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Pyrolysis liquids and gases as alternative fuels in internal combustion engines – A review

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  • Hossain, A.K.
  • Davies, P.A.

Abstract

Liquids and gases produced through biomass pyrolysis have potential as renewable fuels to replace fossil fuels in conventional internal combustion engines. This review compares the properties of pyrolysis fuels, produced from a variety of feedstocks and using different pyrolysis techniques, against those of fossil fuels. High acidity, the presence of solid particles, high water content, high viscosity, storage and thermal instability, and low energy content are typical characteristics of pyrolysis liquids. A survey of combustion, performance and exhaust emission results from the use of pyrolysis liquids (both crude and up-graded) in compression ignition engines is presented. With only a few exceptions, most authors have reported difficulties associated with the adverse properties of pyrolysis liquids, including: corrosion and clogging of the injectors, long ignition delay and short combustion duration, difficulty in engine start-up, unstable operation, coking of the piston and cylinders and subsequent engine seizure. Pyrolysis gas can be used more readily, either in spark ignition or compression ignition engines; however, NOx reduction techniques are desirable. Various approaches to improve the properties of pyrolysis liquids are discussed and a comparison of the properties of up-graded vs. crude pyrolysis liquid is included. Further developments in up-gradation techniques, such as hydrocracking and bio-refinery approaches, could lead to the production of green diesel and green gasoline. Modifications required to engines for use with pyrolysis liquids, for example in the fuel supply and injection systems, are discussed. Storage stability and economic issues are also reviewed. Our study presents recent progress and important R&D areas for successful future use of pyrolysis fuels in internal combustion engines.

Suggested Citation

  • Hossain, A.K. & Davies, P.A., 2013. "Pyrolysis liquids and gases as alternative fuels in internal combustion engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 165-189.
    • Handle: RePEc:eee:rensus:v:21:y:2013:i:c:p:165-189
    DOI: 10.1016/j.rser.2012.12.031
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    1. Park, Young-Kwon & Yoo, Myung Lang & Lee, Hyung Won & Park, Sung Hoon & Jung, Sang-Chul & Park, Sang-Sook & Kim, Sang-Chai, 2012. "Effects of operation conditions on pyrolysis characteristics of agricultural residues," Renewable Energy, Elsevier, vol. 42(C), pages 125-130.
    2. Sulaiman, F. & Abdullah, N., 2011. "Optimum conditions for maximising pyrolysis liquids of oil palm empty fruit bunches," Energy, Elsevier, vol. 36(5), pages 2352-2359.
    3. Ganesh, Anuradda & Banerjee, Rangan, 2001. "Biomass pyrolysis for power generation — a potential technology," Renewable Energy, Elsevier, vol. 22(1), pages 9-14.
    4. Goyal, H.B. & Seal, Diptendu & Saxena, R.C., 2008. "Bio-fuels from thermochemical conversion of renewable resources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 504-517, February.
    5. Hoefnagels, Ric & Smeets, Edward & Faaij, André, 2010. "Greenhouse gas footprints of different biofuel production systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(7), pages 1661-1694, September.
    6. A.V. Bridgwater & P. Carson & M. Coulson, 2007. "A comparison of fast and slow pyrolysis liquids from mallee," International Journal of Global Energy Issues, Inderscience Enterprises Ltd, vol. 27(2), pages 204-216.
    7. Bridgwater, A. V. & Toft, A. J. & Brammer, J. G., 2002. "A techno-economic comparison of power production by biomass fast pyrolysis with gasification and combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 6(3), pages 181-246, September.
    8. Chiaramonti, David & Oasmaa, Anja & Solantausta, Yrjö, 2007. "Power generation using fast pyrolysis liquids from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1056-1086, August.
    9. Van de Beld, Bert & Holle, Elmar & Florijn, Jan, 2013. "The use of pyrolysis oil and pyrolysis oil derived fuels in diesel engines for CHP applications," Applied Energy, Elsevier, vol. 102(C), pages 190-197.
    10. Beis, S.H. & Onay, Ö. & Koçkar, Ö.M., 2002. "Fixed-bed pyrolysis of safflower seed: influence of pyrolysis parameters on product yields and compositions," Renewable Energy, Elsevier, vol. 26(1), pages 21-32.
    11. Ioannidou, O. & Zabaniotou, A. & Antonakou, E.V. & Papazisi, K.M. & Lappas, A.A. & Athanassiou, C., 2009. "Investigating the potential for energy, fuel, materials and chemicals production from corn residues (cobs and stalks) by non-catalytic and catalytic pyrolysis in two reactor configurations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(4), pages 750-762, May.
    12. Zhang, Hongmei & Wang, Jun, 2006. "Combustion characteristics of a diesel engine operated with diesel and burning oil of biomass," Renewable Energy, Elsevier, vol. 31(7), pages 1025-1032.
    13. Choi, Hang Seok & Choi, Yeon Seok & Park, Hoon Chae, 2012. "Fast pyrolysis characteristics of lignocellulosic biomass with varying reaction conditions," Renewable Energy, Elsevier, vol. 42(C), pages 131-135.
    14. Özbay, N & Pütün, A.E & Uzun, B.B & Pütün, E, 2001. "Biocrude from biomass: pyrolysis of cottonseed cake," Renewable Energy, Elsevier, vol. 24(3), pages 615-625.
    15. Demirbas, Ayhan, 2011. "Competitive liquid biofuels from biomass," Applied Energy, Elsevier, vol. 88(1), pages 17-28, January.
    16. Williams, Paul T & Nugranad, Nittaya, 2000. "Comparison of products from the pyrolysis and catalytic pyrolysis of rice husks," Energy, Elsevier, vol. 25(6), pages 493-513.
    17. Hossain, A.K. & Davies, P.A., 2010. "Plant oils as fuels for compression ignition engines: A technical review and life-cycle analysis," Renewable Energy, Elsevier, vol. 35(1), pages 1-13.
    18. Faaij, Andre P.C., 2006. "Bio-energy in Europe: changing technology choices," Energy Policy, Elsevier, vol. 34(3), pages 322-342, February.
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