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Insight into kinetics and thermodynamics of distillers’ dried grains with solubles (DDGS) combustion using an approach simultaneously determining frequency factor and reaction model

Author

Listed:
  • Zhang, Pin
  • Li, Chong
  • Xu, Dong
  • Yellezuome, Dominic
  • Wang, Jiong
  • Cai, Junmeng

Abstract

The Kissinger and master plots methods are commonly employed to estimate the frequency factor and reaction model, respectively. However, two methods cannot always provide accurate results, especially for solid-state reaction processes with varying kinetic parameters. A new approach for simultaneously determining the frequency factor and reaction model has been developed. The applicability of the new approach was verified through analyzing a theoretically simulated process. The suitability for combustion conversion of distillers’ dried grains with solubles (DDGS) was analyzed through physicochemical characterization and kinetic and thermodynamic investigation. The effective activation energies for DDGS combustion from the Friedman isoconversional method varied significantly from 129.5 to 206.3 kJ mol−1 in the conversion range 0.05–0.95. The frequency factor range and reaction model for DDGS combustion determined by the newly developed approach were 1.7 × 1011–4.2 × 1016 s−1 and f(α) = 5α1.277(1-0.582α)23.877[-ln(1-α)]−0.100, respectively. Thermodynamic analysis revealed that the changes in Gibbs free energy, enthalpy and entropy for DDGS combustion were in the range of 146.7–162.2 kJ mol−1, 125.3–200.4 kJ mol−1, and -42.5 – 57.0 J mol−1 K−1, respectively, which indicating DDGS combustion has a great potential for energy conversion.

Suggested Citation

  • Zhang, Pin & Li, Chong & Xu, Dong & Yellezuome, Dominic & Wang, Jiong & Cai, Junmeng, 2023. "Insight into kinetics and thermodynamics of distillers’ dried grains with solubles (DDGS) combustion using an approach simultaneously determining frequency factor and reaction model," Renewable Energy, Elsevier, vol. 219(P2).
  • Handle: RePEc:eee:renene:v:219:y:2023:i:p2:s096014812301474x
    DOI: 10.1016/j.renene.2023.119559
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    References listed on IDEAS

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    1. Luo, Laipeng & Zhang, Zhiyi & Li, Chong & Nishu, & He, Fang & Zhang, Xingguang & Cai, Junmeng, 2021. "Insight into master plots method for kinetic analysis of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 233(C).
    2. Cai, Junmeng & He, Yifeng & Yu, Xi & Banks, Scott W. & Yang, Yang & Zhang, Xingguang & Yu, Yang & Liu, Ronghou & Bridgwater, Anthony V., 2017. "Review of physicochemical properties and analytical characterization of lignocellulosic biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 309-322.
    3. Riaz, Sajid & Oluwoye, Ibukun & Al-Abdeli, Yasir M., 2022. "Oxidative torrefaction of densified woody biomass: Performance, combustion kinetics and thermodynamics," Renewable Energy, Elsevier, vol. 199(C), pages 908-918.
    4. Ong, Hwai Chyuan & Yu, Kai Ling & Chen, Wei-Hsin & Pillejera, Ma Katreena & Bi, Xiaotao & Tran, Khanh-Quang & Pétrissans, Anelie & Pétrissans, Mathieu, 2021. "Variation of lignocellulosic biomass structure from torrefaction: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    5. Cai, Junmeng & Xu, Di & Dong, Zhujun & Yu, Xi & Yang, Yang & Banks, Scott W. & Bridgwater, Anthony V., 2018. "Processing thermogravimetric analysis data for isoconversional kinetic analysis of lignocellulosic biomass pyrolysis: Case study of corn stalk," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2705-2715.
    6. Mumbach, Guilherme Davi & Alves, José Luiz Francisco & da Silva, Jean Constantino Gomes & Domenico, Michele Di & Arias, Santiago & Pacheco, Jose Geraldo A. & Marangoni, Cintia & Machado, Ricardo Anton, 2022. "Prospecting pecan nutshell pyrolysis as a source of bioenergy and bio-based chemicals using multicomponent kinetic modeling, thermodynamic parameters estimation, and Py-GC/MS analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    7. Escalante, Jamin & Chen, Wei-Hsin & Tabatabaei, Meisam & Hoang, Anh Tuan & Kwon, Eilhann E. & Andrew Lin, Kun-Yi & Saravanakumar, Ayyadurai, 2022. "Pyrolysis of lignocellulosic, algal, plastic, and other biomass wastes for biofuel production and circular bioeconomy: A review of thermogravimetric analysis (TGA) approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).
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