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Aromatics from Beechwood Organosolv Lignin through Thermal and Catalytic Pyrolysis

Author

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  • Konstantinos G. Kalogiannis

    (Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 6th km Harilaou-Thermi Rd, 57001 Thessaloniki, Greece)

  • Leonidas Matsakas

    (Biochemical Process Engineering, Division of Chemical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, 971-87 Luleå, Sweden)

  • Angelos A. Lappas

    (Chemical Process and Energy Resources Institute (CPERI), Centre for Research and Technology Hellas (CERTH), 6th km Harilaou-Thermi Rd, 57001 Thessaloniki, Greece)

  • Ulrika Rova

    (Biochemical Process Engineering, Division of Chemical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, 971-87 Luleå, Sweden)

  • Paul Christakopoulos

    (Biochemical Process Engineering, Division of Chemical Engineering, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, 971-87 Luleå, Sweden)

Abstract

Biomass fractionation, as an alternative to biomass pretreatment, has gained increasing research attention over the past few years as it provides separate streams of cellulose, hemicellulose, and lignin. These streams can be used separately and can provide a solution for improving the economics of emerging biorefinery technologies. The sugar streams are commonly used in microbial conversions, whereas during recent years lignin has been recognized as a valuable compound as it is the only renewable and abundant source of aromatic chemicals. Successfully converting lignin into valuable chemicals and products is key in achieving both environmental and economic sustainability of future biorefineries. In this work, lignin retrieved from beechwood sawdust delignification pretreatment via an organosolv process was depolymerized with thermal and catalytic pyrolysis. ZSM-5 commercial catalyst was used in situ to upgrade the lignin bio-oil vapors. Lignins retrieved from different modes of organosolv pretreatment were tested in order to evaluate the effect that upstream pretreatment has on the lignin fraction. Both thermal and catalytic pyrolysis yielded oils rich in phenols and aromatic hydrocarbons. Use of ZSM-5 catalyst assisted in overall deoxygenation of the bio-oils and enhanced aromatic hydrocarbons production. The oxygen content of the bio-oils was reduced at the expense of their yield. Organosolv lignins were successfully depolymerized towards phenols and aromatic hydrocarbons via thermal and catalytic pyrolysis. Hence, lignin pyrolysis can be an effective manner for lignin upgrading towards high added value products.

Suggested Citation

  • Konstantinos G. Kalogiannis & Leonidas Matsakas & Angelos A. Lappas & Ulrika Rova & Paul Christakopoulos, 2019. "Aromatics from Beechwood Organosolv Lignin through Thermal and Catalytic Pyrolysis," Energies, MDPI, vol. 12(9), pages 1-11, April.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:9:p:1606-:d:226455
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    References listed on IDEAS

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    1. Puri, Munish & Abraham, Reinu E. & Barrow, Colin J., 2012. "Biofuel production: Prospects, challenges and feedstock in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 6022-6031.
    2. Azadi, Pooya & Inderwildi, Oliver R. & Farnood, Ramin & King, David A., 2013. "Liquid fuels, hydrogen and chemicals from lignin: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 506-523.
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    1. Min Wei & Fu Yang & Xuyan Song & Ran Li & Xi Pan & Qiang Gao & Yunlu He & Mingqiao Ye & Hongyun Hu, 2020. "Extraction of Nitrogen Compounds from Tobacco Waste via Thermal Treatment," Energies, MDPI, vol. 13(18), pages 1-11, September.
    2. Zhongyang Luo & Qian Qian & Haoran Sun & Qi Wei & Jinsong Zhou & Kaige Wang, 2022. "Lignin-First Biorefinery for Converting Lignocellulosic Biomass into Fuels and Chemicals," Energies, MDPI, vol. 16(1), pages 1-25, December.
    3. Sergio Suárez & Jose Guillermo Rosas & Marta Elena Sánchez & Roberto López & Natalia Gómez & Jorge Cara-Jiménez, 2019. "Parametrization of a Modified Friedman Kinetic Method to Assess Vine Wood Pyrolysis Using Thermogravimetric Analysis," Energies, MDPI, vol. 12(13), pages 1-14, July.

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