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Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC)

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  • Aboelazayem, Omar
  • Gadalla, Mamdouh
  • Alhajri, Ibrahim
  • Saha, Basudeb

Abstract

Biodiesel production using supercritical methanolysis has received immense interest over the last few years. It has the ability to convert high acid value feedstock into biodiesel using a single-pot reaction. However, the energy intensive process is the main disadvantage of supercritical biodiesel process. Herein, a conceptual design for the integration of supercritical biodiesel process with organic Rankine cycle (ORC) is presented to recover residual hot streams and to generate electric power. This article provides energy and techno-economic comparative study for three developed scenarios as follows: original process with no energy integration (Scenario 1), energy integrated process (Scenario 2) and advanced energy integrated process with ORC (Scenario 3). The developed integrated biodiesel process with ORC resulted in electric power generation that has not only satisfied the process electric requirement but also provided excess power of 257 kW for 8,000 tonnes/annum biodiesel plant. The techno-economic comparative analysis resulted in favouring the third scenario with 36% increase in the process profitability than the second scenario. Sensitivity analysis has shown that biodiesel price variation has significant effect on the process profitability. In summary, integrating supercritical biodiesel production process with ORC appears to be a promising approach for enhancing the process techno-economic profitability and viability.

Suggested Citation

  • Aboelazayem, Omar & Gadalla, Mamdouh & Alhajri, Ibrahim & Saha, Basudeb, 2021. "Advanced process integration for supercritical production of biodiesel: Residual waste heat recovery via organic Rankine cycle (ORC)," Renewable Energy, Elsevier, vol. 164(C), pages 433-443.
    • Handle: RePEc:eee:renene:v:164:y:2021:i:c:p:433-443
    DOI: 10.1016/j.renene.2020.09.058
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    References listed on IDEAS

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    1. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Design and simulation of an integrated process for biodiesel production from waste cooking oil using supercritical methanolysis," Energy, Elsevier, vol. 161(C), pages 299-307.
    2. Aboelazayem, Omar & El-Gendy, Nour Sh. & Abdel-Rehim, Ahmed A. & Ashour, Fatma & Sadek, Mohamed A., 2018. "Biodiesel production from castor oil in Egypt: Process optimisation, kinetic study, diesel engine performance and exhaust emissions analysis," Energy, Elsevier, vol. 157(C), pages 843-852.
    3. Emadi, Mohammad Ali & Chitgar, Nazanin & Oyewunmi, Oyeniyi A. & Markides, Christos N., 2020. "Working-fluid selection and thermoeconomic optimisation of a combined cycle cogeneration dual-loop organic Rankine cycle (ORC) system for solid oxide fuel cell (SOFC) waste-heat recovery," Applied Energy, Elsevier, vol. 261(C).
    4. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2018. "Valorisation of high acid value waste cooking oil into biodiesel using supercritical methanolysis: Experimental assessment and statistical optimisation on typical Egyptian feedstock," Energy, Elsevier, vol. 162(C), pages 408-420.
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    6. Gadalla, Mamdouh A., 2015. "A new graphical method for Pinch Analysis applications: Heat exchanger network retrofit and energy integration," Energy, Elsevier, vol. 81(C), pages 159-174.
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    8. Wei, Juntao & Gong, Yan & Guo, Qinghua & Chen, Xueli & Ding, Lu & Yu, Guangsuo, 2019. "A mechanism investigation of synergy behaviour variations during blended char co-gasification of biomass and different rank coals," Renewable Energy, Elsevier, vol. 131(C), pages 597-605.
    9. Aboelazayem, Omar & Gadalla, Mamdouh & Saha, Basudeb, 2019. "Derivatisation-free characterisation and supercritical conversion of free fatty acids into biodiesel from high acid value waste cooking oil," Renewable Energy, Elsevier, vol. 143(C), pages 77-90.
    10. Lion, Simone & Taccani, Rodolfo & Vlaskos, Ioannis & Scrocco, Pietro & Vouvakos, Xenakis & Kaiktsis, Lambros, 2019. "Thermodynamic analysis of waste heat recovery using Organic Rankine Cycle (ORC) for a two-stroke low speed marine Diesel engine in IMO Tier II and Tier III operation," Energy, Elsevier, vol. 183(C), pages 48-60.
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    2. Omar Aboelazayem & Mamdouh Gadalla & Basudeb Saha, 2022. "Comprehensive Optimisation of Biodiesel Production Conditions via Supercritical Methanolysis of Waste Cooking Oil," Energies, MDPI, vol. 15(10), pages 1-22, May.
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    4. Sun, Zhixin & Huang, Yisheng & Tian, Na & Lin, Kui, 2023. "Performance improvement of ORC by breaking the barrier of ambient pressure," Energy, Elsevier, vol. 262(PA).
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    6. Jiang, Chao & Zhu, Shunmin & Yu, Guoyao & Luo, Ercang & Li, Ke, 2022. "Numerical and experimental investigations on a regenerative static thermomagnetic generator for low-grade thermal energy recovery," Applied Energy, Elsevier, vol. 311(C).
    7. Kang, Lixia & Tang, Jianping & Liu, Yongzhong, 2021. "Optimal design of organic Rankine cycle system for multi-source waste heat recovery involving multi-period operation," Energy, Elsevier, vol. 235(C).
    8. Zhang, Qiang & Zhang, Ningqi & Zhu, Shengbo & Heydarian, Dariush, 2023. "Thermodynamic simulation and optimization of natural gas liquefaction cycle based on the common structure of organic rankine cycle," Energy, Elsevier, vol. 264(C).
    9. Gómez-Castro, F.I. & Gutiérrez-Antonio, C. & Romero-Izquierdo, A.G. & May-Vázquez, M.M. & Hernández, S., 2023. "Intensified technologies for the production of triglyceride-based biofuels: Current status and future trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 184(C).
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