IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v251y2019ic96.html
   My bibliography  Save this article

Bifunctional electrocatalytic activity of La0.8Sr0.2MnO3-based perovskite with the A-site deficiency for oxygen reduction and evolution reactions in alkaline media

Author

Listed:
  • Yuan, Rong-hua
  • He, Yun
  • He, Wei
  • Ni, Meng
  • Leung, Michael K.H.

Abstract

The development of efficient noble-metal free electrocatalysts for oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is of great importance for energy storage devices, such as fuel cell and zinc-air battery. In this work, we report a facile approach to enhance the electrocatalytic activity of La0.8Sr0.2MnO3-based perovskite by introducing the deficiency in the A-site and transition-metal Fe in the B-site. Bifunctional electrocatalysts La0.8Sr0.2MnO3, (La0.8Sr0.2)0.98MnO3, (La0.8Sr0.2)0.95MnO3 and (La0.8Sr0.2)0.95Mn0.5Fe0.5O3 were prepared by a facile sol–gel process. The material characterization results showed that compared with La0.8Sr0.2MnO3, (La0.8Sr0.2)0.98MnO3 and (La0.8Sr0.2)0.95MnO3 have smaller particle size, more oxygen vacancies and proper Mn valence, which will benefit both ORR and OER. The results were verified by testing the electrocatalytic activities using rotating-disk electrode (RDE) in alkaline media. For the perovskite oxides with only A-site cation deficiency, the bifunctional electrocatalytic activities increase in the following order: La0.8Sr0.2MnO3 < (La0.8Sr0.2)0.98MnO3 < (La0.8Sr0.2)0.95MnO3. With partial substitution of Mn by Fe in the B-site, the (La0.8Sr0.2)0.95Mn0.5Fe0.5O3 perovskite oxide exhibits even better electrocatalytic activity. Further experiments reveal that (La0.8Sr0.2)0.95Mn0.5Fe0.5O3 has the highest current density (4.5 mA cm−2) in ORR which is comparable to commercial Pt/C (5 mA cm−2) and the enhancement of the OER is more obvious than that of the ORR. Subsequently, the perovskite samples were used as the cathode catalysts in zinc-air batteries. The results further prove that proper use of A-site deficiency and B-site Fe doping in perovskite oxides can boost up the electrocatalytic activities.

