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Optimization of the Electrolyte Parameters and Components in Zinc Particle Fuel Cells

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  • Thangavel Sangeetha

    (Department of Energy and Refrigerating Air-Conditioning Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
    Research Center of Energy Conservation for New Generation of Residential, Commercial, and Industrial Sectors, National Taipei University of Technology, Taipei 10608, Taiwan
    These authors contributed equally to this work (TS and PTC).)

  • Po-Tuan Chen

    (Center for Condensed Matter Sciences, National Taiwan University, Taipei 10617, Taiwan
    These authors contributed equally to this work (TS and PTC).)

  • Wu-Fu Cheng

    (Department of Vehicle Engineering, National Taipei University of Technology, Taipei 10608, Taiwan)

  • Wei-Mon Yan

    (Department of Energy and Refrigerating Air-Conditioning Engineering, National Taipei University of Technology, Taipei 10608, Taiwan
    Research Center of Energy Conservation for New Generation of Residential, Commercial, and Industrial Sectors, National Taipei University of Technology, Taipei 10608, Taiwan)

  • K. David Huang

    (Department of Vehicle Engineering, National Taipei University of Technology, Taipei 10608, Taiwan)

Abstract

Zinc (Zn)-air fuel cells (ZAFC) are a widely-acknowledged type of metal air fuel cells, but optimization of several operational parameters and components will facilitate enhanced power performance. This research study has been focused on the investigation of ZAFC Zn particle fuel with flowing potassium hydroxide (KOH) electrolyte. Parameters like optimum electrolyte concentration, temperature, and flow velocity were optimized. Moreover, ZAFC components like anode current collector and cathode conductor material were varied and the appropriate materials were designated. Power performance was analyzed in terms of open circuit voltage (OCV), power, and current density production and were used to justify the results of the study. The flow rate of the electrolyte was determined as 150 mL/min in the self-designed configuration. KOH electrolyte of 40 wt% concentration, at a temperature of 55 to 65 ℃, and with a flow velocity of 0.12 m/s was considered to be beneficial for the ZAFCs operated in this study. Nickel mesh with a surface area of 400 cm 2 was chosen as anode current collector and copper plate was considered as cathode conductor material in the fuel cells designed and operated in this study. The power production of this study was better compared to some previously published works. Thus, effective enhancement and upgrading process of the ZAFCs will definitely provide great opportunities for their applications in the future.

Suggested Citation

  • Thangavel Sangeetha & Po-Tuan Chen & Wu-Fu Cheng & Wei-Mon Yan & K. David Huang, 2019. "Optimization of the Electrolyte Parameters and Components in Zinc Particle Fuel Cells," Energies, MDPI, vol. 12(6), pages 1-13, March.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:6:p:1090-:d:215935
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    References listed on IDEAS

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    1. Wang, Chin-Tsan & Huang, Yan-Sian & Sangeetha, Thangavel & Yan, Wei-Mon, 2018. "Assessment of recirculation batch mode operation in bufferless Bio-cathode microbial Fuel Cells (MFCs)," Applied Energy, Elsevier, vol. 209(C), pages 120-126.
    2. K. David Huang & Thangavel Sangeetha & Wu-Fu Cheng & Chunyo Lin & Po-Tuan Chen, 2018. "Computational Fluid Dynamics Approach for Performance Prediction in a Zinc–Air Fuel Cell," Energies, MDPI, vol. 11(9), pages 1-13, August.
    3. Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    4. Pei, Pucheng & Wang, Keliang & Ma, Ze, 2014. "Technologies for extending zinc–air battery’s cyclelife: A review," Applied Energy, Elsevier, vol. 128(C), pages 315-324.
    5. Arenas, Luis F. & Loh, Adeline & Trudgeon, David P. & Li, Xiaohong & Ponce de León, Carlos & Walsh, Frank C., 2018. "The characteristics and performance of hybrid redox flow batteries with zinc negative electrodes for energy storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 992-1016.
    6. Yan-Ming Chen & Chin-Tsan Wang & Yung-Chin Yang, 2018. "Effect of Wall Boundary Layer Thickness on Power Performance of a Recirculation Microbial Fuel Cell," Energies, MDPI, vol. 11(4), pages 1-11, April.
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    Cited by:

    1. Sangeetha, Thangavel & Chen, Po-Tuan & Yan, Wei-Mon & Huang, K. David, 2020. "Enhancement of air-flow management in Zn-air fuel cells by the optimization of air-flow parameters," Energy, Elsevier, vol. 197(C).

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