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Simultaneous transesterification and esterification of acidic oil feedstocks catalyzed by heterogeneous tungsten loaded bovine bone under mild conditions

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  • Chaveanghong, Suwilai
  • Smith, Siwaporn Meejoo
  • Smith, Christopher B.
  • Luengnaruemitchai, Apanee
  • Boonyuen, Supakorn

Abstract

A highly active bi-functional catalyst system for the conversion of high free fatty acid content oil feedstock, and waste cooking oil to fatty acid methyl ester (FAME), is described. Tungsten loaded CaO/hydroxyapatite materials containing both basic, and acidic sites were derived from addition of 12-phosphotungstic acid to powdered bovine bone (BV), followed by calcination at 750 °C. Addition of 10% tungsten afforded 10 W/BV, which catalyzes FAME production from high acid value oil feedstock (24.38 mg KOH/g of oil) in 7 h at 120 °C at a methanol:oil ratio of 6:1. Conversion of waste cooking oil to FAME via simultaneous transesterification/esterification can be achieved in 5 h at 100 °C and at a methanol:oil ratio of 6:1, significantly more efficient than achievable using other bi-functional catalyst systems. The 10 W/BV catalyst system, readily prepared from a cheap, biomass derived support containing basic sites, is reusable, and allows for the production of fuel quality FAME in high yields from waste cooking oil, allowing for sustainable use of an otherwise wasted resource.

Suggested Citation

  • Chaveanghong, Suwilai & Smith, Siwaporn Meejoo & Smith, Christopher B. & Luengnaruemitchai, Apanee & Boonyuen, Supakorn, 2018. "Simultaneous transesterification and esterification of acidic oil feedstocks catalyzed by heterogeneous tungsten loaded bovine bone under mild conditions," Renewable Energy, Elsevier, vol. 126(C), pages 156-162.
    • Handle: RePEc:eee:renene:v:126:y:2018:i:c:p:156-162
    DOI: 10.1016/j.renene.2018.03.036
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    References listed on IDEAS

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    1. Lee, H.V. & Juan, J.C. & Taufiq-Yap, Y.H., 2015. "Preparation and application of binary acid–base CaO–La2O3 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 74(C), pages 124-132.
    2. Chaveanghong, Suwilai & Smith, Siwaporn Meejoo & Oopathum, Chutima & Smith, Christopher B. & Luengnaruemitchai, Apanee, 2017. "Fatty acid methyl ester (FAME) production from soybean oil under ambient conditions using strontium loaded bovine bone," Renewable Energy, Elsevier, vol. 109(C), pages 480-486.
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    1. Akhabue, Christopher Ehiaguina & Osa-Benedict, Evidence Osayi & Oyedoh, Eghe Amenze & Otoikhian, Shegun Kevin, 2020. "Development of a bio-based bifunctional catalyst for simultaneous esterification and transesterification of neem seed oil: Modeling and optimization studies," Renewable Energy, Elsevier, vol. 152(C), pages 724-735.

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