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The Effect of Hydroxylated Multi-Walled Carbon Nanotubes on the Properties of Peg-Cacl 2 Form-Stable Phase Change Materials

Author

Listed:
  • Lingyu Zheng

    (Merchant Marine College 1, Shanghai Maritime University, Shanghai 200135, China)

  • Xuelai Zhang

    (Merchant Marine College 1, Shanghai Maritime University, Shanghai 200135, China)

  • Weisan Hua

    (Merchant Marine College 1, Shanghai Maritime University, Shanghai 200135, China)

  • Xinfeng Wu

    (Merchant Marine College 1, Shanghai Maritime University, Shanghai 200135, China)

  • Fa Mao

    (Merchant Marine College 1, Shanghai Maritime University, Shanghai 200135, China)

Abstract

Calcium ions can react with polyethylene glycol (PEG) to form a form-stable phase change material, but the low thermal conductivity hinders its practical application. In this paper, hydroxylated multi-walled carbon nanotubes (MWCNTs) with different mass are introduced into PEG1500·CaCl 2 form-stable phase change material to prepare a new type of energy storage material. Carbon nanotubes increased the mean free path (MFP) of phonons and effectively reduced the interfacial thermal resistance between pure PEG and PEG1500·CaCl 2 3D skeleton structure. Thermal conductivity was significant improved after increasing MWCNTs mass, while the latent heat decreases. At 1.5 wt%, composite material shows the highest phase change temperature of 42 °C, and its thermal conductivity is 291.30% higher than pure PEG1500·CaCl 2 . This article can provide some suggestions for the preparation and application of high thermal conductivity form-stable phase change materials.

Suggested Citation

  • Lingyu Zheng & Xuelai Zhang & Weisan Hua & Xinfeng Wu & Fa Mao, 2021. "The Effect of Hydroxylated Multi-Walled Carbon Nanotubes on the Properties of Peg-Cacl 2 Form-Stable Phase Change Materials," Energies, MDPI, vol. 14(5), pages 1-17, March.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:5:p:1403-:d:510105
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