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Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO 2 /γ-Al 2 O 3 Catalyst

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  • Sukhe Badmaev

    (Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia
    Department of Natural Sciences, Novosibirsk State University, Pirogova St. 2, 630090 Novosibirsk, Russia)

  • Vladimir Sobyanin

    (Boreskov Institute of Catalysis, 630090 Novosibirsk, Russia)

Abstract

The catalytic properties of CuO-CeO 2 supported on alumina for the oxidative steam reforming (OSR) of dimethoxymethane (DMM) to hydrogen-rich gas in a tubular fixed bed reactor were studied. The CuO-CeO 2 /γ-Al 2 O 3 catalyst provided complete DMM conversion and hydrogen productivity > 10 L h −1 g cat −1 at 280 °C, GHSV (gas hourly space velocity) = 15,000 h −1 and DMM:O 2 :H 2 O:N 2 = 10:2.5:40:47.5 vol.%. Comparative studies showed that DMM OSR exceeded DMM steam reforming (SR) and DMM partial oxidation (PO) in terms of hydrogen productivity. Thus, the outcomes of lab-scale catalytic experiments show high promise of DMM oxidative steam reforming to produce hydrogen-rich gas for fuel cell feeding.

Suggested Citation

  • Sukhe Badmaev & Vladimir Sobyanin, 2020. "Production of Hydrogen-Rich Gas by Oxidative Steam Reforming of Dimethoxymethane over CuO-CeO 2 /γ-Al 2 O 3 Catalyst," Energies, MDPI, vol. 13(14), pages 1-10, July.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:14:p:3684-:d:385966
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    References listed on IDEAS

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    1. Alexey Pechenkin & Sukhe Badmaev & Vladimir Belyaev & Vladimir Sobyanin, 2019. "Production of Hydrogen-Rich Gas by Formic Acid Decomposition over CuO-CeO 2 /γ-Al 2 O 3 Catalyst," Energies, MDPI, vol. 12(18), pages 1-10, September.
    2. Samuel Simon Araya & Vincenzo Liso & Xiaoti Cui & Na Li & Jimin Zhu & Simon Lennart Sahlin & Søren Højgaard Jensen & Mads Pagh Nielsen & Søren Knudsen Kær, 2020. "A Review of The Methanol Economy: The Fuel Cell Route," Energies, MDPI, vol. 13(3), pages 1-32, January.
    3. Panagiota Garbis & Christoph Kern & Andreas Jess, 2019. "Kinetics and Reactor Design Aspects of Selective Methanation of CO over a Ru/γ-Al 2 O 3 Catalyst in CO 2 /H 2 Rich Gases," Energies, MDPI, vol. 12(3), pages 1-15, February.
    4. Raluca-Andreea Felseghi & Elena Carcadea & Maria Simona Raboaca & Cătălin Nicolae TRUFIN & Constantin Filote, 2019. "Hydrogen Fuel Cell Technology for the Sustainable Future of Stationary Applications," Energies, MDPI, vol. 12(23), pages 1-28, December.
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