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N/S-Me (Fe, Co, Ni) doped hierarchical porous carbons for fuel cell oxygen reduction reaction with high catalytic activity and long-term stability

Author

Listed:
  • Wu, Mingjie
  • Zhang, Enguang
  • Guo, Qinping
  • Wang, Yongzhen
  • Qiao, Jinli
  • Li, Kaixi
  • Pei, Pucheng

Abstract

A series of novel and high-performing oxygen reduction reaction (ORR) catalysts based on N/S-Me-doped (Me=Fe, Co, Ni) hierarchical porous carbons (N/S-Fe-HPC, N/S-Co-HPC and N/S-Ni-HPC) have been synthesized by a green and cost-effective method combining a simple silicate templated two-step graphitization of the impregnated carbon. After optimization of the porous structures and enlargement of the BET specific surface area by combining the silicate template and the Fe-, Co- and Ni-metal sulfates, the obtained N/S-Me-HPC catalysts exhibit excellent ORR performance in both alkaline and acidic media. In particular, N/S-Fe-HPC shows superior catalytic ORR performance compared to commercially available 20% Pt/C in alkaline medium reflected by the onset potential of 0.98V and half-wave potential of 0.86V, and comparable ORR activity in acidic media with the onset potential of 0.84V and half-wave potential of 0.73V. In addition, the N/S-Fe-HPC catalyst exhibits excellent long-term stability and a high methanol tolerance. The outstanding electrochemical performance of such catalysts thereby makes it possible for these non-noble catalysts to replace the commercial Pt/C in both fuel cell and metal–air battery applications.

Suggested Citation

  • Wu, Mingjie & Zhang, Enguang & Guo, Qinping & Wang, Yongzhen & Qiao, Jinli & Li, Kaixi & Pei, Pucheng, 2016. "N/S-Me (Fe, Co, Ni) doped hierarchical porous carbons for fuel cell oxygen reduction reaction with high catalytic activity and long-term stability," Applied Energy, Elsevier, vol. 175(C), pages 468-478.
    • Handle: RePEc:eee:appene:v:175:y:2016:i:c:p:468-478
    DOI: 10.1016/j.apenergy.2016.03.065
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    References listed on IDEAS

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    1. Mark K. Debe, 2012. "Electrocatalyst approaches and challenges for automotive fuel cells," Nature, Nature, vol. 486(7401), pages 43-51, June.
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    3. Hai-Wei Liang & Xiaodong Zhuang & Sebastian Brüller & Xinliang Feng & Klaus Müllen, 2014. "Hierarchically porous carbons with optimized nitrogen doping as highly active electrocatalysts for oxygen reduction," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
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    Cited by:

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    3. Zhong, Kengqiang & Li, Meng & Yang, Yue & Zhang, Hongguo & Zhang, Bopeng & Tang, Jinfeng & Yan, Jia & Su, Minhua & Yang, Zhiquan, 2019. "Nitrogen-doped biochar derived from watermelon rind as oxygen reduction catalyst in air cathode microbial fuel cells," Applied Energy, Elsevier, vol. 242(C), pages 516-525.
    4. Nandan, Ravi & Goswami, Gopal Krishna & Nanda, Karuna Kar, 2017. "Direct synthesis of Pt-free catalyst on gas diffusion layer of fuel cell and usage of high boiling point fuels for efficient utilization of waste heat," Applied Energy, Elsevier, vol. 205(C), pages 1050-1058.
    5. Hu, Zunyan & Xu, Liangfei & Huang, Yiyuan & Li, Jianqiu & Ouyang, Minggao & Du, Xiaoli & Jiang, Hongliang, 2018. "Comprehensive analysis of galvanostatic charge method for fuel cell degradation diagnosis," Applied Energy, Elsevier, vol. 212(C), pages 1321-1332.
    6. She, Yiyi & Chen, Jinfan & Zhang, Chengxu & Lu, Zhouguang & Ni, Meng & Sit, Patrick H.-L. & Leung, Michael K.H., 2018. "Nitrogen-doped graphene derived from ionic liquid as metal-free catalyst for oxygen reduction reaction and its mechanisms," Applied Energy, Elsevier, vol. 225(C), pages 513-521.

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