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Ultrasonic emulsification assisted immobilized Burkholderia cepacia lipase catalyzed transesterification of soybean oil for biodiesel production in a novel reactor design

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  • Murillo, Gabriel
  • Ali, Sameh S.
  • Sun, Jianzhong
  • Yan, Yunjun
  • Bartocci, Pietro
  • El-Zawawy, Nessma
  • Azab, Maha
  • He, Yaojia
  • Fantozzi, Francesco

Abstract

Increasing energy demands coupled with decreasing fossil fuel resources create an urgent need to switch over bio-based fuel, such as biodiesel. In a newly designed reactor, the production of biodiesel was conducted with soybean oil (SBO) in solvent-free system through transesterification by immobilized Burkholderia cepacia lipase under the influence of ultrasonic emulsification. Effects of operational parameters viz. methanol-to-oil molar ratio, water concentration, immobilized enzyme concentration, and temperature on fatty acid methyl esters (FAME) yield were investigated. Molar ratio and enzyme concentration showed a significant linear correlation with biodiesel yield (r = − 0.8 and 0.6; respectively). Linear regression analysis of both parameters later revealed a significant prediction ability for biodiesel with a yield of 78.8 and 31.7%, respectively. FAME yield was 30% at 7 h in the pretreatment reactor. Without ultrasonic emulsification, the yield was significantly enhanced to 64% for the same reaction time in the packed-bed reactor. However, the reaction time was further reduced significantly under the influence of ultrasonic emulsification coupled with immobilized lipase as a catalyst and resulted into higher biodiesel yield of 68.6% at 3 h. Clearly, ultrasonic emulsification-assisted immobilized lipase catalysis of SBO might be a potential alternative route to conventional methods of biodiesel production.

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  • Murillo, Gabriel & Ali, Sameh S. & Sun, Jianzhong & Yan, Yunjun & Bartocci, Pietro & El-Zawawy, Nessma & Azab, Maha & He, Yaojia & Fantozzi, Francesco, 2019. "Ultrasonic emulsification assisted immobilized Burkholderia cepacia lipase catalyzed transesterification of soybean oil for biodiesel production in a novel reactor design," Renewable Energy, Elsevier, vol. 135(C), pages 1025-1034.
  • Handle: RePEc:eee:renene:v:135:y:2019:i:c:p:1025-1034
    DOI: 10.1016/j.renene.2018.12.080
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    1. Michelin, Simone & Penha, Frederico M. & Sychoski, Melania M. & Scherer, Robison P. & Treichel, Helen & Valério, Alexsandra & Di Luccio, M. & de Oliveira, Débora & Oliveira, J. Vladimir, 2015. "Kinetics of ultrasound-assisted enzymatic biodiesel production from Macauba coconut oil," Renewable Energy, Elsevier, vol. 76(C), pages 388-393.
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    1. Oliveira, Anne Caroline Defranceschi & Frensch, Gustavo & Marques, Francisco de Assis & Vargas, José Viriato Coelho & Rodrigues, Maria Luiza Fernandes & Mariano, André Bellin, 2020. "Production of methyl oleate by direct addition of fermented solid Penicillium sumatrense and Aspergillus fumigatus," Renewable Energy, Elsevier, vol. 162(C), pages 1132-1139.
    2. Karimian, A. & Pourhoseini, S.H. & Nozari, A., 2023. "Persica Akhani Salicornia as novel biodiesel feedstock production for economic prosperity in salty and water scarcity areas: Optimized oil extraction process and transesterification reaction using new," Renewable Energy, Elsevier, vol. 211(C), pages 361-369.
    3. Kumar, Dilip & Das, Tapas & Giri, Balendu Shekher & Verma, Bhawna, 2020. "Preparation and characterization of novel hybrid bio-support material immobilized from Pseudomonas cepacia lipase and its application to enhance biodiesel production," Renewable Energy, Elsevier, vol. 147(P1), pages 11-24.
    4. Phromphithak, Sanphawat & Meepowpan, Puttinan & Shimpalee, Sirivatch & Tippayawong, Nakorn, 2020. "Transesterification of palm oil into biodiesel using ChOH ionic liquid in a microwave heated continuous flow reactor," Renewable Energy, Elsevier, vol. 154(C), pages 925-936.

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