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Carbon Dioxide Gasification Kinetics of Char from Rapeseed Oil Press Cake

Author

Listed:
  • Lech Nowicki

    (Faculty of Process and Environmental Engineering, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland)

  • Dorota Siuta

    (Faculty of Process and Environmental Engineering, Lodz University of Technology, Wolczanska 213, 90-924 Lodz, Poland)

  • Maciej Markowski

    (EKO-SERWIS S.C., Wierzbowa 48, 90-133 Lodz, Poland)

Abstract

Rapeseed oil press cake (RPC) is an abundantly available and renewable agricultural waste material for the production of fuels or chemicals. In this study, the rates of carbon dioxide gasification of rapeseed oil press cake char were measured by thermogravimetric analysis measurements performed at various temperatures (800–900 °C) and CO 2 mole fractions (0.10–1.00). The char was obtained by slow pyrolysis, where the dried RPC was decomposed at a temperature range of 1000 °C to obtain char free of impurities that can affect the measurements. The random pore model appeared to be suitable for describing the effect of conversion on the reaction rate. The temperature, CO 2 , and concentration dependence of the reaction rate were given by the Arrhenius equation and a power law (nth order) correlation. The kinetic parameters based on the experimental data were determined by a two-step estimation procedure. For the experimental conditions employed in this study, the parameters E and n were 222.1 kJ/mol and 0.57, respectively.

Suggested Citation

  • Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Carbon Dioxide Gasification Kinetics of Char from Rapeseed Oil Press Cake," Energies, MDPI, vol. 13(9), pages 1-12, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:9:p:2318-:d:354788
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    References listed on IDEAS

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    1. Wang, Guangwei & Zhang, Jianliang & Shao, Jiugang & Liu, Zhengjian & Wang, Haiyang & Li, Xinyu & Zhang, Pengcheng & Geng, Weiwei & Zhang, Guohua, 2016. "Experimental and modeling studies on CO2 gasification of biomass chars," Energy, Elsevier, vol. 114(C), pages 143-154.
    2. Al Arni, Saleh, 2018. "Comparison of slow and fast pyrolysis for converting biomass into fuel," Renewable Energy, Elsevier, vol. 124(C), pages 197-201.
    3. Ahmed, I.I. & Gupta, A.K., 2011. "Kinetics of woodchips char gasification with steam and carbon dioxide," Applied Energy, Elsevier, vol. 88(5), pages 1613-1619, May.
    4. Onay, Ozlem & Kockar, O.Mete, 2003. "Slow, fast and flash pyrolysis of rapeseed," Renewable Energy, Elsevier, vol. 28(15), pages 2417-2433.
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    Cited by:

    1. Nadia Cerone & Francesco Zimbardi, 2021. "Effects of Oxygen and Steam Equivalence Ratios on Updraft Gasification of Biomass," Energies, MDPI, vol. 14(9), pages 1-18, May.
    2. Paweł Wolny & Norbert Tuśnio & Artur Lewandowski & Filip Mikołajczyk & Sławomir Kuberski, 2021. "Self-Acting Formation of an ANFO Similar Type of Explosive under Fire Conditions: A Case Study," Energies, MDPI, vol. 14(21), pages 1-10, October.
    3. Andreas Schwabauer & Marco Mancini & Yunus Poyraz & Roman Weber, 2021. "On the Mathematical Modelling of a Moving-Bed Counter-Current Gasifier Fuelled with Wood-Pellets," Energies, MDPI, vol. 14(18), pages 1-24, September.
    4. Lech Nowicki & Dorota Siuta & Maciej Markowski, 2020. "Pyrolysis of Rapeseed Oil Press Cake and Steam Gasification of Solid Residues," Energies, MDPI, vol. 13(17), pages 1-12, August.
    5. Alejandro Lyons Cerón & Alar Konist, 2023. "Co-Pyrolysis of Woody Biomass and Oil Shale in a Batch Reactor in CO 2 , CO 2 -H 2 O, and Ar Atmospheres," Energies, MDPI, vol. 16(7), pages 1-14, March.

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