IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i4p983-d323963.html
   My bibliography  Save this article

Ammonia/Ethanol Mixture for Adsorption Refrigeration

Author

Listed:
  • Mauro Luberti

    (School of Engineering, Institute for Materials and Processes, the University of Edinburgh, Sanderson Building, King′s Buildings, Robert Stevenson Road, Edinburgh EH9 3FB, UK)

  • Chiara Di Santis

    (School of Engineering, Institute for Materials and Processes, the University of Edinburgh, Sanderson Building, King′s Buildings, Robert Stevenson Road, Edinburgh EH9 3FB, UK)

  • Giulio Santori

    (School of Engineering, Institute for Materials and Processes, the University of Edinburgh, Sanderson Building, King′s Buildings, Robert Stevenson Road, Edinburgh EH9 3FB, UK)

Abstract

Adsorption refrigeration has become an attractive technology due to the capability to exploit low-grade thermal energy for cooling power generation and the use of environmentally friendly refrigerants. Traditionally, these systems work with pure fluids such as water, ethanol, methanol, and ammonia. Nevertheless, the operating conditions make their commercialization still unfeasible, especially owing to safety and cost issues as a consequence of the working pressures, which are higher or lower than 1 atm. The present work represents the first thermodynamic insight in the use of mixtures for adsorption refrigeration and aims to assess the performance of a binary system of ammonia and ethanol. According to the Gibbs’ phase rule, the addition of a component introduces an additional degree of freedom, which allows to adjust the pressure of the system varying the composition of the mixture. The refrigeration process was simulated with isothermal- isochoric flash calculations to solve the phase equilibria, described by the Peng-Robinson-Stryjek-Vera (PRSV) equation of state for the vapor and liquid phases and by the ideal adsorbed solution theory (IAST) and the multicomponent potential theory of adsorption (MPTA) for the adsorbed phase. In operating condenser and evaporator, pressure levels around atmospheric pressure can be achieved using an ammonia/ethanol mixture with a mole fraction of ethanol in the range of 0.70−0.75. A good agreement in the predictions of the adsorbed phase composition was also reported using the IAST and the MPTA methods.