Suggested Citation

  • Yuan, Rong-hua & He, Yun & He, Wei & Ni, Meng & Leung, Michael K.H., 2019. "Bifunctional electrocatalytic activity of La0.8Sr0.2MnO3-based perovskite with the A-site deficiency for oxygen reduction and evolution reactions in alkaline media," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    • Handle: RePEc:eee:appene:v:251:y:2019:i:c:96
    DOI: 10.1016/j.apenergy.2019.113406
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919310803
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.113406?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Pei, Pucheng & Wang, Keliang & Ma, Ze, 2014. "Technologies for extending zinc–air battery’s cyclelife: A review," Applied Energy, Elsevier, vol. 128(C), pages 315-324.
    2. Xu, Nengneng & Qiao, Jinli & Zhang, Xia & Ma, Chengyu & Jian, Saiai & Liu, Yuyu & Pei, Pucheng, 2016. "Morphology controlled La2O3/Co3O4/MnO2–CNTs hybrid nanocomposites with durable bi-functional air electrode in high-performance zinc–air energy storage," Applied Energy, Elsevier, vol. 175(C), pages 495-504.
    3. Karim, N.A. & Kamarudin, S.K., 2013. "An overview on non-platinum cathode catalysts for direct methanol fuel cell," Applied Energy, Elsevier, vol. 103(C), pages 212-220.
    4. Tang, Sheng & Zhou, Xuejun & Xu, Nengneng & Bai, Zhengyu & Qiao, Jinli & Zhang, Jiujun, 2016. "Template-free synthesis of three-dimensional nanoporous N-doped graphene for high performance fuel cell oxygen reduction reaction in alkaline media," Applied Energy, Elsevier, vol. 175(C), pages 405-413.
    5. Chao, Shujun & Zhang, Yatian & Wang, Kui & Bai, Zhengyu & Yang, Lin, 2016. "Flower–like Ni and N codoped hierarchical porous carbon microspheres with enhanced performance for fuel cell storage," Applied Energy, Elsevier, vol. 175(C), pages 421-428.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Pan, Lyuming & Chen, Dongfang & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "A novel structural design of air cathodes expanding three-phase reaction interfaces for zinc-air batteries," Applied Energy, Elsevier, vol. 290(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhong, Kengqiang & Li, Meng & Yang, Yue & Zhang, Hongguo & Zhang, Bopeng & Tang, Jinfeng & Yan, Jia & Su, Minhua & Yang, Zhiquan, 2019. "Nitrogen-doped biochar derived from watermelon rind as oxygen reduction catalyst in air cathode microbial fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 516-525.
    2. Pei, Pucheng & Huang, Shangwei & Chen, Dongfang & Li, Yuehua & Wu, Ziyao & Ren, Peng & Wang, Keliang & Jia, Xiaoning, 2019. "A high-energy-density and long-stable-performance zinc-air fuel cell system," Applied Energy, Elsevier, vol. 241(C), pages 124-129.
    3. She, Yiyi & Chen, Jinfan & Zhang, Chengxu & Lu, Zhouguang & Ni, Meng & Sit, Patrick H.-L. & Leung, Michael K.H., 2018. "Nitrogen-doped graphene derived from ionic liquid as metal-free catalyst for oxygen reduction reaction and its mechanisms," Applied Energy, Elsevier, vol. 225(C), pages 513-521.
    4. Wang, Keliang & Pei, Pucheng & Wang, Yichun & Liao, Cheng & Wang, Wei & Huang, Shangwei, 2018. "Advanced rechargeable zinc-air battery with parameter optimization," Applied Energy, Elsevier, vol. 225(C), pages 848-856.
    5. Wu, Mingjie & Zhang, Enguang & Guo, Qinping & Wang, Yongzhen & Qiao, Jinli & Li, Kaixi & Pei, Pucheng, 2016. "N/S-Me (Fe, Co, Ni) doped hierarchical porous carbons for fuel cell oxygen reduction reaction with high catalytic activity and long-term stability," Applied Energy, Elsevier, vol. 175(C), pages 468-478.
    6. Sangeetha, Thangavel & Chen, Po-Tuan & Yan, Wei-Mon & Huang, K. David, 2020. "Enhancement of air-flow management in Zn-air fuel cells by the optimization of air-flow parameters," Energy, Elsevier, vol. 197(C).
    7. Nandan, Ravi & Goswami, Gopal Krishna & Nanda, Karuna Kar, 2017. "Direct synthesis of Pt-free catalyst on gas diffusion layer of fuel cell and usage of high boiling point fuels for efficient utilization of waste heat," Applied Energy, Elsevier, vol. 205(C), pages 1050-1058.
    8. Liu, Guicheng & Li, Xinyang & Wang, Hui & Liu, Xiuying & Chen, Ming & Woo, Jae Young & Kim, Ji Young & Wang, Xindong & Lee, Joong Kee, 2017. "Design of 3-electrode system for in situ monitoring direct methanol fuel cells during long-time running test at high temperature," Applied Energy, Elsevier, vol. 197(C), pages 163-168.
    9. Chen, Dongfang & Pan, Lyuming & Pei, Pucheng & Huang, Shangwei & Ren, Peng & Song, Xin, 2021. "Carbon-coated oxygen vacancies-rich Co3O4 nanoarrays grow on nickel foam as efficient bifunctional electrocatalysts for rechargeable zinc-air batteries," Energy, Elsevier, vol. 224(C).
    10. Kiyani, Roya & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Nitrogen doped graphene supported palladium-cobalt as a promising catalyst for methanol oxidation reaction: Synthesis, characterization and electrocatalytic performance," Energy, Elsevier, vol. 113(C), pages 1162-1173.
    11. Song, Xingjuan & Zhang, Dongming, 2014. "Bimetallic Ag–Ni/C particles as cathode catalyst in AFCs (alkaline fuel cells)," Energy, Elsevier, vol. 70(C), pages 223-230.
    12. Zhou, Xuejun & Tang, Sheng & Yin, Yan & Sun, Shuihui & Qiao, Jinli, 2016. "Hierarchical porous N-doped graphene foams with superior oxygen reduction reactivity for polymer electrolyte membrane fuel cells," Applied Energy, Elsevier, vol. 175(C), pages 459-467.
    13. Kim, Joon-Hee & Yang, Min-Jee & Park, Jun-Young, 2014. "Improvement on performance and efficiency of direct methanol fuel cells using hydrocarbon-based membrane electrode assembly," Applied Energy, Elsevier, vol. 115(C), pages 95-102.
    14. Halima Alnaqbi & Oussama El-Kadri & Mohammad Ali Abdelkareem & Sameer Al-Asheh, 2022. "Recent Progress in Metal-Organic Framework-Derived Chalcogenides (MX; X = S, Se) as Electrode Materials for Supercapacitors and Catalysts in Fuel Cells," Energies, MDPI, vol. 15(21), pages 1-25, November.
    15. Jung, Chi-Young & Kim, Tae-Hyun & Kim, Wha-Jung & Yi, Sung-Chul, 2016. "Computational analysis of the zinc utilization in the primary zinc-air batteries," Energy, Elsevier, vol. 102(C), pages 694-704.
    16. Abdul Ghani Olabi & Enas Taha Sayed & Tabbi Wilberforce & Aisha Jamal & Abdul Hai Alami & Khaled Elsaid & Shek Mohammod Atiqure Rahman & Sheikh Khaleduzzaman Shah & Mohammad Ali Abdelkareem, 2021. "Metal-Air Batteries—A Review," Energies, MDPI, vol. 14(21), pages 1-46, November.
    17. Liu, Zhenning & Li, Zhiyuan & Ma, Jian & Dong, Xu & Ku, Wen & Wang, Mi & Sun, Hang & Liang, Song & Lu, Guolong, 2018. "Nitrogen and cobalt-doped porous biocarbon materials derived from corn stover as efficient electrocatalysts for aluminum-air batteries," Energy, Elsevier, vol. 162(C), pages 453-459.
    18. Trocino, Stefano & Lo Faro, Massimiliano & Zignani, Sabrina Campagna & Antonucci, Vincenzo & Aricò, Antonino Salvatore, 2019. "High performance solid-state iron-air rechargeable ceramic battery operating at intermediate temperatures (500–650 °C)," Applied Energy, Elsevier, vol. 233, pages 386-394.
    19. Wenger, Erez & Epstein, Michael & Kribus, Abraham, 2017. "Thermo-electro-chemical storage (TECS) of solar energy," Applied Energy, Elsevier, vol. 190(C), pages 788-799.
    20. Deva Harsha Perugupalli & Tao Xu & Kyu Taek Cho, 2019. "Activation of Carbon Porous Paper for Alkaline Alcoholic Fuel Cells," Energies, MDPI, vol. 12(17), pages 1-12, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:251:y:2019:i:c:96. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.