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Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis

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  • Kim, Kwang Ho
  • Kim, Tae-Seung
  • Lee, Soo-Min
  • Choi, Donha
  • Yeo, Hwanmyeong
  • Choi, In-Gyu
  • Choi, Joon Weon

Abstract

The objective of this study was to characterize biooils and biochars produced from four different woody biomasses (two hardwoods: oak, eucalyptus and two softwoods: pitch pine, Japanese cedar). Fast pyrolysis was performed at 500 °C for ca. 2 s using fluidized bed reactor. The mass balances of essential pyrolytic products (biooil, biochar and gas) were influenced by the types of feedstocks. The yields of biooils and biochars were determined to ca. 62–68% and 11–14% based on dry weight of feedstock, respectively. However, physical properties of biooils such as pH, water content, and heating value were almost similar regardless of feedstocks. All biooils were acidic (pH 1.7–2.4) and water contents were estimated between 20% and 26%. The heating values were determined to 15.5–19 MJ/kg. X-ray fluorescence (WDXRF) spectrometry and scanning electron microscopy analyses of biochars showed that considerable amounts of mineral components, which could play an important role for plants growth, were detected in the biochars.

Suggested Citation

  • Kim, Kwang Ho & Kim, Tae-Seung & Lee, Soo-Min & Choi, Donha & Yeo, Hwanmyeong & Choi, In-Gyu & Choi, Joon Weon, 2013. "Comparison of physicochemical features of biooils and biochars produced from various woody biomasses by fast pyrolysis," Renewable Energy, Elsevier, vol. 50(C), pages 188-195.
    • Handle: RePEc:eee:renene:v:50:y:2013:i:c:p:188-195
    DOI: 10.1016/j.renene.2012.06.030
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    References listed on IDEAS

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    1. Pütün, Ayşe E & Apaydin, Esin & Pütün, Ersan, 2002. "Bio-oil production from pyrolysis and steam pyrolysis of soybean-cake: product yields and composition," Energy, Elsevier, vol. 27(7), pages 703-713.
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    3. Merckel, Ryan D. & Heydenrych, Mike D. & Sithole, Bruce B., 2021. "Pyrolysis oil composition and catalytic activity estimated by cumulative mass analysis using Py-GC/MS EGA-MS," Energy, Elsevier, vol. 219(C).
    4. Feng, Qunjie & Lin, Yunqin, 2017. "Integrated processes of anaerobic digestion and pyrolysis for higher bioenergy recovery from lignocellulosic biomass: A brief review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 1272-1287.
    5. Jin, Wenjia & Singh, Kaushlendra & Zondlo, John, 2015. "Co-processing of pyrolysis vapors with bio-chars for ex-situ upgrading," Renewable Energy, Elsevier, vol. 83(C), pages 638-645.
    6. Sangjan, Amornrat & Ngamsiri, Pornthip & Klomkliang, Nikom & Wu, Kevin C.-W. & Matsagar, Babasaheb M. & Ratchahat, Sakhon & Liu, Chen-Guang & Laosiripojana, Navadol & Sakdaronnarong, Chularat, 2020. "Effect of microwave-assisted wet torrefaction on liquefaction of biomass from palm oil and sugarcane wastes to bio-oil and carbon nanodots/nanoflakes by hydrothermolysis and solvothermolysis," Renewable Energy, Elsevier, vol. 154(C), pages 1204-1217.
    7. Braimakis, Konstantinos & Atsonios, Konstantinos & Panopoulos, Kyriakos D. & Karellas, Sotirios & Kakaras, Emmanuel, 2014. "Economic evaluation of decentralized pyrolysis for the production of bio-oil as an energy carrier for improved logistics towards a large centralized gasification plant," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 57-72.
    8. Cuong, Dinh Viet & Matsagar, Babasaheb M. & Lee, Mengshan & Hossain, Md. Shahriar A. & Yamauchi, Yusuke & Vithanage, Meththika & Sarkar, Binoy & Ok, Yong Sik & Wu, Kevin C.-W. & Hou, Chia-Hung, 2021. "A critical review on biochar-based engineered hierarchical porous carbon for capacitive charge storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    9. Zhu, Haodong & Yi, Baojun & Hu, Hongyun & Fan, Qizhou & Wang, Hao & Yao, Hong, 2021. "The effects of char and potassium on the fast pyrolysis behaviors of biomass in an infrared-heating condition," Energy, Elsevier, vol. 214(C).
    10. Dhyani, Vaibhav & Bhaskar, Thallada, 2018. "A comprehensive review on the pyrolysis of lignocellulosic biomass," Renewable Energy, Elsevier, vol. 129(PB), pages 695-716.
    11. Despina Vamvuka & George Tsagris & Christia Loulashi, 2023. "Co-Gasification Performance of Low-Quality Lignite with Woody Wastes Using Greenhouse Gas CO 2 —A TG–MS Study," Sustainability, MDPI, vol. 15(12), pages 1-12, June.
    12. Bamdad, Hanieh & Hawboldt, Kelly & MacQuarrie, Stephanie, 2018. "A review on common adsorbents for acid gases removal: Focus on biochar," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1705-1720.

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