IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v128y2018ipbp446-459.html
   My bibliography  Save this article

Mineral phase transformation of biomass ashes – Experimental and thermochemical calculations

Author

Listed:
  • Magdziarz, Aneta
  • Gajek, Marcin
  • Nowak-Woźny, Dorota
  • Wilk, Małgorzata

Abstract

The paper is focused on the thermal characterisation of biomass ashes especially of mineral phase transformation. Ash generated during combustion (with high alkali metal concentration) can deposit and consequently cause serious operating problems such as slagging, fouling and corrosion of metal surface limiting heat transfer. Four biomass ashes with different origin were investigated. The chemical composition of the mineral matter of ashes varied between the samples, but CaO, SiO2, K2O, MgO, P2O5 and Al2O3 are the main compounds of the ashes. The thermal behaviour of ashes was studied using TG-DSC and Ash Fusion Temperatures (AFTs) techniques. In order to describe and understand the mineral matter transformation at high temperatures the FactSage Thermodynamics Model was used. FactSage calculations allowed to predict chemical composition in equilibrium, showed amount of liquid slag and solid phases, and gave information about slagging properties of ashes. A corrosion study of the metal surface used for heat transfer biomass ashes was undertaken. The corrosion behaviour of steel X10CrMoVNb9-1 in the present of biomass ash at 650 °C in 1000 h in furnace. The degradation of the metal surface was investigated by observation of surface morphology using the SEM method. The presence of potassium and chlorine in deposits causes the acceleration of oxidation. They break and peel off the surface easily, thus evidently accelerating corrosion.

