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Modeling a novel combined solid oxide electrolysis cell (SOEC) - Biomass gasification renewable methanol production system

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  • Ali, Shahid
  • Sørensen, Kim
  • Nielsen, Mads P.

Abstract

Chemical energy storage in the form of hydrogen is playing an important role in the synthesis of alternative energy carriers such as Synthetic Natural Gas (SNG), Methanol and Dimethyl ether (DME) supplementing with a carbon source. The only renewable carbon source is biomass, which is a limited resource. However, the addition of hydrogen could potentially extend the existing biomass resources. This paper describes the modeling of a novel combined Solid Oxide Electrolysis Cell (SOEC) and oxygen blown biomass gasification system using Aspen Plus. One of the advantages of using such a combined system is the use of oxygen for gasification and reforming. The comparison of reforming technologies showed that an autothermal reformer (ATR) could be an advantage since oxygen is already available from the electrolysis stack and the ATR produced syngas has a higher CO/CO2 ratio, which increases the methanol synthesis’s reaction rate. ATR requires much less energy ∼13 MW for almost complete methane conversion compared to ∼35 MW for Steam Reforming (SR). The advantage of using inter-cooled compression upstream or downstream for such a combined process has been explained. A methanol thermal conversion efficiency of 72.08% can be achieved for gasification and SOEC combined system compared to 55.7% for an only gasifier system.

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  • Ali, Shahid & Sørensen, Kim & Nielsen, Mads P., 2020. "Modeling a novel combined solid oxide electrolysis cell (SOEC) - Biomass gasification renewable methanol production system," Renewable Energy, Elsevier, vol. 154(C), pages 1025-1034.
    • Handle: RePEc:eee:renene:v:154:y:2020:i:c:p:1025-1034
    DOI: 10.1016/j.renene.2019.12.108
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    Cited by:

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    2. Kim, Heehyang & Kim, Ayeon & Byun, Manhee & Lim, Hankwon, 2021. "Comparative feasibility studies of H2 supply scenarios for methanol as a carbon-neutral H2 carrier at various scales and distances," Renewable Energy, Elsevier, vol. 180(C), pages 552-559.
    3. Dossow, Marcel & Dieterich, Vincent & Hanel, Andreas & Spliethoff, Hartmut & Fendt, Sebastian, 2021. "Improving carbon efficiency for an advanced Biomass-to-Liquid process using hydrogen and oxygen from electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 152(C).
    4. Tabibian, Seyed Shayan & Sharifzadeh, Mahdi, 2023. "Statistical and analytical investigation of methanol applications, production technologies, value-chain and economy with a special focus on renewable methanol," Renewable and Sustainable Energy Reviews, Elsevier, vol. 179(C).
    5. Xia, Qi & Zhao, Jianguo & Chen, Chen & Jin, Weiya, 2023. "Modeling of CO2/H2O Co-electrolysis using solar-driven SOEC coupled with ammonia-based chemical heat pump," Renewable Energy, Elsevier, vol. 212(C), pages 128-137.
    6. Li, Huabin & Tao, Ye & Zhang, Yang & Fu, Hong, 2022. "Two-objective optimization of a hybrid solar-geothermal system with thermal energy storage for power, hydrogen and freshwater production based on transcritical CO2 cycle," Renewable Energy, Elsevier, vol. 183(C), pages 51-66.
    7. Adnan, Muflih A. & Kibria, Md Golam, 2020. "Comparative techno-economic and life-cycle assessment of power-to-methanol synthesis pathways," Applied Energy, Elsevier, vol. 278(C).

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