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Rechargeable Zn-air batteries: Recent trends and future perspectives

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  • Leong, Kee Wah
  • Wang, Yifei
  • Ni, Meng
  • Pan, Wending
  • Luo, Shijing
  • Leung, Dennis Y.C.

Abstract

Currently a hot research topic, rechargeable zinc-air batteries are considered one of the most promising post lithium-ion battery technologies for utility-scale energy storage, electric vehicles, and other consumer electronics. Nevertheless, despite a high energy density, low cost, and material abundance, the development of alkaline-based Zn-air batteries has been hampered by parasitic reactions at the Zn anode and sluggish oxygen redox kinetics. This article will review the current status of Zn-air batteries, discuss recent development trends including neutral and hybrid Zn-air batteries, and highlight future research needs. Specifically, an analysis of the latest publications will show that, through redesigning the anode, introducing alternative electrolytes, and engineering high-performing bifunctional oxygen catalysts, researchers have successfully prolonged the battery reversibility to a few thousand cycles and reached unprecedented energy efficiencies over 70%. Although unsolved obstacles remain, these strategies have opened up interesting possibilities in the advancement of rechargeable Zn-air batteries, creating promising prospects for the energy and electronics industries.

Suggested Citation

  • Leong, Kee Wah & Wang, Yifei & Ni, Meng & Pan, Wending & Luo, Shijing & Leung, Dennis Y.C., 2022. "Rechargeable Zn-air batteries: Recent trends and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    • Handle: RePEc:eee:rensus:v:154:y:2022:i:c:s1364032121010406
    DOI: 10.1016/j.rser.2021.111771
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    References listed on IDEAS

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    1. Yong-Sheng Hu, 2016. "Batteries: Getting solid," Nature Energy, Nature, vol. 1(4), pages 1-2, April.
    2. Yazhou Zhou & Xiafang Tao & Guangbo Chen & Ruihu Lu & Ding Wang & Ming-Xi Chen & Enquan Jin & Juan Yang & Hai-Wei Liang & Yan Zhao & Xinliang Feng & Akimitsu Narita & Klaus Müllen, 2020. "Multilayer stabilization for fabricating high-loading single-atom catalysts," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    3. Xiaorui Liu & Yifei Yuan & Jie Liu & Bin Liu & Xu Chen & Jia Ding & Xiaopeng Han & Yida Deng & Cheng Zhong & Wenbin Hu, 2019. "Utilizing solar energy to improve the oxygen evolution reaction kinetics in zinc–air battery," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
    4. Rui Lang & Wei Xi & Jin-Cheng Liu & Yi-Tao Cui & Tianbo Li & Adam Fraser Lee & Fang Chen & Yang Chen & Lei Li & Lin Li & Jian Lin & Shu Miao & Xiaoyan Liu & Ai-Qin Wang & Xiaodong Wang & Jun Luo & Bot, 2019. "Non defect-stabilized thermally stable single-atom catalyst," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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    Cited by:

    1. Abdul Ghani Olabi & Enas Taha Sayed & Tabbi Wilberforce & Aisha Jamal & Abdul Hai Alami & Khaled Elsaid & Shek Mohammod Atiqure Rahman & Sheikh Khaleduzzaman Shah & Mohammad Ali Abdelkareem, 2021. "Metal-Air Batteries—A Review," Energies, MDPI, vol. 14(21), pages 1-46, November.
    2. Kadam, Nishad & Sarkar, A., 2023. "A high voltage zinc–air battery with two isolated electrolytes and moving auxiliary electrodes," Applied Energy, Elsevier, vol. 344(C).

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