Suggested Citation

  • Magdziarz, Aneta & Gajek, Marcin & Nowak-Woźny, Dorota & Wilk, Małgorzata, 2018. "Mineral phase transformation of biomass ashes – Experimental and thermochemical calculations," Renewable Energy, Elsevier, vol. 128(PB), pages 446-459.
    • Handle: RePEc:eee:renene:v:128:y:2018:i:pb:p:446-459
    DOI: 10.1016/j.renene.2017.05.057
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148117304433
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2017.05.057?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Saidur, R. & Abdelaziz, E.A. & Demirbas, A. & Hossain, M.S. & Mekhilef, S., 2011. "A review on biomass as a fuel for boilers," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2262-2289, June.
    2. Magdziarz, Aneta & Wilk, Małgorzata & Gajek, Marcin & Nowak-Woźny, Dorota & Kopia, Agnieszka & Kalemba-Rec, Izabela & Koziński, Janusz A., 2016. "Properties of ash generated during sewage sludge combustion: A multifaceted analysis," Energy, Elsevier, vol. 113(C), pages 85-94.
    3. Luan, Chao & You, Changfu & Zhang, Dongke, 2014. "Composition and sintering characteristics of ashes from co-firing of coal and biomass in a laboratory-scale drop tube furnace," Energy, Elsevier, vol. 69(C), pages 562-570.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wilk, Małgorzata & Śliz, Maciej & Lubieniecki, Bogusław, 2021. "Hydrothermal co-carbonization of sewage sludge and fuel additives: Combustion performance of hydrochar," Renewable Energy, Elsevier, vol. 178(C), pages 1046-1056.
    2. Yao, Xiwen & Zhao, Zhicheng & Xu, Kaili & Zhou, Haodong, 2020. "Determination of ash forming characteristics and fouling/slagging behaviours during gasification of masson pine in a fixed-bed gasifier," Renewable Energy, Elsevier, vol. 160(C), pages 1420-1430.
    3. Yang, Ziqiang & Zhang, Chuanxiang & Li, Fenghai & Liu, Xuefei & Zhou, Meijie & Fang, Yitian, 2025. "Effects of calcium/iron-rich sludge on the ash fusion characteristics of sugarcane bagasse under oxygen-enriched atmosphere," Energy, Elsevier, vol. 324(C).
    4. Zhou, Haodong & Xu, Kaili & Yao, Xiwen & Li, Jishuo, 2023. "Mineral transformations and molten mechanism during combustion of biomass ash," Renewable Energy, Elsevier, vol. 216(C).
    5. Mateusz Jackowski & Łukasz Niedźwiecki & Krzysztof Mościcki & Amit Arora & Muhammad Azam Saeed & Krystian Krochmalny & Jakub Pawliczek & Anna Trusek & Magdalena Lech & Jan Skřínský & Jakub Čespiva & J, 2021. "Synergetic Co-Production of Beer Colouring Agent and Solid Fuel from Brewers’ Spent Grain in the Circular Economy Perspective," Sustainability, MDPI, vol. 13(18), pages 1-17, September.
    6. Yi Zhang & Guanmin Zhang & Min Wei & Zhenqiang Gao & Maocheng Tian & Fang He, 2019. "Comparisons of Acid and Water Solubilities of Rice Straw Ash Together with Its Major Ash-Forming Elements at Different Ashing Temperatures: An Experimental Study," Sustainability, MDPI, vol. 11(7), pages 1-18, April.
    7. Yao, Xiwen & Zhou, Haodong & Xu, Keqiang & Liu, Qinghua & Xu, Kaili, 2024. "Understanding impacts of introducing CO2 in N2 and operation conditions on physicochemical property and fusion behaviour of solid products during thermal decomposition of corn stalks," Renewable Energy, Elsevier, vol. 221(C).
    8. Yao, Xiwen & Zhao, Zhicheng & Li, Jishuo & Zhang, Bohan & Zhou, Haodong & Xu, Kaili, 2020. "Experimental investigation of physicochemical and slagging characteristics of inorganic constituents in ash residues from gasification of different herbaceous biomass," Energy, Elsevier, vol. 198(C).
    9. Mlonka-Mędrala, Agata & Gołombek, Klaudiusz & Buk, Paulina & Cieślik, Ewelina & Nowak, Wojciech, 2019. "The influence of KCl on biomass ash melting behaviour and high-temperature corrosion of low-alloy steel," Energy, Elsevier, vol. 188(C).
    10. Ghazidin, Hafizh & Suyatno, Suyatno & Prismantoko, Adi & Karuana, Feri & Sarjono, & Prabowo, & Setiyawan, Atok & Darmawan, Arif & Aziz, Muhammad & Vuthaluru, Hari & Hariana, Hariana, 2024. "Impact of additives in mitigating ash-related problems during co-combustion of solid recovered fuel and high-sulfur coal," Energy, Elsevier, vol. 292(C).
    11. Zhang, Heng & Li, Junguo & Yang, Xin & Song, Shuangshuang & Wang, Zhiqing & Huang, Jiejie & Zhang, Yongqi & Fang, Yitian, 2020. "Influence of coal ash on CO2 gasification reactivity of corn stalk char," Renewable Energy, Elsevier, vol. 147(P1), pages 2056-2063.
    12. Zhou, Tianxing & Zhang, Weiwei & Luo, Siyi & Zuo, Zongliang & Ren, Dongdong, 2023. "The effect of ash fusion characteristic on the structure characteristics of carbon and the migration of potassium during rice straw high-temperature gasification process," Energy, Elsevier, vol. 284(C).
    13. Tomasz Hardy & Amit Arora & Halina Pawlak-Kruczek & Wojciech Rafajłowicz & Jerzy Wietrzych & Łukasz Niedźwiecki & Vishwajeet & Krzysztof Mościcki, 2021. "Non-Destructive Diagnostic Methods for Fire-Side Corrosion Risk Assessment of Industrial Scale Boilers, Burning Low Quality Solid Biofuels—A Mini Review," Energies, MDPI, vol. 14(21), pages 1-15, November.
    14. Zhang, Weiwei & Huang, Sheng & Wu, Shiyong & Wu, Youqing & Gao, Jinsheng, 2020. "Ash fusion characteristics and gasification activity during biomasses co-gasification process," Renewable Energy, Elsevier, vol. 147(P1), pages 1584-1594.
    15. Ghazidin, Hafizh & Suyatno, Suyatno & Prismantoko, Adi & Ruhiyat, Ade Sana & Prabowo, & Darmawan, Arif & Soleh, Mochamad & Aziz, Amiral & Asmanto, Puji & Vuthaluru, Hari & Wang, Yibin & Yurismono, Har, 2025. "Control of slagging and fouling during co-firing of solid recovered fuel and high-sodium coal using aluminum and magnesium-based additives," Energy, Elsevier, vol. 318(C).
