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Pyrolysis of typical plastics and coupled with steam reforming of their derived volatiles for simultaneous production of hydrogen-rich gases and heavy organics

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  • Jiang, Yuchen
  • Li, Xianglin
  • Li, Chao
  • Zhang, Lijun
  • Zhang, Shu
  • Li, Bin
  • Wang, Shuang
  • Hu, Xun

Abstract

Pyrolysis is a thermochemical route for converting waste plastics into hydrocarbons that might be further upgraded to fine chemicals via the process such as hydrotreatment. In this study, the pyrolysis of five typical plastics (PE, PP, PVC, PS and PET) and steam reforming of their derived volatiles were coupled in one process, named as pyro-reforming. The reaction behaviors, especially the property of their derived cokes, in the pyro-reforming were investigated. The results indicated that the volatiles from the pyrolysis of PE had the highest reactivity with steam to produce H2 of the highest yield, followed by that of PP, PVC, PET and PS. The Cl in PVC promoted nickel sintering, enhanced formation of heavy aromatics through aromatization. Moreover, the existence of Cl interrupted formation of carbon nanotube, forming the highest amount of coke with hemp rope-like fiber form of very coarse surface. This was very different from the carbon nanotube form of coke with smooth surface and uniform outer/inner diameters from the pyro-reforming of PE or PP. The pyro-reforming of PET or PS generated mainly the aromatic intermediates that were chemically more inert in steam reforming, forming polymeric type of coke with no carbon nanotube morphology and very low crystallinity.

Suggested Citation

  • Jiang, Yuchen & Li, Xianglin & Li, Chao & Zhang, Lijun & Zhang, Shu & Li, Bin & Wang, Shuang & Hu, Xun, 2022. "Pyrolysis of typical plastics and coupled with steam reforming of their derived volatiles for simultaneous production of hydrogen-rich gases and heavy organics," Renewable Energy, Elsevier, vol. 200(C), pages 476-491.
    • Handle: RePEc:eee:renene:v:200:y:2022:i:c:p:476-491
    DOI: 10.1016/j.renene.2022.09.120
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    References listed on IDEAS

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    1. Tobias D. Nielsen & Jacob Hasselbalch & Karl Holmberg & Johannes Stripple, 2020. "Politics and the plastic crisis: A review throughout the plastic life cycle," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 9(1), January.
    2. Li, Chao & Sun, Yifan & Yi, Zijun & Zhang, Lijun & Zhang, Shu & Hu, Xun, 2022. "Co-pyrolysis of coke bottle wastes with cellulose, lignin and sawdust: Impacts of the mixed feedstock on char properties," Renewable Energy, Elsevier, vol. 181(C), pages 1126-1139.
    3. Laurent Lebreton & Anthony Andrady, 2019. "Future scenarios of global plastic waste generation and disposal," Palgrave Communications, Palgrave Macmillan, vol. 5(1), pages 1-11, December.
    4. Xu, Jun & Tang, Hao & Su, Sheng & Liu, Jiawei & Xu, Kai & Qian, Kun & Wang, Yi & Zhou, Yingbiao & Hu, Song & Zhang, Anchao & Xiang, Jun, 2018. "A study of the relationships between coal structures and combustion characteristics: The insights from micro-Raman spectroscopy based on 32 kinds of Chinese coals," Applied Energy, Elsevier, vol. 212(C), pages 46-56.
    5. Zhong, Dian & Zeng, Kuo & Li, Jun & Qiu, Yi & Flamant, Gilles & Nzihou, Ange & Vladimirovich, Vasilevich Sergey & Yang, Haiping & Chen, Hanping, 2022. "Characteristics and evolution of heavy components in bio-oil from the pyrolysis of cellulose, hemicellulose and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    6. Lam, Su Shiung & Wan Mahari, Wan Adibah & Ok, Yong Sik & Peng, Wanxi & Chong, Cheng Tung & Ma, Nyuk Ling & Chase, Howard A. & Liew, Zhenling & Yusup, Suzana & Kwon, Eilhann E. & Tsang, Daniel C.W., 2019. "Microwave vacuum pyrolysis of waste plastic and used cooking oil for simultaneous waste reduction and sustainable energy conversion: Recovery of cleaner liquid fuel and techno-economic analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 115(C).
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