Suggested Citation

  • Mauro Luberti & Chiara Di Santis & Giulio Santori, 2020. "Ammonia/Ethanol Mixture for Adsorption Refrigeration," Energies, MDPI, vol. 13(4), pages 1-18, February.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:4:p:983-:d:323963
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/4/983/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/13/4/983/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Santori, Giulio & Sapienza, Alessio & Freni, Angelo, 2012. "A dynamic multi-level model for adsorptive solar cooling," Renewable Energy, Elsevier, vol. 43(C), pages 301-312.
    2. Brancato, V. & Frazzica, A. & Sapienza, A. & Gordeeva, L. & Freni, A., 2015. "Ethanol adsorption onto carbonaceous and composite adsorbents for adsorptive cooling system," Energy, Elsevier, vol. 84(C), pages 177-185.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Karol Sztekler, 2021. "Optimisation of Operation of Adsorption Chiller with Desalination Function," Energies, MDPI, vol. 14(9), pages 1-20, May.
    2. Mahmoud Badawy Elsheniti & Mohamed Shaaban Eissa & Hany Al-Ansary & Jamel Orfi & Osama Elsamni & Abdelrahman El-Leathy, 2022. "Examination of Using Aluminum-Foam/Finned-Tube Beds Packed with Maxsorb III for Adsorption Ice Production System," Energies, MDPI, vol. 15(8), pages 1-21, April.
    3. Aristov, Yu. I., 2022. "Adsorption heat conversion and storage in closed systems: What have we learned over the past decade of this century?," Energy, Elsevier, vol. 239(PB).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Askalany, Ahmed A. & Ernst, Sebastian-Johannes & Hügenell, Philipp P.C. & Bart, Hans-Jörg & Henninger, Stefan K. & Alsaman, Ahmed S., 2017. "High potential of employing bentonite in adsorption cooling systems driven by low grade heat source temperatures," Energy, Elsevier, vol. 141(C), pages 782-791.
    2. Olkis, Christopher & AL-Hasni, Shihab & Brandani, Stefano & Vasta, Salvatore & Santori, Giulio, 2021. "Solar powered adsorption desalination for Northern and Southern Europe," Energy, Elsevier, vol. 232(C).
    3. Jiang, L. & Roskilly, A.P. & Wang, R.Z. & Wang, L.W., 2018. "Analysis on innovative resorption cycle for power and refrigeration cogeneration," Applied Energy, Elsevier, vol. 218(C), pages 10-21.
    4. Gordeeva, Larisa G. & Solovyeva, Marina V. & Aristov, Yuri I., 2016. "NH2-MIL-125 as a promising material for adsorptive heat transformation and storage," Energy, Elsevier, vol. 100(C), pages 18-24.
    5. Frazzica, A. & Palomba, V. & Dawoud, B. & Gullì, G. & Brancato, V. & Sapienza, A. & Vasta, S. & Freni, A. & Costa, F. & Restuccia, G., 2016. "Design, realization and testing of an adsorption refrigerator based on activated carbon/ethanol working pair," Applied Energy, Elsevier, vol. 174(C), pages 15-24.
    6. Zhang, Z.X. & Xu, H.J., 2023. "Thermodynamic modeling on multi-stage vacuum-pressure swing adsorption (VPSA) for direct air carbon capture with extreme dilute carbon dioxide," Energy, Elsevier, vol. 276(C).
    7. Kyle R. Gluesenkamp & Andrea Frazzica & Andreas Velte & Steven Metcalf & Zhiyao Yang & Mina Rouhani & Corey Blackman & Ming Qu & Eric Laurenz & Angeles Rivero-Pacho & Sam Hinmers & Robert Critoph & Ma, 2020. "Experimentally Measured Thermal Masses of Adsorption Heat Exchangers," Energies, MDPI, vol. 13(5), pages 1-21, March.
    8. Shabir, Faizan & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed & Ali, Imran & Zhou, Yuguang & Ahmad, Riaz & Shamshiri, Redmond R., 2020. "Recent updates on the adsorption capacities of adsorbent-adsorbate pairs for heat transformation applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    9. Yunlong Ma & Suvash C. Saha & Wendy Miller & Lisa Guan, 2017. "Parametric Analysis of Design Parameter Effects on the Performance of a Solar Desiccant Evaporative Cooling System in Brisbane, Australia," Energies, MDPI, vol. 10(7), pages 1-22, June.
    10. Md. Matiar Rahman & Mahbubul Muttakin & Animesh Pal & Abu Zar Shafiullah & Bidyut Baran Saha, 2019. "A Statistical Approach to Determine Optimal Models for IUPAC-Classified Adsorption Isotherms," Energies, MDPI, vol. 12(23), pages 1-34, November.
    11. Piotr Boruta & Tomasz Bujok & Łukasz Mika & Karol Sztekler, 2021. "Adsorbents, Working Pairs and Coated Beds for Natural Refrigerants in Adsorption Chillers—State of the Art," Energies, MDPI, vol. 14(15), pages 1-41, August.
    12. Santori, Giulio & Charalambous, Charithea & Ferrari, Maria-Chiara & Brandani, Stefano, 2018. "Adsorption artificial tree for atmospheric carbon dioxide capture, purification and compression," Energy, Elsevier, vol. 162(C), pages 1158-1168.
    13. Wang, Ji & Hu, Eric & Blazewicz, Antoni & Ezzat, Akram W., 2018. "Simulation of accumulated performance of a solar thermal powered adsorption refrigeration system with daily climate conditions," Energy, Elsevier, vol. 165(PA), pages 487-498.
    14. Frazzica, Andrea & Freni, Angelo, 2017. "Adsorbent working pairs for solar thermal energy storage in buildings," Renewable Energy, Elsevier, vol. 110(C), pages 87-94.
    15. Wang, Dechang & Zhang, Jipeng & Tian, Xiaoliang & Liu, Dawei & Sumathy, K., 2014. "Progress in silica gel–water adsorption refrigeration technology," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 85-104.
    16. Olkis, C. & Santori, G. & Brandani, S., 2018. "An Adsorption Reverse Electrodialysis system for the generation of electricity from low-grade heat," Applied Energy, Elsevier, vol. 231(C), pages 222-234.
    17. Marzia Khanam & Skander Jribi & Takahiko Miyazaki & Bidyut Baran Saha & Shigeru Koyama, 2018. "Numerical Investigation of Small-Scale Adsorption Cooling System Performance Employing Activated Carbon-Ethanol Pair," Energies, MDPI, vol. 11(6), pages 1-15, June.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:4:p:983-:d:323963. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.