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Cascade conversion of furfural to fuel bioadditive ethyl levulinate over bifunctional zirconium-based catalysts

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  • Li, Mengzhu
  • Wei, Junnan
  • Yan, Guihua
  • Liu, Huai
  • Tang, Xing
  • Sun, Yong
  • Zeng, Xianhai
  • Lei, Tingzhou
  • Lin, Lu

Abstract

Biomass-derived ethyl levulinate (EL) is currently deemed as a promising fuel bioadditive to improve (bio)diesel combustion performance without the sacrifice of its octane number. In this contribution, a range of Zr–Al bimetallic catalysts were prepared for the cascade conversion of furfural to EL by the integration of transfer hydrogenation and ethanolysis in ethanol. The ratio of Lewis to Brønsted acid sites (L/B) could be tuned by the ratio of Al2O3 to ZrO2 over SBA-15 support. Among these catalysts, Zr–Al/SBA-15(30:10) with appropriate L/B ratio of 2.25 exhibited an outstanding catalytic performance to give a furfural (FF) conversion up to 92.8% with a EL selectivity as high as 71.4% at 453 K in 3 h.

Suggested Citation

  • Li, Mengzhu & Wei, Junnan & Yan, Guihua & Liu, Huai & Tang, Xing & Sun, Yong & Zeng, Xianhai & Lei, Tingzhou & Lin, Lu, 2020. "Cascade conversion of furfural to fuel bioadditive ethyl levulinate over bifunctional zirconium-based catalysts," Renewable Energy, Elsevier, vol. 147(P1), pages 916-923.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:916-923
    DOI: 10.1016/j.renene.2019.09.064
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    References listed on IDEAS

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    1. Xu, Guizhuan & Chang, Chun & Fang, Shuqi & Ma, Xiaojian, 2015. "Cellulose reactivity in ethanol at elevate temperature and the kinetics of one-pot preparation of ethyl levulinate from cellulose," Renewable Energy, Elsevier, vol. 78(C), pages 583-589.
    2. Lei, Tingzhou & Wang, Zhiwei & Chang, Xia & Lin, Lu & Yan, Xiaoyu & Sun, Yincong & Shi, Xinguang & He, Xiaofeng & Zhu, Jinling, 2016. "Performance and emission characteristics of a diesel engine running on optimized ethyl levulinate–biodiesel–diesel blends," Energy, Elsevier, vol. 95(C), pages 29-40.
    3. Srikanth, H.V. & Venkatesh, J. & Godiganur, Sharanappa & Venkateswaran, S. & Manne, Bhaskar, 2017. "Bio-based diluents improve cold flow properties of dairy washed milk-scum biodiesel," Renewable Energy, Elsevier, vol. 111(C), pages 168-174.
    4. Al Arni, Saleh, 2018. "Comparison of slow and fast pyrolysis for converting biomass into fuel," Renewable Energy, Elsevier, vol. 124(C), pages 197-201.
    5. Peng, Lincai & Lin, Lu & Li, Hui & Yang, Qiulin, 2011. "Conversion of carbohydrates biomass into levulinate esters using heterogeneous catalysts," Applied Energy, Elsevier, vol. 88(12), pages 4590-4596.
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    1. Tian, Hongli & Shao, Yuewen & Liang, Chuanfei & Xu, Qing & Zhang, Lijun & Zhang, Shu & Liu, Shuhua & Hu, Xun, 2020. "Sulfated attapulgite for catalyzing the conversion of furfuryl alcohol to ethyl levulinate: Impacts of sulfonation on structural transformation and evolution of acidic sites on the catalyst," Renewable Energy, Elsevier, vol. 162(C), pages 1576-1586.
    2. Yu, Yixuan & Liu, Huai & Zhang, Junhua & Zhang, Heng & Sun, Yong & Peng, Lincai, 2023. "Highly efficient, amorphous bimetal Ni-Fe borides-catalyzed hydrogenolysis of 5-hydroxymethylfurfural into 2,5-dimethylfuran," Renewable Energy, Elsevier, vol. 209(C), pages 453-461.
    3. Zhang, Qilin & Guo, Zongwei & Zeng, Xianhai & Ramarao, Bandaru & Xu, Feng, 2021. "A sustainable biorefinery strategy: Conversion and fractionation in a facile biphasic system towards integrated lignocellulose valorizations," Renewable Energy, Elsevier, vol. 179(C), pages 351-358.
    4. Guo, Haixin & Hirosaki, Yuta & Qi, Xinhua & Lee Smith, Richard, 2020. "Synthesis of ethyl levulinate over amino-sulfonated functional carbon materials," Renewable Energy, Elsevier, vol. 157(C), pages 951-958.
    5. Huang, Rulu & Liu, Huai & Zhang, Junhua & Cheng, Yuan & He, Liang & Peng, Lincai, 2022. "Tea polyphenol and HfCl4 Co-doped polyacrylonitrile nanofiber for highly efficient transformation of levulinic acid to γ-valerolactone," Renewable Energy, Elsevier, vol. 200(C), pages 234-243.
    6. Tang, Yiwei & Liu, Xiaoning & Xi, Ran & Liu, Le & Qi, Xinhua, 2022. "Catalytic one-pot conversion of biomass-derived furfural to ethyl levulinate over bifunctional Nb/Ni@OMC," Renewable Energy, Elsevier, vol. 200(C), pages 821-831.

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