IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i8p2040-d531534.html
   My bibliography  Save this article

Low-Rank Coal Supported Ni Catalysts for CO 2 Methanation

Author

Listed:
  • Soohyun Kim

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

  • Yunxia Yang

    (CSIRO Energy, 71 Normanby Rd., Clayton North, VIC 3169, Australia)

  • Renata Lippi

    (CSIRO Energy, 71 Normanby Rd., Clayton North, VIC 3169, Australia
    Australian Synchrotron (ANSTO), 800 Blackburn Rd., Clayton, VIC 3168, Australia)

  • Hokyung Choi

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

  • Sangdo Kim

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

  • Donghyuk Chun

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

  • Hyuk Im

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

  • Sihyun Lee

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

  • Jiho Yoo

    (Find Dust Research Department, Korea Institute of Energy Research, Daejeon 34129, Korea)

Abstract

As renewable energy source integration increases, P2G technology that can store surplus renewable power as methane is expected to expand. The development of a CO 2 methanation catalyst, one of the core processes of the P2G concept, is being actively conducted. In this work, low-rank coal (LRC) was used as a catalyst support for CO 2 methanation, as it can potentially enhance the diffusion and adsorption behavior by easily controlling the pore structure and composition. It can also improve the process efficiency owing to its simplicity (no pre-reduction step) and high thermal conductivity, compared to conventional metal oxide-supported catalysts. A screening of single metals (Ni, Co, Ru, Rh, and Pd) on LRC was performed, which showed that Ni was the most active. When Ni on the LRC catalyst was doped with a promoter (Ce and Mg), the CO 2 conversion percentage increased by >10% compared to that of the single Ni catalyst. When the CO 2 methanation activity was compared at 250–500 °C, the Ce-doped Ni/Eco and Mg-doped Ni/Eco catalysts showed similar or better activity than the commercial metal oxide-supported catalyst. In addition, the catalytic performance remained stable even after the test for an extended time (~200 h). The results of XRD, TEM, and TPR showed that highly efficient LRC-based CO 2 methanation catalysts can be made when the metal dispersion and composition are modified.

