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H2S adsorption on nanostructured iron oxide at room temperature for biogas purification: Application of renewable energy

Author

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  • Cristiano, Djema Maria
  • de A. Mohedano, Rodrigo
  • Nadaleti, Willian Cézar
  • de Castilhos Junior, Armando B.
  • Lourenço, Vitor Alves
  • Gonçalves, Débora F.H.
  • Filho, Paulo Belli

Abstract

The energetic use of biogas is limited by the presence of contaminants which hinder the process and generate excessive maintenance costs. This study aims to evaluate the H2S adsorption on nanostructured iron oxide (NIO), towards applications for landfill gas cleaning. The iron oxide utilized in this study is obtained from mining residues, which provides economic and environmental advantages compared to other recognized adsorbents. In order to determine the performance of NIO, adsorption tests were performed in a lab scale with the use of synthetic gas (H2S + N2) and a continuous up-flow reactor. Experiments produced data regarding the process efficiency as a function of different operating conditions including gas hourly space velocity, H2S inlet concentration and gas humidity. Fresh and sulfided samples were characterized by SEM, TEM, BET, EDX and XRD techniques. The characterization results suggest that under lower GHSV (1,250 h-1), lower H2S inlet concentrations (200 ppm) and dry gas, the highest breakthrough capacity was recorded at 2.5 mg H2S per gram of NIO. Due to the good efficiency in removing H2S under ambient conditions, NIO can be considered a cost-effective promising alternative for biogas desulfurization.

Suggested Citation

  • Cristiano, Djema Maria & de A. Mohedano, Rodrigo & Nadaleti, Willian Cézar & de Castilhos Junior, Armando B. & Lourenço, Vitor Alves & Gonçalves, Débora F.H. & Filho, Paulo Belli, 2020. "H2S adsorption on nanostructured iron oxide at room temperature for biogas purification: Application of renewable energy," Renewable Energy, Elsevier, vol. 154(C), pages 151-160.
    • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:151-160
    DOI: 10.1016/j.renene.2020.02.054
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    1. Rasi, S. & Veijanen, A. & Rintala, J., 2007. "Trace compounds of biogas from different biogas production plants," Energy, Elsevier, vol. 32(8), pages 1375-1380.
    2. Lino, F.A.M. & Ismail, K.A.R., 2011. "Energy and environmental potential of solid waste in Brazil," Energy Policy, Elsevier, vol. 39(6), pages 3496-3502, June.
    3. Pipatmanomai, Suneerat & Kaewluan, Sommas & Vitidsant, Tharapong, 2009. "Economic assessment of biogas-to-electricity generation system with H2S removal by activated carbon in small pig farm," Applied Energy, Elsevier, vol. 86(5), pages 669-674, May.
    4. Kapdi, S.S. & Vijay, V.K. & Rajesh, S.K. & Prasad, Rajendra, 2005. "Biogas scrubbing, compression and storage: perspective and prospectus in Indian context," Renewable Energy, Elsevier, vol. 30(8), pages 1195-1202.
    5. Papurello, Davide & Lanzini, Andrea & Tognana, Lorenzo & Silvestri, Silvia & Santarelli, Massimo, 2015. "Waste to energy: Exploitation of biogas from organic waste in a 500 Wel solid oxide fuel cell (SOFC) stack," Energy, Elsevier, vol. 85(C), pages 145-158.
    6. Nadaletti, W.C. & Cremonez, P.A. & de Souza, S.N.M. & Bariccatti, R.A. & Belli Filho, P. & Secco, D., 2015. "Potential use of landfill biogas in urban bus fleet in the Brazilian states: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 277-283.
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    2. Becker, C.M. & Marder, M. & Junges, E. & Konrad, O., 2022. "Technologies for biogas desulfurization - An overview of recent studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    3. Zhang, Yuyao & Kawasaki, Yu & Oshita, Kazuyuki & Takaoka, Masaki & Minami, Daisuke & Inoue, Go & Tanaka, Toshihiro, 2021. "Economic assessment of biogas purification systems for removal of both H2S and siloxane from biogas," Renewable Energy, Elsevier, vol. 168(C), pages 119-130.

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