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Synthesis of T-Type low-viscosity hydrocarbon bio-lubricant from fatty acid methyl esters and coconut oil

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  • Chen, Shuang
  • Wu, Tingting
  • Fang, Yuan
  • Zhao, Chen

Abstract

Biomass-derived long-chain alkanes with highly symmetrical branches, which show comparable properties to traditional petrochemical-based poly-α-olefin (PAO), have great potential economic value for industrial application. In this work, we developed a new strategy to prepare T-type low-viscosity bio-lubricant base oil using inexpensive lipid-derived fatty acid methyl esters (FAMEs) as raw materials with a total carbon yield of around 67.3%. The fatty acid methyl ester compounds (R1-COOCH3) were converted to fatty alcohols using methanol as the solvent and hydrogen donor over the Cu/SiO2 catalyst. Subsequently, fatty alcohol was further brominated to the Bromo-Grignard reagents (R1-CH2-MgBr). In the next step, a T-type synthetic bio-lubricant base oil (R1-C(R2)-R1) was formed by the hydrodeoxygenation of symmetrical tertiary alcohol precursors over Pd/C, where symmetrical tertiary alcohol precursors were obtained via the nucleophilic addition of Bromo-Grignard reagents with fatty acid methyl ester (R2-COOCH3). The specific properties of the branched representative bio-lubricant C32 (12'10'10') are comparable to those of the commercial lubricant PAO 3.6. This strategy offered a new promising route for synthesizing high-quality bio-lubricant base oil.

Suggested Citation

  • Chen, Shuang & Wu, Tingting & Fang, Yuan & Zhao, Chen, 2022. "Synthesis of T-Type low-viscosity hydrocarbon bio-lubricant from fatty acid methyl esters and coconut oil," Renewable Energy, Elsevier, vol. 186(C), pages 280-287.
    • Handle: RePEc:eee:renene:v:186:y:2022:i:c:p:280-287
    DOI: 10.1016/j.renene.2021.12.150
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    References listed on IDEAS

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    1. Zhang, Le & Liu, Ronghou & Yin, Renzhan & Mei, Yuanfei, 2013. "Upgrading of bio-oil from biomass fast pyrolysis in China: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 66-72.
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