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Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review

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  • Agarwal, Bhumica
  • Kailasam, Kamalakannan
  • Sangwan, Rajender Singh
  • Elumalai, Sasikumar

Abstract

5-Hydroxymethylfurfural (HMF) belongs to the group of “drop-in biofuels” and platform molecule of prime importance. Synthesis of HMF from various sugar sources has traversed a long span of time and has witnessed various modifications viz., use of heterogeneous catalysts over homogeneous catalysts, employment of organic phase over aqueous, introduction of biphasic systems to overcome side reaction limitations and still counting. Every modification has been carried out with the objective of improved selectivity and product synthesis, cost and energy optimization, and a shift towards greener process over existing methods. Use of lignocellulosic biomass instead of commercial sugars also finds applicability in direct HMF synthesis along with levulinic acid, furfural etc. However, low yields from these abundant, cheap and readily available sugar sources are still ideal for scale-up of the process strategies. Among large pool of studies available in this area, current review presents the advantages imparted towards HMF synthesis with the advent of heterogeneous catalysis over the course of time and various reaction systems evolved to meet the steeping demand of HMF, specifically from common carbohydrate sources. Special attention has been paid to understand the mechanism of modifications imparted to various solid catalysts for improved HMF synthesis.

Suggested Citation

  • Agarwal, Bhumica & Kailasam, Kamalakannan & Sangwan, Rajender Singh & Elumalai, Sasikumar, 2018. "Traversing the history of solid catalysts for heterogeneous synthesis of 5-hydroxymethylfurfural from carbohydrate sugars: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2408-2425.
    • Handle: RePEc:eee:rensus:v:82:y:2018:i:p3:p:2408-2425
    DOI: 10.1016/j.rser.2017.08.088
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    References listed on IDEAS

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    1. Alipour, Siamak & Omidvarborna, Hamid & Kim, Dong-Shik, 2017. "A review on synthesis of alkoxymethyl furfural, a biofuel candidate," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 908-926.
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    1. Yang, Fengli & Weng, Jushi & Ding, Jiajing & Zhao, Zhiyan & Qin, Lizhen & Xia, Feifei, 2020. "Effective conversion of saccharides into hydroxymethylfurfural catalyzed by a natural clay, attapulgite," Renewable Energy, Elsevier, vol. 151(C), pages 829-836.
    2. Wang, Ping & Liu, Chaoqi & Chang, Juan & Yin, Qingqiang & Huang, Weiwei & Liu, Yang & Dang, Xiaowei & Gao, Tianzeng & Lu, Fushan, 2019. "Effect of physicochemical pretreatments plus enzymatic hydrolysis on the composition and morphologic structure of corn straw," Renewable Energy, Elsevier, vol. 138(C), pages 502-508.
    3. Tuan Hoang, Anh & Viet Pham, Van, 2021. "2-Methylfuran (MF) as a potential biofuel: A thorough review on the production pathway from biomass, combustion progress, and application in engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    4. Hu, Lei & Wu, Zhen & Jiang, Yetao & Wang, Xiaoyu & He, Aiyong & Song, Jie & Xu, Jiming & Zhou, Shouyong & Zhao, Yijiang & Xu, Jiaxing, 2020. "Recent advances in catalytic and autocatalytic production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    5. Cai, Xin & Wang, Zhichao & Ye, Yueyuan & Wang, Duo & Zhang, Zhaoxia & Zheng, Zhifeng & Liu, Yunquan & Li, Shuirong, 2021. "Conversion of chitin biomass into 5-hydroxymethylfurfural: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    6. Zhao, Yuan & Lu, Kaifeng & Xu, Hao & Zhu, Lingjun & Wang, Shurong, 2021. "A critical review of recent advances in the production of furfural and 5-hydroxymethylfurfural from lignocellulosic biomass through homogeneous catalytic hydrothermal conversion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    7. Daniel Carreira Batalha & Márcio José da Silva, 2021. "Biodiesel Production over Niobium-Containing Catalysts: A Review," Energies, MDPI, vol. 14(17), pages 1-33, September.
    8. Zuo, Miao & Jia, Wenlong & Feng, Yunchao & Zeng, Xianhai & Tang, Xing & Sun, Yong & Lin, Lu, 2021. "Effective selectivity conversion of glucose to furan chemicals in the aqueous deep eutectic solvent," Renewable Energy, Elsevier, vol. 164(C), pages 23-33.
    9. Wiranarongkorn, K. & Im-orb, K. & Patcharavorachot, Y. & Maréchal, F. & Arpornwichanop, A., 2023. "Comparative techno-economic and energy analyses of integrated biorefinery processes of furfural and 5-hydroxymethylfurfural from biomass residue," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    10. Kirtika Kohli & Ravindra Prajapati & Brajendra K. Sharma, 2019. "Bio-Based Chemicals from Renewable Biomass for Integrated Biorefineries," Energies, MDPI, vol. 12(2), pages 1-40, January.
    11. Hu, Di & Zhang, Man & Xu, Hong & Wang, Yuchen & Yan, Kai, 2021. "Recent advance on the catalytic system for efficient production of biomass-derived 5-hydroxymethylfurfural," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).

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