    16. Szwaja, Stanisław & Magdziarz, Aneta & Zajemska, Monika & Poskart, Anna, 2019. "A torrefaction of Sida hermaphrodita to improve fuel properties. Advanced analysis of torrefied products," Renewable Energy, Elsevier, vol. 141(C), pages 894-902.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Karol Król & Dorota Nowak-Woźny, 2021. "Application of the Mechanical and Pressure Drop Tests to Determine the Sintering Temperature of Coal and Biomass Ash," Energies, MDPI, vol. 14(4), pages 1-14, February.
    2. Magdziarz, Aneta & Wilk, Małgorzata & Gajek, Marcin & Nowak-Woźny, Dorota & Kopia, Agnieszka & Kalemba-Rec, Izabela & Koziński, Janusz A., 2016. "Properties of ash generated during sewage sludge combustion: A multifaceted analysis," Energy, Elsevier, vol. 113(C), pages 85-94.
    3. Jha, Gaurav & Soren, S., 2017. "Study on applicability of biomass in iron ore sintering process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 399-407.
    4. Suopajärvi, Hannu & Umeki, Kentaro & Mousa, Elsayed & Hedayati, Ali & Romar, Henrik & Kemppainen, Antti & Wang, Chuan & Phounglamcheik, Aekjuthon & Tuomikoski, Sari & Norberg, Nicklas & Andefors, Alf , 2018. "Use of biomass in integrated steelmaking – Status quo, future needs and comparison to other low-CO2 steel production technologies," Applied Energy, Elsevier, vol. 213(C), pages 384-407.
    5. Gürel, Barış & Kurtuluş, Karani & Yurdakul, Sema & Karaca Dolgun, Gülşah & Akman, Remzi & Önür, Muhammet Enes & Varol, Murat & Keçebaş, Ali & Gürbüz, Habib, 2024. "Combustion of chicken manure and Turkish lignite mixtures in a circulating fluidized bed," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    6. Yek, Peter Nai Yuh & Cheng, Yoke Wang & Liew, Rock Keey & Wan Mahari, Wan Adibah & Ong, Hwai Chyuan & Chen, Wei-Hsin & Peng, Wanxi & Park, Young-Kwon & Sonne, Christian & Kong, Sieng Huat & Tabatabaei, 2021. "Progress in the torrefaction technology for upgrading oil palm wastes to energy-dense biochar: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    7. Małgorzata Wzorek & Robert Junga & Ersel Yilmaz & Bohdan Bozhenko, 2021. "Thermal Decomposition of Olive-Mill Byproducts: A TG-FTIR Approach," Energies, MDPI, vol. 14(14), pages 1-16, July.
    8. Miguel-Angel Perea-Moreno & Quetzalcoatl Hernandez-Escobedo & Fernando Rueda-Martinez & Alberto-Jesus Perea-Moreno, 2020. "Zapote Seed ( Pouteria mammosa L. ) Valorization for Thermal Energy Generation in Tropical Climates," Sustainability, MDPI, vol. 12(10), pages 1-21, May.
    9. Yao, Xiwen & Zheng, Yan & Zhou, Haodong & Xu, Kaili & Xu, Qingwei & Li, Li, 2020. "Effects of biomass blending, ashing temperature and potassium addition on ash sintering behaviour during co-firing of pine sawdust with a Chinese anthracite," Renewable Energy, Elsevier, vol. 147(P1), pages 2309-2320.
    10. Li, Fenghai & Zhao, Chaoyue & Guo, Qianqian & Li, Yang & Fan, Hongli & Guo, Mingxi & Wu, Lishun & Huang, Jiejie & Fang, Yitian, 2020. "Exploration in ash-deposition (AD) behavior modification of low-rank coal by manure addition," Energy, Elsevier, vol. 208(C).
    11. Kütt, Lauri & Millar, John & Karttunen, Antti & Lehtonen, Matti & Karppinen, Maarit, 2018. "Thermoelectric applications for energy harvesting in domestic applications and micro-production units. Part I: Thermoelectric concepts, domestic boilers and biomass stoves," Renewable and Sustainable Energy Reviews, Elsevier, vol. 98(C), pages 519-544.
    12. Carmen de la Cruz-Lovera & Francisco Manzano-Agugliaro & Esther Salmerón-Manzano & José-Luis de la Cruz-Fernández & Alberto-Jesus Perea-Moreno, 2019. "Date Seeds ( Phoenix dactylifera L. ) Valorization for Boilers in the Mediterranean Climate," Sustainability, MDPI, vol. 11(3), pages 1-14, January.
    13. Yi Zhang & Guanmin Zhang & Min Wei & Zhenqiang Gao & Maocheng Tian & Fang He, 2019. "Comparisons of Acid and Water Solubilities of Rice Straw Ash Together with Its Major Ash-Forming Elements at Different Ashing Temperatures: An Experimental Study," Sustainability, MDPI, vol. 11(7), pages 1-18, April.
    14. Zhang, Zhikun & Zhu, Zongyuan & Shen, Boxiong & Liu, Lina, 2019. "Insights into biochar and hydrochar production and applications: A review," Energy, Elsevier, vol. 171(C), pages 581-598.
    15. Gutiérrez-Alvarez, R. & Guerra, K. & Haro, P., 2023. "Market profitability of CSP-biomass hybrid power plants: Towards a firm supply of renewable energy," Applied Energy, Elsevier, vol. 335(C).
    16. Silva, D.A.L. & Filleti, R.A.P. & Musule, R. & Matheus, T.T. & Freire, F., 2022. "A systematic review and life cycle assessment of biomass pellets and briquettes production in Latin America," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    17. Li, Fenghai & Liu, Quanrun & Li, Meng & Fang, Yitian, 2018. "Understanding fly-ash formation during fluidized-bed gasification of high-silicon-aluminum coal based on its characteristics," Energy, Elsevier, vol. 150(C), pages 142-152.
    18. Xuejun Qian & Jingwen Xue & Yulai Yang & Seong W. Lee, 2021. "Thermal Properties and Combustion-Related Problems Prediction of Agricultural Crop Residues," Energies, MDPI, vol. 14(15), pages 1-18, July.
    19. Vincent Bertrand, 2013. "Switching to biomass co-firing in European coal power plants: Estimating the biomass and CO2 breakeven prices," Economics Bulletin, AccessEcon, vol. 33(2), pages 1535-1546.
    20. Wang, Qian & Han, Kuihua & Wang, Peifu & Li, Shijie & Zhang, Mingyang, 2020. "Influence of additive on ash and combustion characteristics during biomass combustion under O2/CO2 atmosphere," Energy, Elsevier, vol. 195(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:128:y:2018:i:pb:p:446-459. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.