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Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries

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  • Kirtika Kohli

    (Prairie Research Institute—Illinois Sustainable Technology Center, University of Illinois, Urbana Champaign, IL 61820, USA)

  • Ravindra Prajapati

    (Conversions & Catalysis Division, CSIR-Indian Institute of Petroleum, Dehradun, Uttarakhand 248005, India)

  • Brajendra K. Sharma

    (Prairie Research Institute—Illinois Sustainable Technology Center, University of Illinois, Urbana Champaign, IL 61820, USA)

Abstract

The production of chemicals from biomass, a renewable feedstock, is highly desirable in replacing petrochemicals to make biorefineries more economical. The best approach to compete with fossil-based refineries is the upgradation of biomass in integrated biorefineries. The integrated biorefineries employed various biomass feedstocks and conversion technologies to produce biofuels and bio-based chemicals. Bio-based chemicals can help to replace a large fraction of industrial chemicals and materials from fossil resources. Biomass-derived chemicals, such as 5-hydroxymethylfurfural (5-HMF), levulinic acid, furfurals, sugar alcohols, lactic acid, succinic acid, and phenols, are considered platform chemicals. These platform chemicals can be further used for the production of a variety of important chemicals on an industrial scale. However, current industrial production relies on relatively old and inefficient strategies and low production yields, which have decreased their competitiveness with fossil-based alternatives. The aim of the presented review is to provide a survey of past and current strategies used to achieve a sustainable conversion of biomass to platform chemicals. This review provides an overview of the chemicals obtained, based on the major components of lignocellulosic biomass, sugars, and lignin. First, important platform chemicals derived from the catalytic conversion of biomass were outlined. Later, the targeted chemicals that can be potentially manufactured from the starting or platform materials were discussed in detail. Despite significant advances, however, low yields, complex multistep synthesis processes, difficulties in purification, high costs, and the deactivation of catalysts are still hurdles for large-scale competitive biorefineries. These challenges could be overcome by single-step catalytic conversions using highly efficient and selective catalysts and exploring purification and separation technologies.

Suggested Citation

  • Kirtika Kohli & Ravindra Prajapati & Brajendra K. Sharma, 2019. "Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries," Energies, MDPI, vol. 12(2), pages 1-40, January.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:2:p:233-:d:197328
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    References listed on IDEAS

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    2. Cai, Xin & Wang, Zhichao & Ye, Yueyuan & Wang, Duo & Zhang, Zhaoxia & Zheng, Zhifeng & Liu, Yunquan & Li, Shuirong, 2021. "Conversion of chitin biomass into 5-hydroxymethylfurfural: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
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    4. Pomeroy, Brett & Grilc, Miha & Likozar, Blaž, 2022. "Artificial neural networks for bio-based chemical production or biorefining: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    5. Aristide Giuliano, 2023. "The Transition of Scientific Research from Biomass-to-Energy/Biofuels to Biomass-to-Biochemicals in a Biorefinery Systems Framework," Energies, MDPI, vol. 16(5), pages 1-4, February.
    6. Ibrahim, Qusay & Arauzo, Pablo J. & Kruse, Andrea, 2020. "The effect of using different acids to catalyze the prehydrolysis stage on the organosolv delignification of beech wood in two-stage process," Renewable Energy, Elsevier, vol. 153(C), pages 1479-1487.
    7. Guzelciftci, Begum & Park, Ki-Bum & Kim, Joo-Sik, 2020. "Production of phenol-rich bio-oil via a two-stage pyrolysis of wood," Energy, Elsevier, vol. 200(C).
    8. Zhou, Qiaoqiao & Liu, Zhenyu & Wu, Ta Yeong & Zhang, Lian, 2023. "Furfural from pyrolysis of agroforestry waste: Critical factors for utilisation of C5 and C6 sugars," Renewable and Sustainable Energy Reviews, Elsevier, vol. 176(C).
    9. Martyna Przydacz & Marcin Jędrzejczyk & Jacek Rogowski & Małgorzata Szynkowska-Jóźwik & Agnieszka M. Ruppert, 2020. "Highly Efficient Production of DMF from Biomass-Derived HMF on Recyclable Ni-Fe/TiO 2 Catalysts," Energies, MDPI, vol. 13(18), pages 1-14, September.
    10. Bartolucci, L. & Cordiner, S. & Di Carlo, A. & Gallifuoco, A. & Mele, P. & Mulone, V., 2024. "Platform chemicals recovery from spent coffee grounds aqueous-phase pyrolysis oil," Renewable Energy, Elsevier, vol. 220(C).
    11. Akinola David Olugbemide & Ana Oberlintner & Uroš Novak & Blaž Likozar, 2021. "Lignocellulosic Corn Stover Biomass Pre-Treatment by Deep Eutectic Solvents (DES) for Biomethane Production Process by Bioresource Anaerobic Digestion," Sustainability, MDPI, vol. 13(19), pages 1-13, September.
    12. Bogusława Waliszewska & Mieczysław Grzelak & Eliza Gaweł & Agnieszka Spek-Dźwigała & Agnieszka Sieradzka & Wojciech Czekała, 2021. "Chemical Characteristics of Selected Grass Species from Polish Meadows and Their Potential Utilization for Energy Generation Purposes," Energies, MDPI, vol. 14(6), pages 1-14, March.
    13. Sigrid Kusch-Brandt & Mohammad A. T. Alsheyab, 2021. "Wastewater Refinery: Producing Multiple Valuable Outputs from Wastewater," J, MDPI, vol. 4(1), pages 1-11, February.
    14. Zhou, Man & Fakayode, Olugbenga Abiola & Ahmed Yagoub, Abu ElGasim & Ji, Qinghua & Zhou, Cunshan, 2022. "Lignin fractionation from lignocellulosic biomass using deep eutectic solvents and its valorization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 156(C).
    15. Parvez, Ashak Mahmud & Lewis, Jonathan David & Afzal, Muhammad T., 2021. "Potential of industrial hemp (Cannabis sativa L.) for bioenergy production in Canada: Status, challenges and outlook," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    16. Nneka B. Ekwe & Maksim V. Tyufekchiev & Ali A. Salifu & Klaus Schmidt-Rohr & Zhaoxi Zheng & Alex R. Maag & Geoffrey A. Tompsett & Charles M. Cai & Emmanuel O. Onche & Ayten Ates & Winston O. Soboyejo , 2022. "Bamboo as a Cost-Effective Source of Renewable Carbon for Sustainable Economic Development in Low- and Middle-Income Economies," Energies, MDPI, vol. 16(1), pages 1-17, December.
    17. Thombal, Priyanka Raju & Thombal, Raju S. & Han, Sung Soo, 2021. "Comprehensive study on the catalytic methods for furyl alkane synthesis: A promising biodiesel precursor," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).

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