diesel-biodiesel-ethanol blends," Energy, Elsevier, vol. 83(C), pages 343-350.
    6. Teoh, Y.H. & How, H.G. & Masjuki, H.H. & Nguyen, H.-T. & Kalam, M.A. & Alabdulkarem, A., 2019. "Investigation on particulate emissions and combustion characteristics of a common-rail diesel engine fueled with Moringa oleifera biodiesel-diesel blends," Renewable Energy, Elsevier, vol. 136(C), pages 521-534.
    7. Hirner, Felix Sebastian & Hwang, Joonsik & Bae, Choongsik & Patel, Chetankumar & Gupta, Tarun & Agarwal, Avinash Kumar, 2019. "Performance and emission evaluation of a small-bore biodiesel compression-ignition engine," Energy, Elsevier, vol. 183(C), pages 971-982.
    8. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    9. Chang, Yu-Cheng & Lee, Wen-Jhy & Wu, Tser Son & Wu, Chang-Yu & Chen, Shui-Jen, 2014. "Use of water containing acetone–butanol–ethanol for NOx-PM (nitrogen oxide-particulate matter) trade-off in the diesel engine fueled with biodiesel," Energy, Elsevier, vol. 64(C), pages 678-687.
    10. Chang, Yu-Cheng & Lee, Wen-Jhy & Wang, Lin-Chi & Yang, Hsi-Hsien & Cheng, Man-Ting & Lu, Jau-Huai & Tsai, Ying I. & Young, Li-Hao, 2014. "Effects of waste cooking oil-based biodiesel on the toxic organic pollutant emissions from a diesel engine," Applied Energy, Elsevier, vol. 113(C), pages 631-638.
    11. Wei, L. & Cheung, C.S. & Ning, Z., 2017. "Influence of waste cooking oil biodiesel on combustion, unregulated gaseous emissions and particulate emissions of a direct-injection diesel engine," Energy, Elsevier, vol. 127(C), pages 175-185.
    12. Shen, Shiquan & Sun, Kai & Che, Zhizhao & Wang, Tianyou & Jia, Ming & Cai, Junqian, 2020. "Mechanism of micro-explosion of water-in-oil emulsified fuel droplet and its effect on soot generation," Energy, Elsevier, vol. 191(C).
    13. Wei, L. & Cheung, C.S. & Ning, Z., 2018. "Effects of biodiesel-ethanol and biodiesel-butanol blends on the combustion, performance and emissions of a diesel engine," Energy, Elsevier, vol. 155(C), pages 957-970.
    14. Chen, Longfei & Ding, Shirun & Liu, Haoye & Lu, Yiji & Li, Yanfei & Roskilly, Anthony Paul, 2017. "Comparative study of combustion and emissions of kerosene (RP-3), kerosene-pentanol blends and diesel in a compression ignition engine," Applied Energy, Elsevier, vol. 203(C), pages 91-100.
    15. Ng, Hoon Kiat & Gan, Suyin & Ng, Jo-Han & Pang, Kar Mun, 2013. "Simulation of biodiesel combustion in a light-duty diesel engine using integrated compact biodiesel–diesel reaction mechanism," Applied Energy, Elsevier, vol. 102(C), pages 1275-1287.
    16. Zhang, Zhi-Hui & Balasubramanian, Rajasekhar, 2014. "Influence of butanol addition to diesel–biodiesel blend on engine performance and particulate emissions of a stationary diesel engine," Applied Energy, Elsevier, vol. 119(C), pages 530-536.
    17. Márcio Carvalho & Felipe Torres & Vitor Ferreira & Júlio Silva & Jorge Martins & Ednildo Torres, 2020. "Effects of Diethyl Ether Introduction in Emissions and Performance of a Diesel Engine Fueled with Biodiesel-Ethanol Blends," Energies, MDPI, vol. 13(15), pages 1-14, July.
    18. Wu, Shaohua & Akroyd, Jethro & Mosbach, Sebastian & Brownbridge, George & Parry, Owen & Page, Vivian & Yang, Wenming & Kraft, Markus, 2020. "Efficient simulation and auto-calibration of soot particle processes in Diesel engines," Applied Energy, Elsevier, vol. 262(C).
    19. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Lee, P.S. & Chua, K.J.E. & Chou, S.K., 2014. "Pine oil–biodiesel blends: A double biofuel strategy to completely eliminate the use of diesel in a diesel engine," Applied Energy, Elsevier, vol. 130(C), pages 466-473.
    20. Alptekin, Ertan, 2017. "Emission, injection and combustion characteristics of biodiesel and oxygenated fuel blends in a common rail diesel engine," Energy, Elsevier, vol. 119(C), pages 44-52.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:21:p:7933-:d:953179. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.