Suggested Citation

  • Soohyun Kim & Yunxia Yang & Renata Lippi & Hokyung Choi & Sangdo Kim & Donghyuk Chun & Hyuk Im & Sihyun Lee & Jiho Yoo, 2021. "Low-Rank Coal Supported Ni Catalysts for CO 2 Methanation," Energies, MDPI, vol. 14(8), pages 1-13, April.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:8:p:2040-:d:531534
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/8/2040/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/8/2040/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Guandalini, Giulio & Campanari, Stefano & Romano, Matteo C., 2015. "Power-to-gas plants and gas turbines for improved wind energy dispatchability: Energy and economic assessment," Applied Energy, Elsevier, vol. 147(C), pages 117-130.
    2. Renda, Simona & Ricca, Antonio & Palma, Vincenzo, 2020. "Precursor salts influence in Ruthenium catalysts for CO2 hydrogenation to methane," Applied Energy, Elsevier, vol. 279(C).
    3. Götz, Manuel & Lefebvre, Jonathan & Mörs, Friedemann & McDaniel Koch, Amy & Graf, Frank & Bajohr, Siegfried & Reimert, Rainer & Kolb, Thomas, 2016. "Renewable Power-to-Gas: A technological and economic review," Renewable Energy, Elsevier, vol. 85(C), pages 1371-1390.
    4. Ye, Run-Ping & Gong, Weibo & Sun, Zhao & Sheng, Qingtao & Shi, Xiufeng & Wang, Tongtong & Yao, Yi & Razink, Joshua J. & Lin, Ling & Zhou, Zhangfeng & Adidharma, Hertanto & Tang, Jinke & Fan, Maohong &, 2019. "Enhanced stability of Ni/SiO2 catalyst for CO2 methanation: Derived from nickel phyllosilicate with strong metal-support interactions," Energy, Elsevier, vol. 188(C).
    5. Nam, Hyungseok & Kim, Jung Hwan & Kim, Hana & Kim, Min Jae & Jeon, Sang-Goo & Jin, Gyoung-Tae & Won, Yooseob & Hwang, Byung Wook & Lee, Seung-Yong & Baek, Jeom-In & Lee, Doyeon & Seo, Myung Won & Ryu,, 2021. "CO2 methanation in a bench-scale bubbling fluidized bed reactor using Ni-based catalyst and its exothermic heat transfer analysis," Energy, Elsevier, vol. 214(C).
    6. Wang, Xiaoliu & Yang, Meng & Zhu, Xiaonan & Zhu, Lingjun & Wang, Shurong, 2020. "Experimental study and life cycle assessment of CO2 methanation over biochar supported catalysts," Applied Energy, Elsevier, vol. 280(C).
    7. Zhou, Suyang & Sun, Kaiyu & Wu, Zhi & Gu, Wei & Wu, Gaoxiang & Li, Zhe & Li, Junjie, 2020. "Optimized operation method of small and medium-sized integrated energy system for P2G equipment under strong uncertainty," Energy, Elsevier, vol. 199(C).
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Qinglin Wu & Meidie Pan & Shikai Zhang & Dongpeng Sun & Yang Yang & Dong Chen & David A. Weitz & Xiang Gao, 2022. "Research Progress in High-Throughput Screening of CO 2 Reduction Catalysts," Energies, MDPI, vol. 15(18), pages 1-18, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Andrea Barbaresi & Mirko Morini & Agostino Gambarotta, 2022. "Review on the Status of the Research on Power-to-Gas Experimental Activities," Energies, MDPI, vol. 15(16), pages 1-32, August.
    2. Farrokhifar, Meisam & Nie, Yinghui & Pozo, David, 2020. "Energy systems planning: A survey on models for integrated power and natural gas networks coordination," Applied Energy, Elsevier, vol. 262(C).
    3. Laslett, Dean & Carter, Craig & Creagh, Chris & Jennings, Philip, 2017. "A large-scale renewable electricity supply system by 2030: Solar, wind, energy efficiency, storage and inertia for the South West Interconnected System (SWIS) in Western Australia," Renewable Energy, Elsevier, vol. 113(C), pages 713-731.
    4. Li, Bo & Li, Xu & Su, Qingyu, 2022. "A system and game strategy for the isolated island electric-gas deeply coupled energy network," Applied Energy, Elsevier, vol. 306(PA).
    5. Bellocchi, Sara & De Falco, Marcello & Gambini, Marco & Manno, Michele & Stilo, Tommaso & Vellini, Michela, 2019. "Opportunities for power-to-Gas and Power-to-liquid in CO2-reduced energy scenarios: The Italian case," Energy, Elsevier, vol. 175(C), pages 847-861.
    6. Masoud Agabalaye-Rahvar & Amin Mansour-Saatloo & Mohammad Amin Mirzaei & Behnam Mohammadi-Ivatloo & Kazem Zare & Amjad Anvari-Moghaddam, 2020. "Robust Optimal Operation Strategy for a Hybrid Energy System Based on Gas-Fired Unit, Power-to-Gas Facility and Wind Power in Energy Markets," Energies, MDPI, vol. 13(22), pages 1-21, November.
    7. Chengkang Guo & Xiwang Abuduwayiti & Yiming Shang & Leiyu Huang & Chuanshi Cui, 2024. "Optimized Scheduling of Integrated Energy Systems Accounting for Hydrogen Energy Multi-Utilization Models," Sustainability, MDPI, vol. 16(3), pages 1-21, January.
    8. Quarton, Christopher J. & Samsatli, Sheila, 2020. "The value of hydrogen and carbon capture, storage and utilisation in decarbonising energy: Insights from integrated value chain optimisation," Applied Energy, Elsevier, vol. 257(C).
    9. Reznicek, Evan P. & Braun, Robert J., 2020. "Reversible solid oxide cell systems for integration with natural gas pipeline and carbon capture infrastructure for grid energy management," Applied Energy, Elsevier, vol. 259(C).
    10. McDonagh, Shane & Deane, Paul & Rajendran, Karthik & Murphy, Jerry D., 2019. "Are electrofuels a sustainable transport fuel? Analysis of the effect of controls on carbon, curtailment, and cost of hydrogen," Applied Energy, Elsevier, vol. 247(C), pages 716-730.
    11. Badami, Marco & Fambri, Gabriele, 2019. "Optimising energy flows and synergies between energy networks," Energy, Elsevier, vol. 173(C), pages 400-412.
    12. Eveloy, Valerie, 2019. "Hybridization of solid oxide electrolysis-based power-to-methane with oxyfuel combustion and carbon dioxide utilization for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 550-571.
    13. Wang, Cheng & Wei, Wei & Wang, Jianhui & Bi, Tianshu, 2019. "Convex optimization based adjustable robust dispatch for integrated electric-gas systems considering gas delivery priority," Applied Energy, Elsevier, vol. 239(C), pages 70-82.
    14. Bucksteeg, Michael & Mikurda, Jennifer & Weber, Christoph, 2023. "Integration of power-to-gas into electricity markets during the ramp-up phase—Assessing the role of carbon pricing," Energy Economics, Elsevier, vol. 124(C).
    15. Gorre, Jachin & Ruoss, Fabian & Karjunen, Hannu & Schaffert, Johannes & Tynjälä, Tero, 2020. "Cost benefits of optimizing hydrogen storage and methanation capacities for Power-to-Gas plants in dynamic operation," Applied Energy, Elsevier, vol. 257(C).
    16. Wang, Ligang & Pérez-Fortes, Mar & Madi, Hossein & Diethelm, Stefan & herle, Jan Van & Maréchal, François, 2018. "Optimal design of solid-oxide electrolyzer based power-to-methane systems: A comprehensive comparison between steam electrolysis and co-electrolysis," Applied Energy, Elsevier, vol. 211(C), pages 1060-1079.
    17. Szoplik, Jolanta & Stelmasińska, Paulina, 2019. "Analysis of gas network storage capacity for alternative fuels in Poland," Energy, Elsevier, vol. 172(C), pages 343-353.
    18. Van Dael, Miet & Kreps, Sabine & Virag, Ana & Kessels, Kris & Remans, Koen & Thomas, Denis & De Wilde, Fabian, 2018. "Techno-economic assessment of a microbial power-to-gas plant – Case study in Belgium," Applied Energy, Elsevier, vol. 215(C), pages 416-425.
    19. Jing Liu & Wei Sun & Jinghao Yan, 2021. "Effect of P2G on Flexibility in Integrated Power-Natural Gas-Heating Energy Systems with Gas Storage," Energies, MDPI, vol. 14(1), pages 1-15, January.
    20. Yunesky Masip Macía & Pablo Rodríguez Machuca & Angel Alexander Rodríguez Soto & Roberto Carmona Campos, 2021. "Green Hydrogen Value Chain in the Sustainability for Port Operations: Case Study in the Region of Valparaiso, Chile," Sustainability, MDPI, vol. 13(24), pages 1-17, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:8:p:2040-:d:531534. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.