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Research on the pyrolysis process of crumb tire rubber in waste cooking oil

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  • Dong, Ruikun
  • Zhao, Mengzhen

Abstract

The use of waste cooking oil (WCO) in crumb tire rubber (CTR) pyrolysis not only improves the safety and controllability of the preparation process, but also recycles these two waste resources effectively. In this study, WCO was used as the solvent to pyrolyse CTR at high temperature to prepare waste rubber oil (WRO). The changes of CTR in molecular structure and rheological properties during thermal energy accumulation were explored through thermogravimetric analysis, Fourier transform infrared spectrometer, gel permeation chromatography and dynamic shear rheometer. The compatibility of CTR with virgin asphalt before and after pyrolysis was described by segregation test. Results show that, with the rise of temperature, depolymerized and broken rubber macromolecule in CTR continue to crack into molecules with less molecular weight, while more of natural rubber and carbon black are released. The rheological properties of WRO have changed greatly, i.e. the decreased zero shear viscosity, the improved flowability and the better plasticity. Complex chemical reactions occur during the pyrolysis of CTR, but no new functional group is generated except for the released natural rubber. The segregation test shows that, the compatibility of CTR with virgin asphalt can be improved by adopting WCO for pyrolysis.

Suggested Citation

  • Dong, Ruikun & Zhao, Mengzhen, 2018. "Research on the pyrolysis process of crumb tire rubber in waste cooking oil," Renewable Energy, Elsevier, vol. 125(C), pages 557-567.
    • Handle: RePEc:eee:renene:v:125:y:2018:i:c:p:557-567
    DOI: 10.1016/j.renene.2018.02.133
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    References listed on IDEAS

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    1. Kunwar, Bidhya & Cheng, H.N. & Chandrashekaran, Sriram R & Sharma, Brajendra K, 2016. "Plastics to fuel: a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 421-428.
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    1. Geraldo Cardoso de Oliveira Neto & Luiz Eduardo Carvalho Chaves & Luiz Fernando Rodrigues Pinto & José Carlos Curvelo Santana & Marlene Paula Castro Amorim & Mário Jorge Ferreira Rodrigues, 2019. "Economic, Environmental and Social Benefits of Adoption of Pyrolysis Process of Tires: A Feasible and Ecofriendly Mode to Reduce the Impacts of Scrap Tires in Brazil," Sustainability, MDPI, vol. 11(7), pages 1-18, April.
    2. Ashraf Aljarmouzi & Ruikun Dong, 2022. "Sustainable Asphalt Rejuvenation by Using Waste Tire Rubber Mixed with Waste Oils," Sustainability, MDPI, vol. 14(14), pages 1-27, July.
    3. Mamdouh T. Ghannam & Mohamed Y. E. Selim, 2021. "Rheological Properties of the Jojoba Biofuel," Sustainability, MDPI, vol. 13(11), pages 1-12, May.

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