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Influencing Factors of Performance Degradation of Zinc–Air Batteries Exposed to Air

Author

Listed:
  • Yuwei Zhong

    (Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)

  • Bin Liu

    (Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)

  • Zequan Zhao

    (Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)

  • Yuanhao Shen

    (Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)

  • Xiaorui Liu

    (Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)

  • Cheng Zhong

    (Key Laboratory of Advanced Ceramics and Machining Technology (Ministry of Education), Tianjin Key Laboratory of Composite and Functional Materials, School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China)

Abstract

Zinc–air batteries feature high energy density, but they usually suffer from their short storage life after they start working, restricting their commercial applications. In the past, scholars did not reach an agreement on the influencing factors of the performance degradation of zinc–air batteries when exposed to air. Here, a series of comparative experiments were conducted to confirm the changes of the battery during storage after being exposed to air. The morphology and composition of the components of the battery were characterized by scanning electron microscopy (SEM) and X-ray diffraction analyses. SEM images revealed that with the increase of storage days, the corrosion of the zinc anode gradually deepens, but the surface morphology of the air cathode does not change much. The electrolyte of the batteries stored for different periods was examined through inductively coupled plasma spectroscopy and titration. After 20 days of storage, the concentration of CO 3 2− reached 2.694 mol L −1 , which indicates that more than 80% of the OH − in the electrolyte was consumed. The results show that after being exposed to air, the carbonation of the electrolyte is the main cause of the battery capacity decay.

Suggested Citation

  • Yuwei Zhong & Bin Liu & Zequan Zhao & Yuanhao Shen & Xiaorui Liu & Cheng Zhong, 2021. "Influencing Factors of Performance Degradation of Zinc–Air Batteries Exposed to Air," Energies, MDPI, vol. 14(9), pages 1-11, May.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:9:p:2607-:d:548087
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    References listed on IDEAS

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    1. Pei, Pucheng & Wang, Keliang & Ma, Ze, 2014. "Technologies for extending zinc–air battery’s cyclelife: A review," Applied Energy, Elsevier, vol. 128(C), pages 315-324.
    2. Xiaorui Liu & Yifei Yuan & Jie Liu & Bin Liu & Xu Chen & Jia Ding & Xiaopeng Han & Yida Deng & Cheng Zhong & Wenbin Hu, 2019. "Utilizing solar energy to improve the oxygen evolution reaction kinetics in zinc–air battery," Nature Communications, Nature, vol. 10(1), pages 1-10, December.
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